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Copper(I) Hexafluorosilicate π-Complex with N-Allylmorpholinium Cation: A Rare Case of (C=C + 3O) Copper(I) Coordination in the Structure of [Cu(C4H8ONH(C3H5))(H2O)2]SiF6·H2O

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Abstract

The [Cu(C4H8ONH(C3H5))(H2O)2]SiF6·H2O compound (I) was obtained by alternating current electrochemical synthesis, starting from a solution containing CuSiF6·4H2O and N-allylmorpholinium hexafluorosilicate. Compound I crystallizes in a trigonal P 31 space group, a = 8.6449(4), c = 16.5629(11) Å, V = 1071.98(10) Å3, Z = 3 for Cu(C7H14NO)SiF6·3H2O composition, R = 0.0569 for 2987 reflections and 182 refined parameters. The C=C bond of one N-allylmorpholinium cation, elongated to 1.38(1) Å, the O-atom from another ligand moiety, and two oxygen atoms from two water molecules form the trigonal-pyramidal environment of the metal atom. The bridging function of the ligand moiety results in infinite metal-organic chains. One more water molecule is fixed in the crystal space by hydrogen bonds only.

Graphical Abstract

In the structure of the title compound, the CuI atom possesses rather unusual surrounding comprising the C=C-bond of the allyl group of one ligand moiety, two oxygen atoms from two water molecules, and one more oxygen atom from the morpholine ring of another ligand moiety.

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References

  1. Goreshnik EA, Olijnyk VV, Pecharsky VK, Mys’kiv MG (1994) Russ J Inorg Chem 39:71

    CAS  Google Scholar 

  2. Olijnyk VV, Goreshnik EA, Pecharsky VK, Budarin LI, Mys’kiv MG (1993) J Struct Chem 34:615

    Article  Google Scholar 

  3. Shkurenko AA, Davydov VN, Mys’kiv MG (2006) Russ J Coord Chem 32:270

    Article  CAS  Google Scholar 

  4. Rigaku Corporation (1999) Crystal clear. The Woodlands, Texas, USA

  5. Altomare A, Cascarano M, Giacovazzo C, Guagliardi A (1993) J Appl Cryst 26:343

    Article  Google Scholar 

  6. Crystal Structure Analysis, Package, Molecular Structure Corporation, (1997–1999) TeXan for Windows, version 1.06

  7. Sheldrick GM (2008) Acta Cryst A 64:112

    Article  Google Scholar 

  8. Farrugia LJ (1999) J Appl Cryst 32:837

    Article  CAS  Google Scholar 

  9. Crystal Impact GbR (2004–2005) DIAMOND v3.1. Bonn, Germany

  10. Myskiv MG, Oliinik VV (1995) Koordinatsionnaya Khimiya 21:290

    Google Scholar 

  11. Olijnyk VV, Goreshnik EA, Schollmeyer D, Mys’kiv MG (1997) Russ J Coord Chem 23:548

    Google Scholar 

  12. Goreshnik EA, Mys’kiv MG (2003) Russ J Coord Chem 29:505

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The authors thank the Slovenian Research Agency (ARRS) and Ukrainian Ministry for Science and Higher Education for financial support (bilateral project BI-UA/09-10-015, M/55-2009)

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Authors and Affiliations

  1. Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia

    E. A. Goreshnik

  2. Department of Inorganic Chemistry, Ivan Franko National University, L’viv, Ukraine

    M. G. Mys’kiv

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  1. E. A. Goreshnik
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  2. M. G. Mys’kiv
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Correspondence to E. A. Goreshnik.

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Goreshnik, E.A., Mys’kiv, M.G. Copper(I) Hexafluorosilicate π-Complex with N-Allylmorpholinium Cation: A Rare Case of (C=C + 3O) Copper(I) Coordination in the Structure of [Cu(C4H8ONH(C3H5))(H2O)2]SiF6·H2O. J Chem Crystallogr 40, 381–383 (2010). https://doi.org/10.1007/s10870-009-9666-1

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