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Solid State Structure of 6,7-Dihydro-1,4-Di(2′-Pyridyl)-5H-Cyclopenta[d]Pyridazine

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Abstract

The X-ray structure of 6,7-dihydro-1,4-di(2′-pyridyl)-5H-cyclopenta[d]pyridazine ligand (5-dppn) shows the existence of a trans/trans conformation. The 5-dppn crystallizes in a triclinic space group P-1 with a = 7.1048(15) Å; b = 9.008(2) Å; c = 10.986(3) Å; α = 88.279(16)°; β = 85.454(15)°; γ = 69.104(12)°; V = 654.7(3) Å3 and Z = 2. The analysis of 5-dppn crystal structure demonstrates the presence of edge-edge Ar–H···N and face-face Aliph-H···N centrosymmetric dimer interactions. The unit cell packing arrangement confirmed the presence of two molecules opposite to each other.

Index Abstract

The X-ray structure of 6,7-dihydro-1,4-di(2′-pyridyl)-5H-cyclopenta[d]pyridazine ligand (5-dppn) shows the existence of a trans/trans conformation.

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Acknowledgments

This work is supported by the Deanship of Scientific Research at Mu’tah University.

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Authors and Affiliations

  1. Department of Chemistry, Yarmouk University, Irbid, Jordan

    Mukarram H. Zaghal

  2. Department of Chemistry, Faculty of Science, Mu’tah University, P.O. Box 7, Mu’tah, 61710, Al-Karak, Jordan

    Hanan A. Qaseer, Arab K. El-Qisairi & Solhe F. Alshahateet

  3. Applied Chemical Sciences Department, Jordan University of Science and Technology, Irbid, Jordan

    Mazin Y. Shatnawi

  4. Centre for Chemical Analysis, Research and Training, Memorial University of Newfoundland, St. John’s, NL, A1B 3X7, Canada

    Louise N. Dawe

Authors
  1. Mukarram H. Zaghal
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  2. Hanan A. Qaseer
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  3. Arab K. El-Qisairi
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Correspondence to Hanan A. Qaseer.

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Zaghal, M.H., Qaseer, H.A., El-Qisairi, A.K. et al. Solid State Structure of 6,7-Dihydro-1,4-Di(2′-Pyridyl)-5H-Cyclopenta[d]Pyridazine. J Chem Crystallogr 39, 564–567 (2009). https://doi.org/10.1007/s10870-009-9533-0

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  • DOI: https://doi.org/10.1007/s10870-009-9533-0

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