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Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of Two Lanthanide Coordination Polymers with Diglycolic Acid

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Abstract

Two new coordination polymers {[Tb2(C4H4O5)3 · 4H2O] · 2H2O} n (1) and {[La2(C4H4O5)3 · 3H2O] · 3H2O} n (2) (C4H4O5 2− = diglycolato) were prepared by hydrothermal reaction and characterized by X-ray crystallography. The two complexes have different network structures through carboxylate oxygen atoms and ether oxygen atoms from diglycolato ligands linking lanthanide ions. The characteristic transition bands 5D4 → 7FJ (J = 6 − 3) of Tb(III) ion are observed in complex 1.

Graphical Abstract

Two new coordination polymers {[Tb2(C4H4O5)3 · 4H2O] · 2H2O} n (1) and {[La2(C4H4O5)3 · 3H2O] · 3H2O} n (2) (C4H4O5 2− = diglycolato) have network structures through the carboxylate oxygen atoms and ether oxygen atoms from diglycolato ligands. The emission spectrum of complex 1 indicates the 5D4 → 7FJ (J = 6 − 3) transitions of Tb(III) ion.

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References

  1. Reineke TM, Eddaoudi M, Fehr M, Kelley D, Yaghi OM (1999) J Am Chem Soc 121:1651–1657

    Article  CAS  Google Scholar 

  2. Pan L, Adams KM, Hermandez HE, Wang X, Zheng C, Hattori Y, Kaneko K (2003) J Am Chem Soc 125:3062–3067

    Article  CAS  Google Scholar 

  3. Kiritsis V, Michaelides A, Skoulika S, Golhen S, Ouahab L (1998) Inorg Chem 37:3407–3410

    Article  CAS  Google Scholar 

  4. Lill DT, Gunning NS, Cahill CL (2005) Inorg Chem 44:258–266

    Article  Google Scholar 

  5. Pan L, Woodlock EB, Wang X (2000) Inorg Chem 39:4174–4178

    Article  CAS  Google Scholar 

  6. Zheng XJ, Zheng TT, Jin LP (2005) J Mol Struct 740:31–35

    Article  CAS  Google Scholar 

  7. Zhang ZH, Okamura T, Hasegawa Y, Kawaguchi H, Kong LY (2005) Inorg Chem 44:6219–6227

    Article  CAS  Google Scholar 

  8. Wang YH, Zhang LP, Jin LP, Gao S, Lu SZ (2003) Inorg Chem 42:4985–4994

    Article  Google Scholar 

  9. Zheng XJ, Jin LP, Gao S (2004) Inorg Chem 43:1600–1602

    Article  CAS  Google Scholar 

  10. Li X, Zou Y (2005) J Chem Crystallorg 35:353–357

    Google Scholar 

  11. Elding I (1976) Acta Chem Scand A30:649–656

    Article  CAS  Google Scholar 

  12. Albertsson J (1968) Acta Chem Scand 22:1563–1578

    Article  CAS  Google Scholar 

  13. Sheldrick GM (1990) Acta Cryst A46:467

    CAS  Google Scholar 

  14. Sheldrick GM (1997) SHELXL97, program for X-ray crystal structure solution. University of Göttingen, Germany

    Google Scholar 

Download references

Acknowledgements

We are grateful to the Science and Technology Program, Beijing Municipal Education Commission (KM200510028007) and the Program supported by Young Mainstay Teachers Foundation of Beijing Municipal Universities.

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Authors and Affiliations

  1. Department of Chemistry, Capital Normal University, Beijing, 100048, People’s Republic of China

    Xia Li & Yan-Ling Ju

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  1. Xia Li
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  2. Yan-Ling Ju
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Correspondence to Xia Li.

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Li, X., Ju, YL. Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of Two Lanthanide Coordination Polymers with Diglycolic Acid. J Chem Crystallogr 39, 213–220 (2009). https://doi.org/10.1007/s10870-008-9462-3

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  • DOI: https://doi.org/10.1007/s10870-008-9462-3

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