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Synthesis and Crystal Structure of a 1D Coordination Polymer [Cd(pydc)(phen)]n (H2pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline)

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Abstract

A new 1D coordination polymer, [Cd(pydc)(phen)]n (1) (pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C19H11CdN3O4) crystallizes in triclinic space group P-1, features an interesting 3D zipper-like network constructed from 1D ribbons via π–π stacking interactions. Unit cell parameters for 1: a = 7.681(1) Å, b = 10.546(2) Å, c = 11.358(2) Å, α = 107.12(2)°, β = 99.50(2)°, γ = 109.12 (2)° and Z = 2.

Index Abstract

The title compound, [Cd(pydc)(phen)]n (1) (pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline), has been hydrothermally synthesized and characterized. X-ray diffraction analysis reveals that 1 features an interesting 3D zipper-like networks constructed by 1D ribbons via π–π stacking interactions.

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Acknowledgements

This work was granted financial support from the Program for Liaoning Excellent Talents in University(RC-05-11).

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  1. College of Chemistry, Liaoning University, Shenyang, 110036, People’s Republic of China

    Zheng-Bo Han, Guo-Xin Zhang, Jian-Wei Ji & Peng Zhang

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  1. Zheng-Bo Han
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  2. Guo-Xin Zhang
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Correspondence to Zheng-Bo Han.

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Han, ZB., Zhang, GX., Ji, JW. et al. Synthesis and Crystal Structure of a 1D Coordination Polymer [Cd(pydc)(phen)]n (H2pydc = pyridine-2,3-dicarboxylic acid, phen = 1,10-phenanthroline). J Chem Crystallogr 39, 169–172 (2009). https://doi.org/10.1007/s10870-008-9448-1

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  • DOI: https://doi.org/10.1007/s10870-008-9448-1

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