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Synthesis, Crystal Structures and Thermal Analysis of Two New Silver(I)–Dithioether Lamellar Coordination Polymers

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Abstract

Two new silver(I)–dithioether coordination polymers based on the self-assembly of the dithioether ligands L n−R = CH3–S(CH2) n S–CH3 (n = 1, 3) and AgX silver salts, where X = ClO4 − (1) and PF6 − (2), have been synthesized and characterized by single crystal X-ray diffraction and TGA. The crystallographic data of those complexes are: (1) Monoclinic P21/c; a = 16.5861(3) Å; b = 10.1048(2) Å; c = 15.7843(3) Å; β = 112.570(1)°; V = 2442.83(8) Å3; Z = 4. (2) Monoclinic P21/n; a = 8.6500(2) Å; b = 9.4053(2) Å; c = 24.0357(6) Å; β = 92.750(2)°; V = 1953.19(8) Å3; Z = 4. In both complexes, the dithioether building blocks propagated the silver(I) centers to build cationic lamellar coordination polymers, while ClO4 − and PF6 −, which were sandwiched between silver-ligand sheets, counterbalance only the charge of the networks. The thermogravimetric investigation reveals that those complexes decompose in a single step respectively to metallic silver and silver salt.

Index Abstract

Two new silver(I)–dithioether coordination polymers, obtained from the self-assembly of dithioether ligands and AgX salts with noncoordinating counteranions (X = ClO4 − and PF6 −), were characterized by X-ray crystallography and thermogravimetric analysis (TGA).

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References

  1. (a) Stumpt HO, Ouahab L, Pei Y, Grandjean D, Kahn O (1993) Science 26:447; (b) Gardner GB, Venkataraman D, Moore JS, Lee S (1995) Nature 374:792; (c) Yaghi OM, Li G, Li H (1995) Nature 378:703; (d) Bruce DW (2000) Acc Chem Rev 33:831

  2. Withersby MA, Blake AJ, Champness NR, Cooke PA, Hubberstey P, Li WS, Schröder M (1999) Inorg Chem 38:2259; (b) Blake AJ, Champness NR, Cooke PA, Nicolson JEB, Wilson C (2000) J Chem Soc Dalton Trans 3811; (c) Noro S, Kitaura R, Kondo M, Kitagawa S, Ishii T, Matsuzaka H, Yamashita M (2002) J Am Chem Soc 124:2568; (d) Chatterton NP, Goodgame DML, Grachvogel DA, Hussain I, White AJP, Williams DJ (2001) Inorg Chem 40:312; (e) Feazell RP, Carson CE, Klausmeyer KK (2006) Inorg Chem 45:2635

  3. (a) Awaleh MO, Badia A, Brisse F, Bu XH (2006) Inorg Chem 45:1560; (b) Awaleh MO, Badia A, Brisse F (2006) Cryst Growth Des 6:2674; (c) Silva RM, Smith MD, Gardinier JR (2006) Inorg Chem 45:2132

  4. (a) Yaghi OM, Li H (1995) J Am Chem Soc 117:10401; (b) Yaghi OM, Li H (1996) J Am Chem Soc 118:295; (c) Jung OS, Kim YJ, Lee YA, Park KM, Lee SS (2003) Inorg Chem 42:844

  5. (a) Pearson RG (1963) J Am Chem Soc 85:3533; (b) Pearson RG (1968) J Chem Educ 45:581; (c) Pearson RG (1968) J Chem Educ 45:643

  6. Hartley FR, Murray SG, Levason W, Soutter HE, McAuliffe CA (1979) Inorg Chim Acta 35:265

    Article  CAS  Google Scholar 

  7. SAINT Release 6.06 (1999) Integration software for single crystal data. Bruker AXS Inc., Madison, WI

  8. Sheldrick GM (1996) SADABS Bruker area detector absorption corrections. Bruker AXS Inc., Madison, WI

    Google Scholar 

  9. XPREP Release 5.10 (1997) X-ray data preparation and reciprocal space exploration program. Bruker AXS Inc., Madison WI

  10. SHELXTL Release 5.10 (1997) The complete software package for single-crystal structure determination. Brucker AXS Inc., Madison, WI

  11. (a) Sheldrick GM (1997) SHELXS97: program for the solution of crystal structures. University of Göttingen, Göttingen, Germany; (b) Sheldrick GM (1997) SHELXL97: program for the refinement of crystal structures. University of Göttingen, Göttingen, Germany

  12. Withersby MA, Blake AJ, Champness NR, Cooke PA, Hubberstey P, Li WS, Schroder M (1997) Angew Chem Int Ed Engl 36:2327

    Article  CAS  Google Scholar 

  13. (a) Feazell RP, Carson CE, Klausmeyer KK (2006) Inorg Chem 45:2627; (b) Feazell RP, Carson CE, Klausmeyer KK (2006) Inorg Chem 45:935

  14. Chen CL, Kang BS, Su CY (2006) Aust J Chem 59:3 and references therein

    Google Scholar 

  15. Moulton B, Zaworotko M (2001) J Chem Rev 101:1629 and references therein

    Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge La Présidence de la République de Djibouti and the Natural Sciences and Engineering Research Council of Canada for supporting this research. We are thankful to Mohamed Hassan, Secrétaire Général du Gouvernement and Président of the Conseil National Scientifique du CERD (Centre d’Étude et de Recherche de Djibouti) and Dr. Idriss Guirreh Farah for their encouragements.

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Authors and Affiliations

  1. Institut des Sciences de la Terre (IST), Centre d’Étude et de Recherche de Djibouti (CERD), B.P. 486, Djibouti-ville, Republic of Djibouti

    Mohamed Osman Awaleh

  2. Département de chimie, Université de Montréal, C.P. 6128, Succursale Centre-ville, Montreal, QC, Canada, H3C 3J7

    Antonella Badia & François Brisse

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  1. Mohamed Osman Awaleh
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  2. Antonella Badia
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  3. François Brisse
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Correspondence to Mohamed Osman Awaleh.

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Awaleh, M.O., Badia, A. & Brisse, F. Synthesis, Crystal Structures and Thermal Analysis of Two New Silver(I)–Dithioether Lamellar Coordination Polymers. J Chem Crystallogr 39, 122–127 (2009). https://doi.org/10.1007/s10870-008-9440-9

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  • DOI: https://doi.org/10.1007/s10870-008-9440-9

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