Skip to main content
SpringerLink
Log in

Synthesis and Structure of a Novel Polyoxomolybdate Lanthanide Complex: [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18] · 14H2O

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A novel polyoxometalate compound consisting of Anderson-type anions and trivalent lanthanide cations, [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18]·14H2O (1), has been synthesized in aqueous solution and characterized by single crystal X-ray diffraction, elemental analyses, IR spectrum and TG analyses. Single crystal X-ray diffraction reveals that compound 1 crystallizes in the triclinic space group P-1 with a = 11.046 (5) Å, b = 11.653 (5) Å, c = 13.935 (5) Å, α = 75.006 (5)°, β = 84.497(5)°, γ = 89.515(5)°. The bulk ions of compound 1 in the cell unit exhibit orthorhombic C-centered packing mode, the eight [Cr(2)(OH)6Mo6O18]3− anions occupy the eight corners and the two [Er2(H2O)14Cr(OH)6Mo6O18]3+ cations occupy the centres of two opposite faces, whereas anions and cations are linked together via hydrogen bonding interactions tightly forming a three-dimensional supramolecular architecture, which contains one-dimensional channels occupied by free water molecules.

Index Abstract

The bulk ions of compound 1 in the cell unit exhibit orthorhombic C-centered packing mode, the eight [Cr(2)(OH)6Mo6O18]3− anions occupy the eight corners and the two [Er2(H2O)14Cr(OH)6Mo6O18]3+ cations occupy the centres of two opposite faces, whereas anions and cations are linked together via hydrogen bonding interactions tightly forming a three-dimensional supramolecular architecture, which contains one-dimensional channels occupied by free water molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Hill CL (1998) Chem Rev 98:1

    Article  CAS  Google Scholar 

  2. (a) Coronado E, Galan-Mascaros JR, Gimenez-Saiz C, Gomez-Garcia CJ (1993) Adv Mater 283:4; (b) Casan-Pastor N, Baker LCW (1992) J Am Chem Soc 114:345; (c) Yamase T (1993) Mol Eng 3:241

  3. (a) Reinoso S, Vitoria P, Lezama L, Luque A, Gutiérrez-Zorrilla JM (2003) Inorg Chem 42:3709; (b) Zhang H, Duan LY, Lan Y, Wang EB, Hu CW (2003) Inorg Chem 42:8053

  4. Bareyt S, Piligkos S, Hasenknopf B, Gouzerh P, Lacôte E, Thorimbert S, Malacria M (2003) Angew Chem Int Ed Engl 42:3404

    Article  CAS  Google Scholar 

  5. (a) Chen YG, Yan LK, Hao XR, Liu K, Wang XH, Lu PP (2006) Inorg Chim Acta 359:2550; (b) Xu L, Lu M, Xu BB, Wei YG, Peng ZH, Powell DR (2002) Angew Chem Int Ed 41:4129

  6. (a) Shivaiah V, Reddy PVN, Cronin L, Das SKJ (2002) Chem Soc Dalton Trans 3781; (b) Drewes D, Limanski EM, Krebs BJ (2004) Chem Soc Dalton Trans 2087; (c) Drewes D, Limanski EM, Krebs BJ (2004) Eur J Inorg Chem 4849; (d) Gao B, Liu SX, Xie LH, Yu M, Zhang CD, Sun CY, Cheng HY (2006) J Solid State Chem 179:1681; (e) An HY, Xiao DR, Wang EB, Li YG, Xu L (2005) Eur J Inorg Chem 854

  7. (a) Khan MI, Yohannes E, Powell D (1999) Chem Commun 23; (b) Khan MI, Yohannes E, Doedens R (1999) Angew Chem Int Ed 38:1292; (c) Cui XB, Xu JQ, Meng H, Zheng ST, Yang GY (2004) Inorg Chem 43:8005

  8. (a) Kalcher K (1990) Electroanalysis 2:419; (b) Wang XL, Wang EB, Lan Y, Hu CW (2002) Electroanalysis 14:1116

  9. Dossing A (2005) Eur J Inorg Chem 1425

  10. Benelli C, Gatteschi D (2002) Chem Rev 102:2369

    Article  CAS  Google Scholar 

  11. Kobayashi S, Sugiura M, Kitagawa H, Lam WWL (2002) Chem Rev 102:2227

    Article  CAS  Google Scholar 

  12. Wang XL, Guo YQ, Li YG, Wang EB, Hu CW, Hu NH (2003) Inorg Chem 42:4135

    Article  CAS  Google Scholar 

  13. (a) An HY, Xiao DR, Wang EB, Sun CY, Li YG, Xu L (2005) J Mol Struct 751:184; (b) An HY, Xiao DR, Wang EB, Sun CY, Xu L (2005) J Mol Struct 743:117; (c) An HY, Li YG, Xiao DR, Wang EB, Sun CY (2006) Cryst Growth Des 6:1107

  14. Perloff A (1970) Inorg Chem 9:2228

    Article  CAS  Google Scholar 

  15. (a) Sheldrick GM (1997) SHELXS 97, Program for crystal structure solution. University of Göttingen, Germany; (b) Sheldrick GM (1997) SHELXS 97, Program for crystal structure refinement. University of Göttingen, Germany

  16. (a) International Tables for X-ray Crystallography (1962) Kynoch Press, Birmingham, England (Present distributor: Kluwer Academic Publisher, Dordrecht), vol III, p 72; (b) Krische MJ, Lehn JM (2000) Struct Bonding 96:3

  17. (a) Yuan M, Li YG, Wang EB, Lu Y, Hu CW, Hu NH, Jia HQ (2002) J Chem Soc Dalton Trans 2916; (b) HanZB, Wang EB, Luan GY, Li YG, Zhang H, Duan YB, Hu CW, Hu NH (2002) J Mater Chem 12:1169

  18. Brown ID, Altermatt D (1985) Acta Crystallogr Sect B 41:244

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, People’s Republic of China

    Dongmei Shi, Mixia Hu, Chunjing Zhang, Jia Li & Yaguang Chen

Authors
  1. Dongmei Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mixia Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chunjing Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jia Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yaguang Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yaguang Chen.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shi, D., Hu, M., Zhang, C. et al. Synthesis and Structure of a Novel Polyoxomolybdate Lanthanide Complex: [Er2(H2O)14Cr(OH)6Mo6O18][Cr(OH)6Mo6O18] · 14H2O. J Chem Crystallogr 38, 695–700 (2008). https://doi.org/10.1007/s10870-008-9378-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-008-9378-y

Keywords

Search

Navigation