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Synthesis and Crystal Structure of a Novel Silver Sulfonate Involving Ag–C Interactions

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Abstract

A new coordination polymer [Ag(C6H5NHC6H4SO3)] (1) was synthesized by the reaction of sodium diphenylamine sulfonate, [C6H5NHC6H4SO3Na] (NaL, L = C6H5NHC6H4SO −3 ) and silver nitrate and its structure was determined by X-ray diffraction analysis. The crystals are triclinic Pī space group with cell parameters a = 5.640(1) Å, b = 10.711(2) Å and c = 10.737(2) Å, α = 117.70(1)°, β = 90.95(1)°, γ = 94.51(1)°, V = 571.5 (4) Å3, and Z = 2. The X-ray analysis shows that each silver cation is 4-coordinated by three oxygen atoms and one phenyl ring carbon atom. Silver cations are bridged by sulfonate groups to form an 8-membered closed ribbon structure, each ribbon is connected to the two neighboring ribbons through the organometallic bonds between the phenyl carbon atoms and the silver ions of the neighboring ribbons to form two-dimensional layer.

Index Abstract

Reaction of sodium diphenylamine sulfonate, [C6H5NHC6H4SO3Na] (NaL, L = C6H5NHC6H4SO −3 ), with silver nitrate affords a novel silver sulfonate, [Ag(C6H5NHC6H4SO3)] (1) involving Ag–C interactions.

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Acknowledgments

We thank the National Natural Science Foundation of China (No. 20471014), Program for New Century Excellent Talents in Chinese University, Program for Changjiang Scholars and Innovative Research Teams in Chinese University and the Analysis and Testing Foundation of Northeast Normal University for support.

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Authors and Affiliations

  1. Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Fang-Fang Li, Jian-Fang Ma, Jin Yang & Ying-Ying Liu

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  1. Fang-Fang Li
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Correspondence to Jian-Fang Ma.

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Li, FF., Ma, JF., Yang, J. et al. Synthesis and Crystal Structure of a Novel Silver Sulfonate Involving Ag–C Interactions. J Chem Crystallogr 38, 525–528 (2008). https://doi.org/10.1007/s10870-008-9344-8

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  • DOI: https://doi.org/10.1007/s10870-008-9344-8

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