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Synthesis and Structure of Di-μ-oxo-bistripyrazolylborato Dioxo Vanadium (V) Complex with Lattice of Diacetonitrile

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Abstract

A novel oxovanadium complex was obtained by the reaction of VOSO4 · 3H2O with tripyrazolylborate sodium in MeOH. The complex (1) was characterized by element analysis, IR spectroscopy, 1HNMR and its crystal for X-ray diffraction recrystallized from saturated CH3CN solution. The compound crystallizes in the monoclinic, space group Pbca, with cell dimensions of a = 15.531(2) Å; b = 18.007(2) Å; c = 10.725(2) Å; V = 2,999.4(8) Å3 and D calc = 1.533 g/cm3 for Z = 4. The structure was solved by direct methods and refined to an R-value of 0.0401. Structure analysis show that it is a di-μ-oxo-bistripyrazolylborato dioxo vanadium (V) complex with lattice of diacetonitrile. In addition, the electronic structure and the bonding characters of the complex were analyzed with ab initio calculations.

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References

  1. Butler A, Carrano CJ (1991) Coord Chem Rev 109:61

    Article  CAS  Google Scholar 

  2. Thompson KH, Orvig C (2001) Coord Chem Rev 219:1033

    Article  Google Scholar 

  3. Thompson KH, McNeill JH, Orvig C (1999) Chem Rev 99:2561

    Article  CAS  Google Scholar 

  4. Sakurai H, Kojitane Y, Yoshikawa Y, Kawabe K, Yasui H (2002) Coord Chem Rev 226:187

    Article  CAS  Google Scholar 

  5. Etcheverry SB, Williams PAM, Salice VC, Barrio DA, Ferrer EG, Cortizo AM (2002) BioMetals 15:37

    Article  CAS  Google Scholar 

  6. Semiz S, Orvig C, McNeill JH (2002) Biochemistry 231:23

    CAS  Google Scholar 

  7. Shechter Y (1990) Diabetes 39:1

    Article  CAS  Google Scholar 

  8. Etcheverry SB, Willams PAM, Barrio DA, Salice VC, Ferrer EG (2000) J Inorg Biochem 80:169

    Article  CAS  Google Scholar 

  9. Thompson KH, Liboiron BD, Sun Y, Bellman KDD, Setyawati IA, Patrick BO, Karunaratne V, Rawji G, Wheeler J, Sutton K, Bhanot S, Cassidy C, McNeill JH, Yuen VG, Orvig C (2003) J Bio Inorg Chem 8:66

    Article  CAS  Google Scholar 

  10. Crans DC, Smee JJ, Gaidamauskas E, Yang L (2004) Chem Rev 104:849

    Article  CAS  Google Scholar 

  11. Collison D, Eardley DR, Mabbs FE, Powell AK, Turner SS (1993) Inorg Chem 32:664

    Article  CAS  Google Scholar 

  12. Scheuer S, Fischer J, Kress J (1995) Organometallics 14:2627

    Article  CAS  Google Scholar 

  13. Ellen K, Spartalian K, DeRusha M, Nunn CM, Carrano CJ (1989) Inorg Chem 28:4392

    Article  Google Scholar 

  14. Kumagai H, Kitagawa S, Maekawa M, Kawata S, Kiso H, Munakata M (2002) J Chem Soc Dalton Trans 2390

  15. Reglinski J, Garner M, Cassidy ID, Slavin PA, Spicer MD, Armstrong DR (1999) J Chem Soc Dalton Trans 2119

  16. Sheldrick GM (1990) Acta Crystallogr A46:467

    CAS  Google Scholar 

  17. Sheldrick GM (1998) Acta cryst B54:443

    Google Scholar 

  18. Farrugia LJ (1997) J Appl Cryst 30:565

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20771051) and SRF for ROCS, SEM and Education Foundation of Liaoning Province (No. 05L212) for financial assistance.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, China

    Yong Heng Xing, Yuan Hong Zhang & Bao Li Zhang

  2. Department of Materials Science, Toyohashi University of Technology, Toyohashi, 441-8580, Japan

    Katsuyuki Aoki

  3. College of Life Science, Liaoning Normal University, Huanghe Road 850#, Dalian, 116029, China

    Feng Ying Bai

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  1. Yong Heng Xing
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  2. Katsuyuki Aoki
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  3. Feng Ying Bai
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  4. Yuan Hong Zhang
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Correspondence to Yong Heng Xing.

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Xing, Y.H., Aoki, K., Bai, F.Y. et al. Synthesis and Structure of Di-μ-oxo-bistripyrazolylborato Dioxo Vanadium (V) Complex with Lattice of Diacetonitrile. J Chem Crystallogr 38, 327–331 (2008). https://doi.org/10.1007/s10870-008-9326-x

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  • DOI: https://doi.org/10.1007/s10870-008-9326-x

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