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Synthesis, Spectroscopic Studies and Crystal Structure of N,N′-bis((thiophene-2-carboxamido)propyl)piperazine

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Abstract

A new multidentate ligand N,N′-bis((thiophene-2-carboxamide)propyl)piperazine has been synthesized from the reaction of thiophene-2-carbonylchloride and 1,4-bis(3-aminopropyl)piperazine. The title compound has been characterized by elemental analysis, FT-IR, 1H-NMR and 13C-NMR spectroscopic techniques. The crystal structure of the title compound (C20H30N4O2S2Cl2) has also been determined by X-ray analysis. The title compound crystallize in the monoclinic space group P21/c with a = 9.768(1), b = 12.895(1), c = 10.083(1) Å, β = 115.12(1)°, V = 1149.9(2) Å3, D x = 1.425 g cm−3 and Z = 2. The crystal structure was solved by direct methods and refined by full-matrix least squares to a find R = 0.039 [I > 2σ (I)] for 2,786 observed reflections.

Graphical Abstract

The (N,N’–bis((thiophene-2- carboxamido)propyl)piperazine) molecule has been synthesized and its molecule structure has been investigated by using , FT-IR, 13C NMR and 1H-NMR spectroscopic and crystallographic techniques.

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Notes

  1. Further information may be obtained from: Cambridge Crystallographic Data Center (CCDC), 12 Union Road, Cambridge CB21EZ, UK, by quoting the depository number CCDC-231864 E-mail: deposit@ccdc.cam. ac.uk

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Authors and Affiliations

  1. Faculty of Arts and Sciences, Department of Chemistry, Gazi University, Besevler, Ankara, 06100, Turkey

    Ayla Balaban, Naki Çolak & Birgül Erk

  2. Faculty of Sciences, Department of Physics, Ankara University, Besevler, Ankara, 06100, Turkey

    Hüseyin Ünver, Tahsin Nuri Durlu & D. Mehmet Zengin

Authors
  1. Ayla Balaban
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  2. Naki Çolak
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  3. Hüseyin Ünver
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  4. Birgül Erk
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  5. Tahsin Nuri Durlu
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  6. D. Mehmet Zengin
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Correspondence to Hüseyin Ünver.

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Balaban, A., Çolak, N., Ünver, H. et al. Synthesis, Spectroscopic Studies and Crystal Structure of N,N′-bis((thiophene-2-carboxamido)propyl)piperazine. J Chem Crystallogr 38, 369–372 (2008). https://doi.org/10.1007/s10870-007-9302-x

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  • DOI: https://doi.org/10.1007/s10870-007-9302-x

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