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Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n [L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine]

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Abstract

The reaction of the organic ligand, 5,6-dicyano-2,3-di(2-pyridyl)pyrazine (L) with AgClO4, leads to the formation of a novel complex {[Ag(L)(CH3CN)](ClO4)}n 1, which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis (monoclinic system, space group P2(1)/n, with a = 11.290(4), b = 12.660(5), c = 15.202(6) Å, β = 90.141(6)°, V = 13371(2) Å3 and Z = 4). The crystal structure of complex consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and \({\text{ClO}}_{\text{4}}^{-}\) anions. In the cation of 1, each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent L ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by L ligands which adopt N3-coordinated bridging mode to form a zig-zag chain.

Index abstract

Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n [L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine]

Qian Gao, Ya-Bo Xie*, Sha Chen, and Dao Wang

The crystal structure of complex {[Ag(L)(CH3CN)](ClO4)}n (L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine) consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and \({\text{ClO}}_{\text{4}}^{-}\) anions. Each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by ligands which adopt N3-coordinated bridging mode to form a zig-zag chain.

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Acknowledgment

This work was supported by the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality.

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  1. College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, 100022, China

    Qian Gao, Ya-Bo Xie, Sha Chen & Dao Wang

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  1. Qian Gao
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  2. Ya-Bo Xie
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  3. Sha Chen
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  4. Dao Wang
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Correspondence to Ya-Bo Xie.

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Gao, Q., Xie, YB., Chen, S. et al. Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n [L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine]. J Chem Crystallogr 37, 797–800 (2007). https://doi.org/10.1007/s10870-007-9249-y

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