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Structure and self-assembly synthesis of a novel heterometallic one-dimensional coordination polymer: {[Cu(II)(DETA)I·DMF]2[Pb2I6]} n

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A novel organic–inorganic hybrid coordination polymer {[Cu(II)(DETA)I·DMF]2[Pb2I6]} n (DETA = diethylene triamine, DMF = N,N′-dimethyl formamide) was synthesized by the reaction of CuSO4·6H2O, DETA, Pb(NO3)2 and NaI in DMF/H2O mixed solvent at room temperature. Structural characterization of X-ray single diffraction reveals that the polymeric negative chain [Pb2I6] n 2− is built up by face-sharing of PbI6 octahedrons. Upon the hydrogen bonds interaction between N–H···I and N–H···O, structure-directing reagent chain {[Cu(II)(DETA)I·DMF]2} n 2+ presents one-dimension arrangement. Structure-directing reagent chains and polymeric negative chains are in combination with each other by static attracting force to form the so-called hybrid structure. The title compound was further characterized by IR, EA, UV-Vis and fluorescence spectrum.

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Acknowledgements

This work was supported by the Foundation of Education Committee of Fujian Province (JB03053, JB04016 and JB04017).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350002, P.R. China

    Haohong Li, Zhirong Chen, Junqian Li, Changcang Huang, Guangcan Xiao & Bin Zhao

  2. Center of Analysis and Measurement, Fuzhou University, Fuzhou, Fujian, 350002, P.R. China

    Guangcan Xiao

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  1. Haohong Li
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  2. Zhirong Chen
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  3. Junqian Li
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  4. Changcang Huang
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Correspondence to Zhirong Chen.

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Supplementary material

Crystallographic data for the structure reported in this paper has been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-248011. Copies of the data can be obtained free of charge at http://www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44(0)1223-336033; email:deposit@ccdc.cam.ac.uk).

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Li, H., Chen, Z., Li, J. et al. Structure and self-assembly synthesis of a novel heterometallic one-dimensional coordination polymer: {[Cu(II)(DETA)I·DMF]2[Pb2I6]} n . J Chem Crystallogr 36, 419–425 (2006). https://doi.org/10.1007/s10870-005-9038-4

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  • DOI: https://doi.org/10.1007/s10870-005-9038-4

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