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A new assembly containing [Fe(dien)2]2+ and [Ni(CN)4]2− ions

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A tetracyanometallate with complex dien cation [Fe(dien)2][Ni(CN)4] (1) (dien = diethylenetriamine), has been prepared and characterized by IR, UV-Vis and ESR spectroscopies. Single crystal X-ray analysis reveals that the compound assumes a ‘zero-dimensional’ structure in which one iron(II) ion is coordinated by six nitrogen atoms of the two dien ligands and the [Ni(CN)4]2− anion remains outside the coordination sphere. The six-coordinate iron(II) centres display a distorted octahedral arrangement.

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Acknowledgments

This work is supported by the National Natural Science Foundation of China (Nos. 20471031, 20331010) and Tianjin Natural Science Foundation (No. 04360211).

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Authors and Affiliations

  1. Department of Chemistry, Nankai University, Tianjin, 300071,, P. R. China

    Hui-Bo Zhou, Li-Hua Yu, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan & Peng Cheng

  2. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on Structure of Matter, Chinese Academy of Science, Fuzhou Fujian, 350002,, P. R. China

    Hui-Bo Zhou & Dai-Zheng Liao

  3. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093,, P. R. China

    Zong-Hui Jiang

  4. Earth Material Chemistry and Application, Peking University, Beijing, 100871,, P. R. China

    Shi-Ping Yan

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  1. Hui-Bo Zhou
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  2. Li-Hua Yu
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Correspondence to Dai-Zheng Liao.

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Zhou, HB., Yu, LH., Liao, DZ. et al. A new assembly containing [Fe(dien)2]2+ and [Ni(CN)4]2− ions. J Chem Crystallogr 36, 13–16 (2006). https://doi.org/10.1007/s10870-005-9009-9

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  • DOI: https://doi.org/10.1007/s10870-005-9009-9

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