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Synthesis and crystal structure of a novel 3D supramolecular complex [Na(DC18C6-B)][Ni(mnt)2]

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Abstract

A supramolecular complex [Na(DC18C6-B)][Ni(mnt)2] (1) (DC18C6-B = cis-anti-cis-dicyclohexyl-18-crown-6, isomer B; mnt = maleonitriledithiolate) has been prepared and characterized by elementary analysis, FT-IR spectroscopy and X-ray single crystal diffraction. It crystallizes in triclinic, space group P1 with crystallographic data: a = 7.974(4) Å, b = 14.343(7) Å, c = 15.559(8) Å, α = 96.230(8)∘, β = 100.361(8)∘, γ = 93.849(9)∘, V = 1733.2(15) Å3, Z = 2, Dcalcd = 1.408 g/cm3, F(000) = 766, R1 = 0.0491, wR2 = 0.1018. The formula unit contains one [Na(DC18C6-B)]+ complex cation and one [Ni(mnt)2]− complex anion, which are constructed into an infinite chain-like structure through Na–N bonds. The resulting chains crisscross on the [Ni(mnt)2]− complex anions and further assemble into an unusual 3D supramolecular framework via the weak interactions.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Feng-Ying Dong, Jian-Min Dou, Da-Cheng Li, Xi-Ke Gao & Da-Qi Wang

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  1. Feng-Ying Dong
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  2. Jian-Min Dou
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  3. Da-Cheng Li
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  4. Xi-Ke Gao
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Correspondence to Jian-Min Dou.

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Dong, FY., Dou, JM., Li, DC. et al. Synthesis and crystal structure of a novel 3D supramolecular complex [Na(DC18C6-B)][Ni(mnt)2]. J Chem Crystallogr 35, 523–528 (2005). https://doi.org/10.1007/s10870-005-2855-7

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  • DOI: https://doi.org/10.1007/s10870-005-2855-7

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