Abstract
The title compound crystallizes in the monoclinic space group P21/n with unit cell parameters a = 10.842(9), b = 5.750(7), c = 12.964(6) Å, β = 110.13(6)∘, V = 758.8(11) Å3 and Z = 4. The final reliability index is 0.060 for 1034 observed reflections. The five-membered heterocyclic thiazole ring is coplanar with its fused benzene ring. The crystal structure is stabilized by two intermolecular N=H ⋅s N hydrogen bonded interactions.
Similar content being viewed by others
References
Gupta, A.K.S.; Misra, H.K. Indian J. Chem. 1979, 17B, 185.
Trivedi, B.; Shah, V.H. Indian Acad. Sci. (Chem. Sci.) 1992, 104(4), 489.
Radha, R.B.; Bhalerao, U.T.; Rahman, M.F. Indian J. Chem. 1990, 20B, 995.
Srivastava, N.; Bahadur, S.; Verma, H.N.; Khan, M.M. Curr. Sci. 1984, 53, 235.
Deshmukh, M.B. Private communication; Shivaji University: Kolhapur, India, 2004.
Rajnikant; Gupta, V.K.; Singh, A. Crystallogr. Rep. 2000, 45(4), 611.
Rajnikant; Gupta, V.K.; Lal, M. Crystallogr. Rep. 2001a, 46, 230.
Rajnikant; Gupta, V.K.; Deshmukh, M.B.; Varghese, B.; Dinesh. Crystallogr. Res. Technol. 2001b, 36(12), 1451.
Rajnikant; Gupta, V.K.; Suri, O.P.; Lal, M. Indian J. Pure Appl. Phys. 2002a, 40, 59.
Rajnikant; Gupta, V.K.; Deshmukh, M.B.; Varghese, B.; Dinesh. Crystallogr. Rep. 2002b, 47, 449.
Rajnikant; Dinesh; Deshmukh; M.B.; Kamni. Acta Cryst. 2003, E59, 1768.
Rajnikant; Dinesh; Kamni; Deshmukh, M.B. J. Chem. Crystallogr. 2004, 34(7), 471.
Sheldrick, G.M. SHELXS86, Program for Crystal Structure Determination; University of Göttingen: Germany, 1986.
Sheldrick, G.M. SHELXL93, Program for Refinement of Crystal Structures; University of Göttingen: Germany, 1993.
Nardelli, M. J. Appl .Cryst. 1995, 28, 659.
Farrugia, L.J. Molecular Graphics—ORTEP-III for Windows, J. Appl. Cryst. 1997, 30, 565.
Khan, M.A.; Taylor, R.W.; Lehn, J.M.; Dietrich, B. Acta Cryst. 1988, C44, 1928.
Potenza, J.; Mastropaolo, D. Acta Cryst. 1974, B30, 2353.
Rudd, S.; Barny, G. Acta Cryst. 1984, B30, 2118.
Bhatia, S.C.; Kumar, A.; Gautam, P.; Jain, P.C. Acta Cryst. 1991, C47, 1908.
Teo, S.B.; Okechuckwu, R.C.; Teoh, S.G. Acta Cryst. 1995, C51, 1629.
Desiraju, G.R.; Steiner, T., The weak hydrogen bond in Structural Chemistry and Biology, IUCr, Oxford Press, 1999, 48.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rajnikant, Dinesh, Kamni et al. Crystallographic investigations of benzothiazol-2-yl-hydrazine. J Chem Crystallogr 35, 293–296 (2005). https://doi.org/10.1007/s10870-005-1440-4
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10870-005-1440-4