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Synthesis and structure of a new hybrid vanadium arsenate: [VO2(phen)]2(H2AsO4)⋅H3O

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Abstract

A new hybrid vanadium arsenate [VO2(phen)]2(H2AsO4)⋅H3O 1 (phen = 1,10′-phenanthroline) was synthesized under hydrothermal reaction conditions and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR and elemental analyses. Crystal data for 1: monoclinic, P21/n, a = 9.175(2) Å, b = 18.638(5) Å, c = 14.482(4) Å, β = 102.333(3)∘, V = 2419(1) Å3, Z = 4. Compound 1 is composed of discrete tricyclic (VO2)2(H2AsO4) cluster decorated with two phen ligands. The discrete arsenic–vanadium clusters are extended into three-dimensional supramolecular arrays via π–π stacking interactions of phen groups.

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China

    Shou-Tian Zheng, Jie Zhang & Guo-Yu Yang

  2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu, 210093, China

    Guo-Yu Yang

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  1. Shou-Tian Zheng
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  2. Jie Zhang
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  3. Guo-Yu Yang
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Correspondence to Guo-Yu Yang.

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Zheng, ST., Zhang, J. & Yang, GY. Synthesis and structure of a new hybrid vanadium arsenate: [VO2(phen)]2(H2AsO4)⋅H3O. J Chem Crystallogr 35, 269–273 (2005). https://doi.org/10.1007/s10870-005-1287-8

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  • DOI: https://doi.org/10.1007/s10870-005-1287-8

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