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ZnCo-MOF derived porous ZnO/Co/C composites as superior electromagnetic wave absorbers

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Abstract

The ZnO/Co/C composite materials, consisting of ZnO and ferromagnetic Co embedded in a carbon skeleton were successfully synthesized through the pyrolysis of a ZnCo-MOF precursor. The evolution of phase and microstructure was systematically investigated. The results indicate that the EMW absorption performance is dependent on the degree of graphitization and phase compositions. When the precursor pyrolysis temperature is 800 ℃, the ZnO/Co/C composites benefiting from the synergistic effect of constituents and microstructure demonstrate exceptional EMW absorption performance, with a minimum reflection loss (RLmin) of -52.2 dB at 11.5 GHz and a sample thickness of 2.23 mm. The widest effective absorption bandwidth (EAB) harvests 6.7 GHz (11.3-18 GHz) with a sample thickness of 2 mm, encompassing the entire Ku band. Herein, this study shed light on exploring high-efficiency MOF-based EMW absorption materials with rational design of components and structure, and the as-prepared ZnO/Co/C composites are potential candidates for EMW absorption applications.

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Acknowledgements

The authors would like to thank Shiyanjia lab (www.shiyanjia.com) for the support of TEM/HRTEM and XPS tests.

Funding

This work was supported by the National Natural Science Foundation of China (51972114, 52272062), National College Students Innovation and Entrepreneurship Training Program (202010561010), and 100-Step Ladder Climbing Program of South China University of Technology (j2tw202302019).

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  1. School of Materials Science and Engineering, South China University of Technology, Guangzhou, 510641, People’s Republic of China

    Sizhu Ren, Pingping Mo & Anze Shui

  2. School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, 333403, People’s Republic of China

    Junjie Qian

  3. School of Physics and Materials Science, Guangzhou University, Guangzhou, 510006, People’s Republic of China

    Bin Du

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Ren performed the experiment; Ren, Qian, Mo performed the data analyses and wrote the manuscript; Du, Shui, Qian helped perform the analysis with constructive discussions.

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Ren, S., Mo, P., Shui, A. et al. ZnCo-MOF derived porous ZnO/Co/C composites as superior electromagnetic wave absorbers. J Mater Sci: Mater Electron 35, 530 (2024). https://doi.org/10.1007/s10854-024-12148-9

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