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Low-temperature sintering and microwave dielectric properties of H3BO3-added 0.8BaSi2O5–0.2Ba3(VO4)2 composite ceramics

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Abstract

In this study, 0.8BaSi2O5–0.2Ba3(VO4)2 composite ceramics were successfully synthesized with the addition of H3BO3 (x = 2–6 wt%) at lower temperatures using a solid-state sintering process. The phase composition and crystal structure were analyzed by X-ray diffraction, which confirmed that the addition of H3BO3 did not change the phase structure of the ceramics. The composite ceramics still consisted of BaSi2O5 and Ba3(VO4)2. The addition of H3BO3 effectively reduced the sintering temperature of the composite ceramics while maintaining the excellent microwave dielectric properties. The sintering temperature of the 0.8BaSi2O5–0.2Ba3(VO4)2 ceramic was reduced from 1140 to 950 °C with the addition of 3 wt% H3BO3. The 0.8BaSi2O5–0.2Ba3(VO4)2–3wt%H3BO3 composite ceramics, sintered at 950 °C for 4 h, exhibited the optimal microwave dielectric properties, with values of εr = 9.23, Q×f = 33,026 GHz, and τf = − 4.85 ppm/°C. XRD and EDS energy spectra revealed no chemical reaction between the composite ceramic and silver, highlighting its potential as a candidate for low-temperature co-fired ceramic (LTCC) applications in communications.

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Funding

The authors thank the National Natural Science Foundation of China (General Program,12374394), Youth Project of Natural Science Foundation of Jiangsu Province (BK20230341), Nanjing Overseas Educated Personnel Science and Technology Innovation Program, Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) and “Qinglan Project” Young and Middle-aged Academic Leaders Program of Jiangsu Province for financial support.

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Authors and Affiliations

  1. College of Materials Science and Engineering, Nanjing Tech University, 211816, Nanjing, Jiangsu, China

    Ben Heng, Lifeng Ding, Dawei Wang, Chun Tong, Haikui Zhu, Lixi Wang, Yi Hou & Qitu Zhang

  2. Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, 211816, Nanjing, Jiangsu, China

    Ben Heng, Lifeng Ding, Dawei Wang, Chun Tong, Haikui Zhu, Lixi Wang, Yi Hou & Qitu Zhang

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  1. Ben Heng
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Contributions

BH and QZ conceived and designed the study. BH, LD and DW performed the work. ST, HZ and LW provided testing and analysis. BH wrote the paper. BH, LD and HZ reviewed and modified the manuscript. All authors read and approved the manuscript.

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Correspondence to Haikui Zhu or Qitu Zhang.

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Heng, B., Ding, L., Wang, D. et al. Low-temperature sintering and microwave dielectric properties of H3BO3-added 0.8BaSi2O5–0.2Ba3(VO4)2 composite ceramics. J Mater Sci: Mater Electron 35, 429 (2024). https://doi.org/10.1007/s10854-024-12095-5

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