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The structural and electrical properties of basaltic glasses modified by ZnO

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Abstract

In order to investigate the structural and electrical properties of basaltic glass modified by ZnO, ZnO-modified basaltic glasses were prepared by the conventional melt-cooling method. The relationship between glass structure and electrical properties was investigated using XRD, FT-IR, Raman, DSC, dielectric properties tester and volume resistance tester. The results show that when ZnO doping is lower than 6 wt%, it does not lead to basalt glass crystallization. The ZnO doping shows roughly a linear relationship with the volume resistivity, but the trend is not obvious. The optimum doping of ZnO was 4 wt%, at this doping level, the glass network was the most connected with the lowest values of dielectric constant (6.5) and dielectric loss (0.005). This finding provides theoretical support for the replacement of E-glass fibers by basalt fibers in terms of dielectric properties.

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The data supporting the findings of this study are available upon reasonable request from the authors.

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Funding

This work was supported by grants from the Hebei Provincial Science and Technology Department (206Z1501G), the Chinese Academy of Sciences Foundation for Poverty Alleviation (81832390), the academician workstation construction grant from Hebei Dipaogu Incubator Co., Ltd (204790416 H), the science and technology project of Hebei Education Department (BJK2023040) and the Hebei University of Geosciences Doctoral Research Start-up Fund (BQ2019008).

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Authors and Affiliations

  1. Hebei Key Laboratory of Green Development of Rock and Mineral Materials, Institute of Basalt Fiber Materials, School of Gemmology and Materials Science, Hebei GEO University, Shijiazhuang, 050031, China

    Lingtao Zeng, Zhao Yuan, Yan Li, Letao Jiang, Chuncheng Yang, Changjiang Liu & Hongchao Li

  2. Land and Resources Exploration Center of Hebei Bureau of Geology and Mineral Exploration and Development (Hebei Mine and Geological Disaster Emergency Rescue Center), Shijiazhuang, 050081, China

    Jinzhao Zhao

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  1. Lingtao Zeng
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  2. Zhao Yuan
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  4. Yan Li
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  6. Chuncheng Yang
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  7. Changjiang Liu
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  8. Hongchao Li
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Contributions

LZ wrote the first draft of the manuscript and completed all the experimental work with ZY, JZ collected and analyzed the data, YL and LJ revised the manuscript, CY and CL conceived and designed the work, and HL approved the final version. All authors expressed their views on the writing of the manuscript and all authors read and approved the final manuscript.

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Correspondence to Hongchao Li.

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Zeng, L., Yuan, Z., Zhao, J. et al. The structural and electrical properties of basaltic glasses modified by ZnO. J Mater Sci: Mater Electron 34, 2305 (2023). https://doi.org/10.1007/s10854-023-11765-0

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