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Effect of doping Mn/Fe/Co on the ferroelectric properties and depolarization behavior of BNT ceramics

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Abstract

The performance of ferroelectric ceramics is usually improved by low-valent ion doping modification. However, the effects of low-valent ions doping on the ferroelectric properties and depolarization behavior of BNT ceramics are unclear. Herein, we fabricated Bi0.5Na0.5(Ti1−xYx)O3 (Y = Mn/Fe/Co) ceramics by conventional solid-state method, and systematically studied the effects of Mn/Fe/Co doping on the ferroelectricity and depolarization behavior of BNT ceramics. It was found that Mn/Fe/Co doping promoted the grain growth with the increased grain size. The density of Mn-doped samples decreased while Fe/Co-doped samples increased. The rhombohedral lattice distortion increased after Mn/Fe/Co doping. As a result, the ferroelectricity of BNT-based ceramics was improved and the dielectric loss was reduced after Mn/Fe/Co doping. However, the depolarization temperature (Td) decreased with Mn/Co doping while increased with Fe doping. The hardness almost decreased after Mn/Fe/Co doping. These results can provide guidance for optimizing ferroelectric properties of BNT-based systems for application in high-power generators. .

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Funding

This work was funded by the National Science Foundation of China (No. 52102125), Natural Science Foundation of Fujian Province (Grant numbers 2021J05223), the Opening Project of Key Laboratory of Inorganic Functional Materials and Devices, Chinese Academy of Sciences (Grant numbers KLIFMD202101), Research Fund of Fujian University of Technology (Grant numbers GY-Z21068), and the Opening Project of Key Laboratory for Ultrafine Materials, Ministry of Education (JKD01231702).

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Authors and Affiliations

  1. Center for Advanced Energy and Functional Materials, Fujian Provincial Key Laboratory of Advanced Materials Processing and Applications, School of Materials Science and Engineering, Fujian University of Technology, 69 Xueyuan Road, Fuzhou, 350108, People’s Republic of China

    Ping Peng, Kun Liu, Kunyou Li, Xinxing Luo, Xueqing Xiao, Wei Li & Chan Zheng

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  1. Ping Peng
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  2. Kun Liu
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  3. Kunyou Li
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Contributions

PP: Investigation, Formal analysis, Writing—original draft preparation, Methodology, Software. KL: Investigation, Methodology, Writing—original draft preparation, Software, Data curation. KL and XL: Investigation, Methodology, Software, Data curation. XX, WL, and CZ: Discussion, Writing—review and editing. All authors read and approved the final manuscript.

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Correspondence to Ping Peng.

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Peng, P., Liu, K., Li, K. et al. Effect of doping Mn/Fe/Co on the ferroelectric properties and depolarization behavior of BNT ceramics. J Mater Sci: Mater Electron 34, 2238 (2023). https://doi.org/10.1007/s10854-023-11646-6

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