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Synthesis of MOF-derived porous multi-metal/carbon composites by metal regulation strategy for efficient microwave absorption application

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Abstract

The combination of carbon and ferrimagnet metallic materials derived from metal-organic frameworks (MOFs) have received increasing research interest for high performance electromagnetic wave absorption (EMA) materials due to their unique composition and microstructure. Here, a series of MOF-74 is synthesized by tuning the ratio of mixed metallic ions of cobalt and nickel, which are then treated in an inert atmosphere to fabricate novel composites with metallic cores encapsulated in a porous carbon shell. The dielectric loss caused by carbon shells and the magnetic loss caused by the cores of cobalt, nickel, or their alloys, coupled with the interfacial polarization caused by the space charge formed between the magnetic cores and the dielectric carbon shells, the highly efficient electromagnetic wave absorption performance of the composites is ensured. Ni@PC has a better EMA with an effective absorption bandwidth of 4.72 GHz at a thickness of 2.66 mm, while CoNi@PC_1 has an effective absorption bandwidth of 4.16 GHz at a thickness of 2.08 mm and is the thinnest at similar absorption widths. The properties obtained in this study indicate that the bimetallic MOF-74 with adjustable metal-ion ratio provides a new idea for the fabrication of high-efficiency MOF-based EMA materials.

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Data availability

All data included in this study are available upon request by contact with the corresponding author.

References

  1. Y. Cui, K. Yang, J. Wang, T. Shah, Q. Zhang, B. Zhang, Carbon 172, 1 (2021)

    Article  CAS  Google Scholar 

  2. X. Zhou, Z. Jia, A. Feng, J. Kou, H. Cao, X. Liu, G. Wu, Compos. Part B Eng. 192, 107980 (2020)

    Article  CAS  Google Scholar 

  3. X. Yang, X. Zhong, J. Zhang, J. Gu, J Mater Sci Technol. 68, 209 (2021)

    Article  CAS  Google Scholar 

  4. M.-S. Cao, X.-X. Wang, W.-Q. Cao, J. Yuan, J. Mater. Chem. C 3, 6589 (2015)

    Article  CAS  Google Scholar 

  5. D.D.L. Chung, Carbon 39, 279 (2001)

    Article  CAS  Google Scholar 

  6. S. Geetha, K.K. Satheesh Kumar, C.R.K. Rao, M. Vijayan, D.C. Trivedi, J Appl. Polym. Sci. 112, 2073 (2009)

    Article  CAS  Google Scholar 

  7. F. Qin, C. Brosseau, J. Appl. Phys. 111, 061301 (2012)

    Article  Google Scholar 

  8. A.N. Yusoff, M.H. Abdullah, S.H. Ahmad, S.F. Jusoh, A.A. Mansor, S.A.A. Hamid, J. Appl. Phys. 92, 876 (2002)

    Article  CAS  Google Scholar 

  9. J.-M. Thomassin, C. Jérôme, T. Pardoen, C. Bailly, I. Huynen, C. Detrembleur, Mater. Sci. Eng. R Rep. 74, 211 (2013)

    Article  Google Scholar 

  10. J. Joo, C.Y. Lee, J. Appl. Phys. 88, 513 (2000)

    Article  CAS  Google Scholar 

  11. S. Motojima, Y. Noda, S. Hoshiya, Y. Hishikawa, J. Appl. Phys. 94, 2325 (2003)

    Article  CAS  Google Scholar 

  12. A. Wang, W. Wang, C. Long, W. Li, J. Guan, H. Gu, G. Xu, J. Mater. Chem. C 2, 3769 (2014)

    Article  CAS  Google Scholar 

  13. X. Huang, J. Zhang, M. Lai, T. Sang, J. Alloys Compd. 627, 367 (2015)

    Article  CAS  Google Scholar 

  14. X. Wu, S. Chen, Y. Feng, Q. Yuan, J. Gao, Y. Chen, Y. Huang, Y.-B. He, W. Gan, Mater. Today Phys. 9, 100132 (2019)

    Article  Google Scholar 

  15. J. Zhao, J. Zhang, L. Wang, J. Li, T. Feng, J. Fan, L. Chen, J. Gu, Compos. Commun. 22, 100486 (2020)

    Article  Google Scholar 

  16. Z. Wang, X. Li, L. Wang, Y. Li, J. Qin, P. Xie, Y. Qu, K. Sun, R. Fan, Adv. Compos. Hybrid. Mater. 3, 1 (2020)

    Article  CAS  Google Scholar 

  17. J. Yu, Y. Li, X. Xu, G. Duan, Y. Li, W. Zhou, Compos. Commun. 24, 100643 (2021)

    Article  Google Scholar 

  18. D. Liu, Y. Du, F. Wang, Y. Wang, L. Cui, H. Zhao, X. Han, Carbon 157, 478 (2020)

    Article  CAS  Google Scholar 

  19. L. Wang, X. Shi, J. Zhang, Y. Zhang, J. Gu, J. Mater. Sci. Technol. 52, 119 (2020)

    Article  CAS  Google Scholar 

  20. P. Liu, S. Gao, Y. Wang, F. Zhou, Y. Huang, J. Luo, Compos. Part B Eng. 202, 108406 (2020)

    Article  CAS  Google Scholar 

  21. Y. Lian, B. Han, D. Liu, Y. Wang, H. Zhao, P. Xu, X. Han, Y. Du, Nano-Micro Lett. 12, 153 (2020)

    Article  CAS  Google Scholar 

  22. T. Hou, J. Wang, T. Zheng, Y. Liu, G. Wu, P. Yin, Small (2023). https://doi.org/10.1002/smll.202303463

    Article  Google Scholar 

  23. P. Yi, X. Zhang, L. Jin, P. Chen, J. Tao, J. Zhou, Z. Yao, Chem. Eng. J 430, 132879 (2022)

    Article  CAS  Google Scholar 

  24. H. Peng, M. He, Y. Zhou, Z. Song, Y. Wang, S. Feng, X. Chen, X. Zhang, H. Chen, Chem. Eng. J. 433, 133269 (2022)

    Article  CAS  Google Scholar 

  25. Z. Li, X. Han, Y. Ma, D. Liu, Y. Wang, P. Xu, C. Li, Y. Du, ACS Sustain. Chem. Eng. 6, 8904 (2018)

    Article  CAS  Google Scholar 

  26. J. Zhou, D. Lan, F. Zhang, Y. Cheng, Z. Jia, G. Wu, P. Yin, Small (2023). https://doi.org/10.1002/smll.202304932

    Article  Google Scholar 

  27. J.-K. Sun, Q. Xu, Energy Environ. Sci. 7, 2071 (2014)

    Article  CAS  Google Scholar 

  28. F. Zhang, Z. Jia, J. Zhou, J. Liu, G. Wu, P. Yin, Chem. Eng. J. 450, 138205 (2022)

    Article  CAS  Google Scholar 

  29. P. Yin, G. Wu, Y. Tang, S. Liu, Y. Zhang, G. Bu, J. Dai, Y. Zhao, Y. Liu, Chem. Eng. J. 446, 136975 (2022)

    Article  CAS  Google Scholar 

  30. B.W. Jacobs, R.J.T. Houk, M.R. Anstey, S.D. House, I.M. Robertson, A.A. Talin, M.D. Allendorf, Chem. Sci. 2, 411 (2011)

    Article  CAS  Google Scholar 

  31. L. Peng, J. Zhang, Z. Xue, B. Han, J. Li, G. Yang, Chem. Commun. 49, 11695 (2013)

    Article  CAS  Google Scholar 

  32. P. Gai, H. Zhang, Y. Zhang, W. Liu, G. Zhu, X. Zhang, J. Chen, J. Mater. Chem. B 1, 2742 (2013)

    Article  CAS  Google Scholar 

  33. K.E. deKrafft, C. Wang, W. Lin, Adv. Mater. 24, 2014 (2012)

    Article  CAS  Google Scholar 

  34. B. Liu, H. Shioyama, T. Akita, Q. Xu, J. Am. Chem. Soc. 130, 5390 (2008)

    Article  CAS  Google Scholar 

  35. L. Ma, S. Li, F. Liu, S. Ma, E.-H. Han, Z. Zhang, J. Alloys Compd 906, 164257 (2022)

    Article  CAS  Google Scholar 

  36. B. Wen, H. Yang, Y. Lin, L. Wang, L. Ma, Y. Qiu, Compos. Part. Appl. Sci. Manuf. 138, 106044 (2020)

    Article  CAS  Google Scholar 

  37. K. Wang, Y. Chen, R. Tian, H. Li, Y. Zhou, H. Duan, H. Liu, ACS Appl. Mater. Interfaces 10, 11333 (2018)

    Article  CAS  Google Scholar 

  38. J. Ouyang, Z. He, Y. Zhang, H. Yang, Q. Zhao, ACS Appl. Mater. Interfaces 11, 39304 (2019)

    Article  CAS  Google Scholar 

  39. P. Xue, Y. Chen, Y. Xu, C. Valenzuela, X. Zhang, H.K. Bisoyi, X. Yang, L. Wang, X. Xu, Q. Li, Nano-Micro Lett. 15, 1 (2023)

    Article  CAS  Google Scholar 

  40. X. Zhang, X. Tian, C. Liu, J. Qiao, W. Liu, J. Liu, Z. Zeng, Carbon 194, 257 (2022)

    Article  CAS  Google Scholar 

  41. X. Yang, S. Fan, Y. Li, Y. Guo, Y. Li, K. Ruan, S. Zhang, J. Zhang, J. Kong, J. Gu, Compos. Part. Appl. Sci. Manuf. 128, 105670 (2020)

    Article  CAS  Google Scholar 

  42. X. Li, A.I. Rykov, B. Zhang, Y. Zhang, J. Wang, Catal. Sci. Technol. 6, 7486 (2016)

    Article  CAS  Google Scholar 

  43. G. Sun, H. Wu, Q. Liao, Y. Zhang, Nano Res. 11, 2689 (2018)

    Article  CAS  Google Scholar 

  44. M. Fu, Q. Jiao, Y. Zhao, H. Li, J. Mater. Chem. A 2, 735 (2013)

    Article  Google Scholar 

  45. H. Ning, G. Li, Y. Chen, K. Zhang, Z. Gong, R. Nie, W. Hu, Q. Xia, ACS Appl. Mater. Interfaces 11, 1957 (2019)

    Article  CAS  Google Scholar 

  46. J. Li, P. Miao, K.-J. Chen, J. Cao, J. Liang, Y. Tang, J. Kong, Compos. Part B Eng. 182, 107613 (2020)

    Article  CAS  Google Scholar 

  47. F.L. Jia, L.Z. Zhang, X.Y. Shang, Y. Yang, Adv Mater. 20, 1050 (2008)

    Article  CAS  Google Scholar 

  48. I. Abdalla, A. Salim, M. Zhu, J. Yu, Z. Li, B. Ding, ACS Appl. Mater. Interfaces 10, 44561 (2018)

    Article  CAS  Google Scholar 

  49. K. Yue, Y. Bo, M.A. Tian, C. Zeng-Yong, Z. Zheng-Jun, J. Inorg. Mater. 33, 1259 (2018)

    Article  Google Scholar 

  50. Y. Wu, D. Lan, J. Ren, S. Zhang, Mater. Today Phys. 36, 101178 (2023)

    Article  CAS  Google Scholar 

  51. C. Luo, T. Jiao, J. Gu, Y. Tang, J. Kong, ACS Appl. Mater. Interfaces 10, 39307 (2018)

    Article  CAS  Google Scholar 

  52. Y. Zhang, Y. Huang, T. Zhang, H. Chang, P. Xiao, H. Chen, Z. Huang, Y. Chen, Adv. Mater. 27, 2049 (2015)

    Article  CAS  Google Scholar 

  53. P. Xu, X. Han, C. Wang, D. Zhou, Z. Lv, A. Wen, X. Wang, B. Zhang, J. Phys. Chem. B 112, 10443 (2008)

    Article  CAS  Google Scholar 

  54. F. Pan, L. Yu, Z. Xiang, Z. Liu, B. Deng, E. Cui, Z. Shi, X. Li, W. Lu, Carbon 172, 506 (2021)

    Article  CAS  Google Scholar 

  55. M. Zhou, W. Gu, G. Wang, J. Zheng, C. Pei, F. Fan, G. Ji, J. Mater. Chem. A 8, 24267 (2020)

    Article  CAS  Google Scholar 

  56. L. Yang, L. Yin, C. Hong, S. Dong, C. Liu, X. Zhang, J. Colloid Interface Sci. 582, 270 (2021)

    Article  CAS  Google Scholar 

  57. H. Zhang, K. Sun, K. Sun, L. Chen, G. Wu, J. Mater. Sci. Technol. 158, 242 (2023)

    Article  Google Scholar 

  58. Y. Shi, L. Yu, K. Li, S. Li, Y. Dong, Y. Zhu, Y. Fu, F. Meng, Compos. Sci. Technol. 197, 108246 (2020)

    Article  CAS  Google Scholar 

  59. Y. Wei, H. Liu, S. Liu, M. Zhang, Y. Shi, J. Zhang, L. Zhang, C. Gong, Compos. Commun. 9, 70 (2018)

    Article  Google Scholar 

  60. W. Liu, S. Tan, Z. Yang, G. Ji, Carbon 138, 143 (2018)

    Article  CAS  Google Scholar 

  61. P. Liu, S. Gao, Y. Wang, Y. Huang, Y. Wang, J. Luo, ACS Appl. Mater. Interfaces 11, 25624 (2019)

    Article  CAS  Google Scholar 

  62. P.J. Van Der Zaag, J. Magn. Magn. Mater. 196–197, 315 (1999)

    Article  Google Scholar 

  63. R. Shu, J. Zhang, C. Guo, Y. Wu, Z. Wan, J. Shi, Y. Liu, M. Zheng, Chem. Eng. J. 384, 123266 (2020)

    Article  CAS  Google Scholar 

  64. Z. Xu, Y. Du, D. Liu, Y. Wang, W. Ma, Y. Wang, P. Xu, X. Han, ACS Appl. Mater. Interfaces 11, 4268 (2019)

    Article  CAS  Google Scholar 

  65. H. Wu, J. Liu, H. Liang, D. Zang, Chem. Eng. J. 393, 124743 (2020)

    Article  CAS  Google Scholar 

  66. W. Li, L. Wang, G. Li, Y. Xu, J. Magn. Magn. Mater. 377, 259 (2015)

    Article  CAS  Google Scholar 

  67. C. Luo, Y. Tang, T. Jiao, J. Kong, ACS Appl. Mater. Interfaces 10, 28051 (2018)

    Article  CAS  Google Scholar 

  68. Y. Pan, Q. Zhu, J. Zhu, Y. Cheng, B. Yu, Z. Jia, G. Wu, Nano Res. 16, 10666 (2023)

    Article  CAS  Google Scholar 

  69. S. Zhang, X. Liu, C. Jia, Z. Sun, H. Jiang, Z. Jia, G. Wu, Nano-Micro Lett. 15, 204 (2023)

    Article  Google Scholar 

  70. J. Peng, Z. Peng, Z. Zhu, R. Augustine, M.M. Mahmoud, H. Tang, M. Rao, Y. Zhang, G. Li, T. Jiang, Ceram Int. 44, 21015 (2018)

    Article  CAS  Google Scholar 

  71. Z. Yang, H. Lv, R. Wu, Nano Res. 9, 3671 (2016)

    Article  CAS  Google Scholar 

  72. L. Huang, C. Chen, X. Huang, S. Ruan, Y.-J. Zeng, Compos. Part B Eng. 164, 583 (2019)

    Article  CAS  Google Scholar 

  73. D. Lan, Y. Wang, Y. Wang, X. Zhu, H. Li, X. Guo, J. Ren, Z. Guo, G. Wu, J. Colloid Interface Sci. 651, 494 (2023)

    Article  CAS  Google Scholar 

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Funding

This work was supported by the Scientific Research Foundation of Hangzhou Dianzi University (Grant No. TKYZTC2021-013), the Fundamental Research Funds for the Provincial Universities of Zhejiang (Grant Nos. GK239909299001-027, GK229909299001-028, GK239909299001-007), the National Natural Science Foundation of China (Grant No. 51901060), the Key Research Project of Zhejiang Lab (Grant No. 2022MH0AC01) and the National Natural Science Foundation of Zhejiang Province (LY21E010004).

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  1. Yuting Li and Kun Zhang have contributed equally to this work.

Authors and Affiliations

  1. School of Material and Environmental Engineering, Hangzhou Dianzi University, Hangzhou, 310018, China

    Yuting Li, Kun Zhang, Zhizhen Xu, Xiaoyu Zhao, Yaxin Wang, Fengyi Zhang, Xiaojie Guo & Yongjun Zhang

  2. Hangzhou Dianzi University Shangyu Institute of Science and Engineering, Shaoxing, 312300, China

    Kun Zhang & Yongjun Zhang

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  1. Yuting Li
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  3. Zhizhen Xu
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by YL, KZ. The first draft of the manuscript was written by YL, KZ and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript. YL and KZ contributed equally to this work.

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Correspondence to Kun Zhang or Yongjun Zhang.

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Li, Y., Zhang, K., Xu, Z. et al. Synthesis of MOF-derived porous multi-metal/carbon composites by metal regulation strategy for efficient microwave absorption application. J Mater Sci: Mater Electron 34, 2229 (2023). https://doi.org/10.1007/s10854-023-11640-y

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