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Direct pen writing and atomic-scale molecular dynamics simulation study of a novel silver nano-ink

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Abstract

Herein, a facile synthesis approach for silver nanoparticles is disclosed through reduction action without the need for a peristaltic pump or inert gas shielding has been disclosed. Subsequent electron microscopy, X-ray diffraction, Ultraviolet–Visible spectroscopy and Fourier transform infrared spectroscopy were conducted to characterize the optimized nanoparticles with an average grain size of 29.9 nm. Employing a designed ink containing 35 wt% silver, four types of inks by direct writing showed different printability on the glass surface and conductive behavior. A resistivity value as low as 4.7 × 10−7 Ω m was achieved following basic traditional sintering process at 250 °C for 30 min, along with stable electrical conductivity under repeated bending, suitable for bending in flexible electronic devices. Finally, molecular dynamics simulation was applied to gain a deeper understanding of the melting and sintering processes of Ag nanoparticles during the atomic-level bonding.

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The datasets generated during and/or analysed during the current study are available from the corresponding author on reasonable request.

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Funding

The financial support of Xi’an Advanced Manufacturing Technology Project (Grant No. 21XJZZ0048), and Key Research and Development Program of Shaanxi Province (Grant No. 2023-YBGY-467) are acknowledged.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Xi’an University of Technology, Xi’an, 710048, China

    Longchao Zhuo, Qinghao Wang & Jiacheng Sun

  2. Xi’an Research Institute of Navigation Technology, Electronics Technology Group Corporation, Xi’an, 710068, China

    Yaoyao Feng & Enhuai Yin

  3. Shaanxi Provincial Machinery Research Institute Co., Ltd, Xi’an, 712000, China

    Wen Liu

  4. 3D Printing Research and Engineering Technology Center, AECC Beijing Institute of Aeronautical Materials, Beijing, 100095, China

    Bingqing Chen

  5. Shenzhen Emerycomm Co. Ltd, Shenzhen, 518100, China

    Samuel Lin

  6. China Railway Liuyuan Xi’an Survey, Design and Research Institute Co., Ltd., of CREC, Xi’an, 710054, China

    Qiqi Zhang

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  1. Longchao Zhuo
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  2. Qinghao Wang
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  3. Jiacheng Sun
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  6. Wen Liu
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by QW, YF, and WL. The first draft of the manuscript was written by LZ and all authors commented on previous versions of the manuscript. QW, JS, EY, BC, SL, and QZ contributed to the writing—review and editing, with additional contributions to figures from JS, EY, WL, BC, SL, and QZ. All authors read and approved the final manuscript.

Corresponding authors

Correspondence to Longchao Zhuo, Enhuai Yin, Bingqing Chen or Samuel Lin.

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Zhuo, L., Wang, Q., Sun, J. et al. Direct pen writing and atomic-scale molecular dynamics simulation study of a novel silver nano-ink. J Mater Sci: Mater Electron 34, 2182 (2023). https://doi.org/10.1007/s10854-023-11628-8

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