Abstract
In this study, both the Au/(ZnCdS:GO(1:1) doped PVP)/n-Si and Au/(ZnCdS:GO(1:0.5) doped PVP)/n-Si (MPS) type SDs which are named as SD1 and SD2, respectively, were fabricated onto the same n-Si wafer to determine effect of the rates of them using the I–V and C/G-V measurements. The basic electrical-parameters of them such as reverse-saturation current (Is), ideality-factor (n), barrier-height (ΦB), rectification-ratio (RR), series/shunt resistances (RS, and Rsh) values, were calculated from the I–V data-based on thermionic-emission (TE) theory. The voltage dependence of surface -states profile was obtained from both the forward-bias I–V data (by considering voltage dependence of n, BH) and high–low frequency capacitance (CLF–CHF) methods for two SDs and were compared. These results indicate that SD2 has a lower leakage current and higher RR, Rsh, and BH than SD1 diode. On the other hand, the values of Nss with the same order (∼1012–1013 eV−1 cm2) for two SDs getting increases from the mid-gap of the semiconductor toward the bottom of the conduction band and change from region to region due to a particular density distribution of them in the bandgap. Both the voltage-dependent profile of Nss and Rs was also extracted from the C/G-V data by using Nicollian–Brews and high–low frequency capacitance method, respectively, and the values of them for SD2 are lower than the SD1 in the whole measured voltage range.
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The datasets generated and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
B.L. Sharma, Metal-semiconductor Schottky barrier junctions and their applications (Plenum Press, New York, 1984)
S.M. Sze, K.K. Ng, Physics of semiconductor devices (Wiley, New York, 2006)
H.C. Card, E.H. Rhoderick, Studies of tunnel MOS diodes I. Interface effects in Silicon Schottky diodes. J. Phys. D 4, 1589 (1971)
S. Altındal Yerişkin, M. Balbaşı, İ Orak, The effects of (graphene doped-PVA) interlayer on the determinative electrical parameters of the Au/n-Si (MS) structures at room temperature. J. Mater. Sci. 28, 14040–14048 (2017)
R. Khan, N. Ilyas, M.Z.M. Shamim, M.I. Khan, M. Sohail, N. Rahman, A.A. Khan, S.N. Khang, A. Khan, Oxide-based resistive switching-based devices: fabrication, influence parameters and applications. J. Mater. Chem. C 9, 15755–15788 (2021)
I. Jabbar, Y. Zaman, K. Althubeiti, S.A. Otaibi, M.Z. Ishaque, N. Rahman, M. Sohail, A. Khan, A. Ullah, T.D. Rosso, Q. Zaman, R. Khan, A. Khan, Diluted magnetic semiconductor properties in TM doped ZnO nanoparticles. RSC Adv. 12, 13456–13463 (2022)
R. Khan, N.U. Rehman, N. Ilyas, N. Sfina, M. Barhoumi, A. Khan, K. Althubeiti, S.A. Otaibi, S. Iqbal, N. Rahman, M. Sohail, A. Ullah, T.D. Rosso, Q. Zaman, A.A. Khan, S.S. Abdullaev, A. Khan, Threshold switching in nickel-doped zinc oxide based memristor for artificial sensory applications. Nanoscale 15, 1900–1913 (2023)
V. Rajagopal Reddy, C. Venkata Prasad, Surface chemical states, electrical and carrier transport properties of Au/ZrO2/n-GaN MIS junction with a high-k ZrO2 as an insulating layer. Mater. Sci. Eng. 231, 74–80 (2018)
Ş Altındal, Ö. Sevgili, Y. Azizian Kalandaragh, A comparison of electrical parameters of Au/nSi and Au/(CoSO4–PVP) /nSi structures (SBDs) to determine the effect of (CoSO4–PVP) organic interlayer at room temperature. J. Mater. Sci. 30, 9273–9280 (2019)
H.G. Çetinkaya, Ş Altındal, İ Orak, İ Uslu, Electrical characteristics of Au/n-Si (MS) Schottky Diodes (SDs) with and without different rates (graphene + Ca1.9Pr0.1Co4Ox doped poly (vinyl alcohol)) interfacial layer. J. Mater. Sci. 28, 7905–7911 (2017)
E. Orhan, A. Anter, M. Ulusoy, B. Polat, C. Okuyucu, M. Yıldız, Ş Altındal, Effect of Gadolinium on electrical properties of polyethyleneimine functionalized and Nitrogen-doped Graphene quantum dot nanocomposite based diode. Adv. Electron. Mater. 2300261, 1–12 (2023)
M. Ulusoy, Y. Badali, G. Pirgholi-Givi, Y. Azizian-Kalandaragh, Ş Altındal, The capacitance/conductance and surface state intensity characteristics of the Schottky structures with ruthenium dioxide-doped organic polymer interface. Synth. Met. 292, 117243 (2023)
M. Sharma, S.K. Tripathi, Analysis of interface states and series resistance for Al/PVA:n-CdS nanocomposite metal–semiconductor and metal–insulator–semiconductor diode structures. Appl. Phys. A 113, 491 (2013)
W. Wan, A. Dawn Bannerman, L. Yang, H. Mak, Poly (vinyl alcohol) cryogels for biomedical applications. Polym. Cryog. 263, 7–8 (2014)
V.R. Reddy, Electrical properties of Au/poly vinylidene fluoride/n-InP Schottky diode with polymer interlayer. Thin Solid Films 556, 300 (2014)
K.K. Sadasivuni, D. Ponnamma, J. Kim, S. Thomas, Graphene-based polymer nanocomposites in electronics (Springer, New York, 2015)
S. Altındal Yerişkin, Y. Şafak Asar, Influence of graphene doping rate in PVA organic thin film on the performance of Al/p-Si structure. J. Mater. Sci. 32, 22860–22867 (2021)
S. Karadaş, S. Altındal Yerişkin, M. Balbaş, Y. Azizian-Kalandaragh, Complex dielectric, complex electric modulus, and electrical conductivity in Al/(Graphene-PVA)/p-Si (metal-polymer-semiconductor) structures. J. Phys. Chem. Solids 148, 109740 (2021)
A. Büyükbaş Ulusan, İ Taşçıoğlu, A. Tataroğlu, F. Yakuphanoğlu, Ş Altındal, A comparative study on the electrical and dielectric properties of Al/(Cd–doped ZnO)/p–Si structures. J. Mater. Sci. 30, 12122–12129 (2019)
M.Y.A. Rahman, Review of graphene and its modification as cathode for dye-sensitized solar cells. J. Mater. Sci. 32, 23690–23719 (2021)
K. Novoselov, V. Falko, L. Colombo, P. Gellert, M. Schwab, K. Kim, A roadmap for graphene. Nature. 490, 192–200 (2012)
T.H. Tsai, S.C. Chiou, S.M. Chen, Enhancement of Dye-Sensitized Solar cells by using Graphene TiO2 Composites as Photoelectrochemical Working Electrode. Int. J. Electrochem. Sci. 6, 3333–3343 (2011)
N.O. Weiss, H. Zhou, L. Liao, Y. Liu, S. Jiang, Y. Huang, X. Duan, Graphene: an emerging electronic material. Adv. Mater. 24, 5782–5825 (2012)
H. Liu, Y.Y. Zhang, D.J. Li, Y.J. Li, Z.L. Jin, Design and preparation of a CeVO4/ Zn0.5Cd0.5S S-scheme heterojunction for efficient photocatalytic hydrogen evolution. ACS Appl. Energy Mater. 5, 2474–2483 (2022)
N. Soltani, E. Saion, M.Z. Hussein, M. Erfani, A. Abedini, G. Bahmanrokh, M. Navasery, P. Vaziri, Visible light-induced degradation of methylene blue in the presence of photocatalytic ZnS and CdS nanoparticles. Int. J. Mol. Sci. 13, 12242–12258 (2012)
Z. Wei, Y. Lu, J. Zhao, S. Zhao, R. Wang, N. Fu, X. Li, L. Guan, F. Teng, Synthesis and luminescent modulation of ZnS crystallite by a hydrothermal method. ACS Omega. 3, 137–143 (2018)
R.J. Stella, G.T. Rao, V.P. Manjari, B. Babu, C.R. Krishna, R.V. Ravikumar, Structural and optical properties of CdO/ZnS core/shell nanocomposites. J. Alloys Compd. 628, 39–45 (2015)
S. Demirezen, Ş Altındal, I. Uslu, Two diodes model and illumination effect on the forward and reverse bias I–V and C–V characteristics of Au/PVA (Bi-doped)/n-Si photodiode at room temperature. Curr. Appl. Phys. 13, 53–59 (2013)
Ç.Ş Güçlü, A.F. Özdemir, Ş Altındal, Double exponential I–V characteristics and double gaussian distribution of barrier heights in (Au/Ti)/Al2O3/n-GaAs (MIS)-type Schottky barrier diodes in wide in wide temperature range. Appl. Phys. A 122, 1032 (2016)
A. Büyükbaş-Uluşan, A. Tataroğlu, Y. Azizian-Kalandaragh, M. Koşal, Double-exponential current-voltage (I-V) and negative capacitance (NC) behavior of Al/(CdSe-PVA)/p-Si/Al (MPS) structure. J. Mater. Sci. 30, 9572–9581 (2019)
M. Gökçen, S. Taran, Double parallel barrier height behavior of Au/Poly (linoleic acid)-g-poly (methyl methacrylate) (PLiMMA)/n-Si structure. Microelectron. Reliab. 99, 132–136 (2019)
E.E. Baydilli, A. Kaymaz, H. Uslu Tecimer, Ş Altındal, On the Multi-Parallel Diodes Model in Au/PVA/n-GaAs Schottky diodes and investigation of conduction mechanisms (CMs) in a temperature range of 80–360 K. J. Electron. Mater. 49, 7427–7434 (2020)
I. Jyothi, V. Janardhanam, V. Rajagopal Reddy, C.J. Choi, Modified electrical characteristics of Pt/n-type Ge Schottky diode with a pyronine-B interlayer. Superlattices Microstruct. 75, 806–817 (2014)
S. Demirezen, Å. Altındal, Y. Azizian-Kalandaragh, A.M. Akbaş, A comparison of Au/n-Si Schottky diodes (SDs) with/without a nanographite (NG) interfacial layer by considering interlayer, surface states (Nss) and series resistance (rs) effects. Phys. Scr. 97, 055811 (2022)
A. Tataroğlu, Å. Altındal, Y. Azizian-Kalandaragh, Electrical characterization of Au/n-Si (MS) diode with and without graphene-polyvinylpyrrolidone (Gr-PVP) interface layer. J. Mater. Sci. 32, 3451–3459 (2021)
M. Gökçen, T. Tunç, Å.A.Ä.Ä. Uslu, Electrical and photocurrent characteristics of Au/PVA (Co-doped)/n-Si photoconductive diodes. Mater. Sci. Eng. 177, 416–420 (2012)
O. Çiçek, H. Uslu Tecimer, S.O. Tan, H. Tecimer, Ş Altındal, İ Uslu, Evaluation of electrical and photovoltaic behaviors as comparative of Au/n-GaAs (MS) diodes with and without pure and graphene (Gr)-doped polyvinyl alcohol (PVA) interfacial layer under dark and illuminated conditions. Compos. Part B 98, 260–268 (2016)
E.H. Nicollian, J.R. Brews, MOS (metal oxide semiconductor) physics and technology (Wiley, New York, 1982)
S.K. Cheung, N.W. Cheung, Extraction of Schottky diode parameters from forward current–voltage characteristics. Appl. Phys. Lett. 49, 85 (1998)
K. Sreenu, C. Venkata Prasad, V.R. Reddy, Barrier parameters and current transport characteristics of Ti/p-InP Schottky junction modified using orange G (OG) organic interlayer. J. Electron. Mater. 46, 5746–5754 (2017)
E. Erbilen Tanrıkulu, Variation of electrical and dielectric characteristics of Schottky diodes (SDs) depending on the existence of PVC and carbon-nanotube (CNT)-doped PVC interlayers. J. Mater. Sci. 34, 63 (2023)
M. Kırkbınar, E. İbrahimoğlu, A. Demir, F. Çalışkan, Å. Altındal, Improvement of electric and photoelectric properties of the Al/n-ZnO/p-Si/Al photodiodes by green synthesis method using chamomille flower extract. J. Mater. Sci. 34, 242 (2023)
M. Kırkbınar, A. Demir, Å. Altındal, F. Çalışkan, The effect of different rates of ultra-thin gossamer-like rGO coatings on photocatalytic performance in ZnO core-shell structures for optoelectronic applications. Diam. Relat. Mater. 130, 109435 (2022)
S. Altındal Yerişkin, E. Erbilen Tanrıkulu, M. Ulusoy, Dielectric properties of MS diodes with ag: ZnO doped PVP interfacial layer depending on voltage and frequency. Mater. Chem. Phys. 303, 127788 (2023)
M. Pavani, A. Ashok Kumar, V. Rajagopal Reddy, V. Janardhanam, C.-J. Choi, Current–voltage (I–V) characteristics of Au/n-Ge heterostructure based on cobalt phthalocyanine (CoPc) interlayer. Mater. Today (2023). https://doi.org/10.1016/j.matpr.2023.02.097
E. Yükseltürk, O. Surucu, M. Terlemezoğlu, M. Parlak, Å. Altındal, Illumination and voltage effects on the forward and reverse bias current–voltage (I-V) characteristics in In/In2S3/p-Si photodiodes. J. Mater. Sci. 32, 21825–21836 (2021)
C. Ben Alaya, B. Dridi Rezgui, F. Chaabouni, B. Khalfallah, S. Aouida, M. Bouaïcha, Correlation of 2D-interface defect density and electrical parameters of a GZO/p-Si heterojunctions: application to three surface morphologies. J. Mater. Sci. 34, 289 (2023)
A. Eroğlu, S. Demirezen, Y. Azizian-Kalandaragh, Å. Altındal, A comparative study on the electrical properties and conduction mechanisms of Au/n-Si Schottky diodes with/without an organic interlayer. J. Mater. Sci. 31, 14466–14477 (2020)
A. Büyükbaş-Uluşan, S. Altındal-Yerişkin, A. Tataroğlu, Forward and reverse bias current–voltage (I–V) characteristics in the metal–ferroelectric–semiconductor (Au/SrTiO3/n-Si) structures at room temperature. J. Mater. Sci. 29, 16740–16746 (2018)
E. Erbilen Tanrıkulu, Investigation of photon-induced effects on some diode parameters and negative capacitance of the Schottky structure with Zn-doped organic polymer (PVA) interface. Phys. Scr. 98, 015804 (2023)
A. Türüt, M. Coșkun, F.M. Coșkun, O. Polat, Z. Durmuș, M. Çağlar, H. Efeoğlu, The current-voltage characteristics of the ferroelectric p-YMnO3 thin film/bulk p-Si heterojunction over a broad measurement temperature range. J. Alloys Compd. 782, 566–575 (2019)
Å. Altındal, A.F. Özdemir, Å. Aydoğan, A. Türüt, Discrepancies in barrier heights obtained from current–voltage (IV) and capacitance–voltage (CV) of Au/PNoMPhPPy/n-GaAs structures in wide range of temperature. J. Mater. Sci. 33, 12210–12223 (2022)
E. Erbilen Tanrıkulu, Ä. Taşçıoğlu, Variation of the surface states and series resistance depending on voltage, and their effects on the electrical features of a Schottky structure with CdZnO interface. J. Electron. Mater. 52, 2432–2440 (2023)
D. Ata, S. Altındal Yeriskin, A. Tataroğlu, M. Balbasi, Analysis of admittance measurements of Al/Gr-PVA/p-Si (MPS) structure. J. Phys. Chem. Solids 169, 110861 (2022)
Ş Karataş, Comparison of electrical parameters of Zn/p-Si and Sn/p-Si Schottky barrier diodes. Solid State Commun. 135, 500–504 (2005)
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The Scientific and Technological Research Council of TURKIYE (TUBITAK) supports this work with the research project number-121C396.
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All authors contributed approximately the same to the preparation of the samples and them interpretation and writing. ÇŞG Manufacturing, investigation, measurements, calculations, writing, reviewing & editing. EET Investigation, calculations, writing, reviewing & editing. AD Measurements & calculations. ŞA Review, editing & supervising. YAK Manufacturing, investigation & measurements.
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Güçlü, Ç., Tanrıkulu, E.E., Dere, A. et al. A comparison of electrical characteristics of the Au/n-Si Schottky diodes with (ZnCdS:GO(1:1) and (ZnCdS:GO(1:0.5) doped PVP interlayer using current–voltage (I–V) and impedance–voltage (Z–V) measurements. J Mater Sci: Mater Electron 34, 1909 (2023). https://doi.org/10.1007/s10854-023-11302-z
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DOI: https://doi.org/10.1007/s10854-023-11302-z