Abstract
Copper zinc tin sulfide solar cell (CZTS), Cu2ZnSnS4-based solar cells have shown promising conversion efficiency because of their ease of variation in configurations. In this work, the architecture of a ZnO–Al/i–ZnO/n–CdS/CZTS/Mo solar cell was optimized by using Silvaco Atlas simulation software. In this simulation study, the thickness and defect density of the CZTS layer has been varied to achieve the highest efficiency of 26.58%, with Isc = 36.64 A and Voc = 0.909 V at a defect density of 1.8 × 1012 cm−3. Increase in the layer thickness of CZTS improves the photon absorption and cell efficiency. This study has evidenced the impact of defect density on the absorber layer, including photo-generation rate, recombination rate, and solar cell efficiency. By optimizing the device parameters, it has achieved a fill factor of 79.74% under AM 1.5 illumination, demonstrating the potential for low-cost, highly efficient CZTS solar cells.
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Acknowledgements
This work was supported by the Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic of Korea (No.20204010600470). This research was supported by research funds of Jeonbuk National University in 2023. The authors are thankful to the Deanship of Scientific Research at Najran University, Najran, Kingdom of Saudi Arabia for funding under the Research Group funding program Grant No. NU/RG/SERC/12/49.
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This work is the collaborative development of all the authors. DKC: original draft, software, conceptualization. DKS: editing-draft, methodology, revision. SK: investigation, formal analysis. NB: data curation, investigation, validation. DRA: data curation, resources. KBK: software. AU: investigation, data curation, editing-draft, writing-review, and editing. AI, MAMA: data curation. MSA, SB: writing-review and editing. OBA: funding acquisition, writing review, supervision, and editing. All authors have read and agreed to the published version of the manuscript.
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Devendra, K.C., Shah, D.K., Kumar, S. et al. Enhanced solar cell efficiency: copper zinc tin sulfide absorber thickness and defect density analysis. J Mater Sci: Mater Electron 34, 1699 (2023). https://doi.org/10.1007/s10854-023-11125-y
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DOI: https://doi.org/10.1007/s10854-023-11125-y