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Growth and characterization of organic 2,2′,4,4′-tetrahydroxybenzophenone single crystals for nonlinear optical applications

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Abstract

The organic 2,2′,4,4′-tetrahydroxybenzophenone single crystal was grown by slow evaporation solution growth technique. The single crystal X-ray diffraction studies show that the grown 2,2′,4,4′-tetrahydroxybenzophenone crystal belongs to the monoclinic crystal system with the centrosymmetric space group of C2/c. The grown crystals’ functional groups have been identified by the FTIR and FT-Raman spectral studies. The UV–Visible studies show that the cut-off wavelength was observed around 401 nm and the grown crystal has good transmittance in the visible regions. The optical parameters such as optical band gap (Eg), extinction coefficient (K), Urbach energy (EU), and skin depth (δ) were calculated. The TG/DTA analyses were used to find the thermal stability of the grown crystal. The dielectric properties of the grown 2,2′,4,4′-tetrahydroxybenzophenone single crystal were analyzed by using the parallel plate capacitor method. The nonlinear optical properties of the grown 2,2′,4,4′-tetrahydroxybenzophenone crystal was measured using the Z-scan technique. The grown 2,2′,4,4′-tetrahydroxybenzophenone single crystals optical limiting threshold values were analyzed.

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Acknowledgements

This work was supported by the University Grants Commission (UGC), South Eastern Regional Office (SERO), Government of India, under the grant of Minor Research Project UGC Reference No: F. MRP-7005/16 (SERO/UGC) Link No: 7005, is hereby gratefully acknowledged.

Funding

This study was funded by University Grants Commission—South Eastern Regional Office, 7005/16, T. Suthan.

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Authors and Affiliations

  1. Department of Physics & Research Centre, S.T. Hindu College, Nagercoil, 629002, India

    M. L. Lima Rose & C. Gnanasambandam

  2. Department of Physics, Malankara Catholic College, Mariagiri, 629153, India

    M. L. Lima Rose

  3. Department of Physics, Lekshmipuram College of Arts and Science, Neyyoor, Tamil Nadu, 629802, India

    T. Suthan & S. Goma

  4. Nanophotonics Laboratory, School of Physics, Bharathidasan University, Tiruchirappalli, 620024, India

    T. C. Sabari Girisun

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  1. M. L. Lima Rose
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All authors contributed to the study’s conception and design. Material preparation, data collection, and analysis were performed by all authors. All authors read and approved the final manuscript.

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Correspondence to T. Suthan.

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Lima Rose, M.L., Suthan, T., Goma, S. et al. Growth and characterization of organic 2,2′,4,4′-tetrahydroxybenzophenone single crystals for nonlinear optical applications. J Mater Sci: Mater Electron 34, 1679 (2023). https://doi.org/10.1007/s10854-023-11013-5

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