Skip to main content
SpringerLink
Log in

Structure, spectroscopic, optical, photoluminescence, and thermal characterization of 2-amino 3-picolinium arsenate crystalline material

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

By means of single-crystal X-ray diffraction analysis, vibrational, optical, photoluminescence, and thermal examination, a novel crystal of 2-amino-3-picolinium arsenate has been produced and described. The developed crystal crystallized in triclinic crystal system with centrosymmetric space group P-1 was confirmed by single-crystal XRD investigation. The lattice parameters are calculated as follows: a = 7.28 Å, b = 8.15 Å, c = 8.46 Å, α = 76.98°, β = 79.27°, γ = 88.30°, and volume of the unit cell V = 480.51 (Å)3. The 2-amino 3-picolinum cations and arsenate anions are present in the molecular structure, according to the FT-IR and FT-Raman spectrum studies. The hydrogen and carbon molecular environment are present in the chemical, according to the proton and carbon NMR spectrum. UV–Vis spectral and photoluminescence analysis have been performed to study optical characteristics of the grown crystal. DSC analysis was used to measure heat flow as a function of temperature. Crystal explorer software was used to calculate the Hirshfeld surface, and the 2D finger plot provides insight into the overall packing characteristics of the developed molecule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Data availability

Data sharing is not applicable to this article as no datasets were generated or analysed during the current study.

References

  1. G. Anandha Babu, P. Ramasamy, Growth and characterization of 2-amino-4-picolinium toluene sulfonate single crystal. Spectrochim. Acta A Mol. Biomol. Spectrosc. 82, 521–526 (2011)

    Article  CAS  Google Scholar 

  2. G. Peramaiyan, P. Pandi, B.M. Sornamurthy, G. Bhagavannarayana, R. Mohan Kumar, Growth, structural, thermal, linear and nonlinear optical and laser damage threshold studies of picolinium tartrate monohydrate single crystals. Spectrochim. Acta A Mol. Biomol. Spectrosc. 95, 310–316 (2012)

    Article  CAS  Google Scholar 

  3. P. Pandi, G. Peramaiyan, S. Sudhahar, G. Chakkaravarthi, R. Mohan Kumar, G. Bhagavannarayana, R. Jayavel, Studies on synthesis, growth, structural, thermal, linear and nonlinear optical properties of organic picolinium maleate single crystals. Spectrochim. Acta A Mol. Biomol. Spectrosc. 98, 7–13 (2012)

    Article  CAS  Google Scholar 

  4. L. Wang, Y. Fang, UV-Raman study and theoretical analogue of picolinic acid in aqueous solution. J. Mol. Spectrosc. 234, 137–142 (2005)

    Article  CAS  Google Scholar 

  5. S. Muralidharan, P. Nagapandiselvi, T. Srinivasan, Y. Vidyalakshmi, D. Velmurugan, R. Gopalakrishnan, Single crystal structure and characterization of 2-Amino-4 methylpyridinium-4-nitrophenolate-4-nitrophenol. Asian J. Chem. 25, 10107–10112 (2013)

    Article  CAS  Google Scholar 

  6. I. Bryndal, E. Kucharska, W. Sąsiadek, M. Wandas, T. Lis, J. Lorenc, J. Hanuza, Molecular and crystal structures, vibrational studies and quantum chemical calculations of 3 and 5-nitroderivatives of 2-amino-4-methylpyridine. Spectrochim. Acta A 96, 952–962 (2012)

    Article  CAS  Google Scholar 

  7. G.N. Sundaraganesan, C. Meganathan, M. Kurt, Molecular structure and vibrational spectra of 2-amino-5-methyl pyridine and 2-amino-6-methyl pyridine by density functional methods. J. Mol. Struc. 891, 284–291 (2008)

    Article  CAS  Google Scholar 

  8. D. Xue, H. Ratajczak, Effect of hydrogen bonds on physical properties of ammonium dihydrogenphosphate crystals. J. Mol. Struc. Theochem. 716, 207–210 (2005)

    Article  CAS  Google Scholar 

  9. A. A.Oueslati, C. Rayes, F. Ben Nasr, Lefebvre, Synthesis and characterization of 2-amino-3-methylpyridinium dihydrogenomonoarsenate. Mater. Res. Bullet. 40, 1680–1689 (2005)

    Article  Google Scholar 

  10. Z.M. Jin, Y.J. Pan, M.L. Hu, S. Liang, Crystal structure of 2-amino-3-methylpyridinium ortho-phthalate. J. Chem. Crystallogr. 31, 191–195 (2001)

    Article  CAS  Google Scholar 

  11. A.S. Albrecht, C.P. Landee, M.M. Turnbull, Structure of bis (2-amino-5-methylpyridinium) tetrachlorozincate at 298 and 150 K. J. Chem. Crystallogr. 33, 269–276 (2003)

    Article  CAS  Google Scholar 

  12. R.M. Silverstein, G.C. Bassler, T.C. Morill, Spectrometric Identification of Organic Compounds, 3rd edn. (Wiley, New York, 1974)

    Google Scholar 

  13. G. Socrates, Infrared and Raman Characteristic Group Frequencies, 3rd edn. (Wiley, New York, 2001)

    Google Scholar 

  14. Celal, Bayrak, Vibrational spectroscopic investigation of 2-amino-4-methylpyrimidine tetracyanonickelate complexes. Hacettepe J. Biol. Chem. 41, 133–141 (2013)

    Google Scholar 

  15. H.A. Szymanski, L. Marabella, J. Hoke, J. Harter, Infrared and Raman studies of arsenic compounds. Appl. Spectrosc. 22, 297–304 (1968)

    Article  CAS  Google Scholar 

  16. F.K. Vansant, B.J. Van Der Veken, H.O. Desseyn, Vibrational analysis of arsenic acid and its anions: I. description of the Raman spectra. J. Mol. Struct. 15, 425–437 (1973)

    Article  CAS  Google Scholar 

  17. P. Sujin, S. Jose, Mohan, Vibrational spectra and normal co-ordinate analysis of 2-aminopyridine and 2-amino picoline. Spectrochim. Acta A Mol. Biomol. Spectrosc. 64, 240–245 (2006)

    Article  Google Scholar 

  18. M.K. Elmkaddem, C. Fischmeister, C.M. Thomas, J.-L. Renaud, Efficient synthesis of amino-pyridine derivatives by copper catalyzed amination reactions. Chem. Commun. 46, 925–927 (2010)

    Article  CAS  Google Scholar 

  19. J. Yin, B. Xiang, A. General, Efficient 2-amination of pyridines and quinolines. J. Org. Chem. 72, 4554–4557 (2007)

    Article  CAS  Google Scholar 

  20. N. Kanagathara, M.K. Marchewka, G. Anbalagan, A. Ben Ahmed, H. Feki, Molecular structure, vibrational spectra and first order hyperpolarizability of anilinium L-tartrate monohydrate (ALTM). J. Optoelectron. Adv. Mater. 19, 251–265 (2017)

    CAS  Google Scholar 

  21. N. Sivakumar, J. Srividya, J. Mohana, G. Anbalagan, Growth, crystalline perfection, spectral and optical characterization of a novel optical material: l-tryptophan p-nitrophenol trisolvate single crystal. Spectrochim. Acta A Mol. Biomol. Spectrosc. 139, 156–164 (2015)

    Article  CAS  Google Scholar 

  22. V. Krishnakumar, L. Guru Prasad, R. Nagalakshmi, Investigation on 3-aminophenol: a nonlinear optical crystal for frequency doubling. Eur. Phys. J. Appl. Phys. 48, 20403–20409 (2009)

    Article  Google Scholar 

  23. N. Sivakumar, V. Jayaramakrishnan, K. Baskar, G. Anbalagan, Synthesis, growth and characterization of γ-glycine—a promising material for optical applications. Opt. Mater. 37, 780–787 (2014)

    Article  CAS  Google Scholar 

  24. G. Shanmugam, S. Brahadeeswaran, Spectroscopic, thermal and mechanical studies on 4-methylanilinium p-toluenesulfonate—a new organic NLO single crystal. Spectrochim. Acta A Mol. Biomol. Spectrosc. 95, 177–183 (2012)

    Article  CAS  Google Scholar 

  25. S. Sudhahar, M. KrishnaKumar, A. Silambarasan, R. Muralidharan, R. Mohan Kumar, Studies on structural spectral and optical properties of organic nonlinear optical single crystal: 2-amino 46-dimethylpyrimidinium p-hydroxybenzoate. J. Mater. 2013, 1 (2013)

    Google Scholar 

  26. S. Kalaiyarasi, S. Suresh, R. Mohan Kumar, Studies on the growth, thermal and optical properties of p-methyl anilinium malate single crystal. Mech. Mater. Sci. Eng. 9, 1–7 (2017)

    Google Scholar 

  27. K. Saiadali Fathima, P. Kavitha, K. Anitha, Synthesis, crystal growth and characterization of bioactive material: 2-Amino-1H-benzimidazolium pyridine-3-carboxylate single crystal- a proton transfer molecular complex. J. Mol. Struct. 1143, 444–451 (2017)

    Article  Google Scholar 

  28. R. Bhavani, N. Kanagathara, M.K. Marchewk, J. Janczak, Structural and spectroscopic characterization of the products formed in aqueous solution of hydrazine and maleic acid. J. Mol. Struct. 1271, 134077 (2023)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The Researchers Supporting Project (RSP-2023R78), King Saud University, Riyadh, Saudi Arabia, is gratefully acknowledged by the authors.

Funding

This work was partly supported by King Saud University, Riyadh, Saudi Arabia under Researchers Supporting Project (RSP-2023R78) is gratefully acknowledged by the authors. Author N. Sivakumar has received research support.

Author information

Authors and Affiliations

  1. Department of Physics, Saveetha School of Engineering, SIMATS, Thandalam, Chennai, 602105, India

    N. Kanagathara

  2. Functional Materials Research Laboratory (FMRL), Department of Physics, Sri Sai Ram Engineering College, West Tambaram, Chennai, 600044, India

    N. Sivakumar

  3. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 937, 50-950, Wrocław, Poland

    M. K. Marchewka & J. Janczak

  4. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia

    Ali Alsulmi

  5. Department of Physical Chemistry, School of Chemical Sciences, University of Madras, Guindy Campus, Chennai, 600025, India

    V. Yogaraj & E. Murugan

Authors
  1. N. Kanagathara
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. Sivakumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. K. Marchewka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Janczak
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ali Alsulmi
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. Yogaraj
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. E. Murugan
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by NS. The first draft of the manuscript was written by NK and all the other authors commented on previous versions of the manuscript. Finally it was validated by NS. All authors read and approved the final manuscript.

Corresponding author

Correspondence to N. Sivakumar.

Ethics declarations

Competing Interests

The authors N. Kanagathara, M.K. Marchewka, J. Janczak, Ali Alsulmi, V. Yogaraj, and E. Murugan declare that they have no financial interests. Author N. Sivakumar has received research support from King Saud University, Riyadh, Saudi Arabia under Researchers Supporting Project (RSP-2023R78) scheme.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kanagathara, N., Sivakumar, N., Marchewka, M.K. et al. Structure, spectroscopic, optical, photoluminescence, and thermal characterization of 2-amino 3-picolinium arsenate crystalline material. J Mater Sci: Mater Electron 34, 1573 (2023). https://doi.org/10.1007/s10854-023-10974-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-023-10974-x

Search

Navigation