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Porous CoNi2O4 petal-like structures derived from bimetallic Co,Ni-MOF for energy storage aims

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Abstract

In this paper, C-NiCo2O4 petal-like active material is prepared by post-calcination of Ni,Co-based metal–organic-framework (Ni,Co-MOF) electrodeposited onto Ni-foam (NF). The as-prepared Ni,Co-MOF and C-NiCo2O4 electrodes are characterized by various techniques such as X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry, Field emission scanning electron microscope, and Energy dispersive X-ray spectroscopy. The electrochemical performances of the pristine Ni,Co-MOF and C-NiCo2O4 electrodes are evaluated by cyclic voltammetry, galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy tests. The CV and GCD results proved that the synthesized C-NiCo2O4/NF electrode represents superior storage capability as compared to pristine Ni,Co-MOF/NF electrode. The specific capacity of C-NiCo2O4/NF was 825 C g−1 at the discharge current of 1 A g−1 and 63.6% capacity retention was observed at the high current density of 20 A g−1. The specific capacity of C-NiCo2O4/NF remained 86.3% of its initial value after 7000 cycling at 5 A g−1. The carbon-coated NiCo2O4 porous petals are promising electrode material for energy storage/conversion devices with excellent performance.

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

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Authors and Affiliations

  1. Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute (NSTRI), Tehran, Iran

    Mustafa Aghazadeh, Hamzeh Foratirad & Mohamad Afkhami Ardakani

  2. Department of Physics, Faculty of Science, Central Tehran Branch, Islamic Azad University, Tehran, Iran

    Isa Karimzadeh

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  1. Mustafa Aghazadeh
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  2. Hamzeh Foratirad
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  3. Isa Karimzadeh
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  4. Mohamad Afkhami Ardakani
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Contributions

Conceptualization: MA; Methodology: MA and IK; Formal analysis and investigation: IK, HF; Writing—original draft preparation: HF and MAA; Writing—review and editing: MA; Funding acquisition: HF and IK, Resources: HF and MAA; Supervision: MA.

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Correspondence to Mustafa Aghazadeh.

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Aghazadeh, M., Foratirad, H., Karimzadeh, I. et al. Porous CoNi2O4 petal-like structures derived from bimetallic Co,Ni-MOF for energy storage aims. J Mater Sci: Mater Electron 34, 1465 (2023). https://doi.org/10.1007/s10854-023-10863-3

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