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Aminoterephthalic acid ligand terminated zirconium metal-organic framework/palladium nanoparticles composite for voltammetric determination of syringic acid in wine samples

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Abstract

In this study, we investigated the electrochemical determination of syringic acid using palladium nanoparticles dispersed zirconium metal-organic framework composite. Transmission electron microscopic images illustrated that the average diameter of < 10 nm spherical Pd nanoparticles was decorated on the surface of the metal-organic framework. Cyclic voltammetric analysis showed that the composite exhibited well-defined oxidation (0.61 eV) and reduction (0.48 eV) peaks toward the determination of syringic acid in 0.1 M phosphate buffer saline (pH 3). In addition, the composite electrode demonstrated higher currents than the bare glassy carbon electrode and pure metal-organic framework. The differential pulse voltammetric analysis showed that the composite electrode manifested a dynamic linear range of concentrations from 0.5 to 100 µM with a regression equation of I (µA) = 0.3217x + 5.8055 (R2 = 0.9981). The sensitivity and detection limit of the composite electrode were identified as 0.32 µA/µM and 0.17 µM, respectively. The composite electrode demonstrated good anti-interference properties towards benzoic acid, routine, caffeic acid, sinapic acid, and KCl. The composite electrode was used to determine the syringic acid level in wine samples with good recoveries (99 to 103%), indicating its feasibility for practical applications in the pharmaceutical sector.

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Acknowledgements

This study was supported by the Department of Biotechnology, Ministry of Science and Technology, Government of India, under the Ramalingasami Fellowship Scheme (BT/RLF/Re-entry/48/2015). This study was also supported by the Researchers Supporting Project number (RSP2023R142), King Saud University, Riyadh, Saudi Arabia.

Funding

Funding was provided by Department of Biotechnology, Ministry of Science and Technology, India. King Saud University also provided the funding.

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Authors and Affiliations

  1. Advanced Materials & Devices Laboratory (AMDL), Department of Nanoscience and Technology, Bharathiar University, Coimbatore, Tamil Nadu, 641046, India

    K. V. Kavya, Dhanaprabhu Pattappan, Stella Vargheese, R. T. Rajendra Kumar & Yuvaraj Haldorai

  2. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia

    Raju Suresh Kumar

  3. School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeonbuk, 38541, Republic of Korea

    Yuvaraj Haldorai

  4. Department of Mechanical, Robotics and Energy Engineering, Dongguk University, Pildong-ro 1 gil, Jung-gu, Seoul, 04620, Republic of Korea

    Sivalingam Ramesh

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  1. K. V. Kavya
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Contributions

Conceptualization: KVK, Methodology: SV, Formal analysis and investigation: SR, Writing—original draft preparation: KVK, DP, Writing—review and editing: RTRK, Funding acquisition: RSK, Resources, Supervision: YH.

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Correspondence to Yuvaraj Haldorai.

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Kavya, K.V., Pattappan, D., Vargheese, S. et al. Aminoterephthalic acid ligand terminated zirconium metal-organic framework/palladium nanoparticles composite for voltammetric determination of syringic acid in wine samples. J Mater Sci: Mater Electron 34, 1240 (2023). https://doi.org/10.1007/s10854-023-10697-z

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