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Preparation and electrochemical properties of mesoporous α-Fe2O3 nanowires for supercapacitor application

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Abstract

Mesoporous α-Fe2O3 nanowires have been prepared through solid-state thermal conversion of ferrous oxalate dihydrate precursor for supercapacitor application. The possible growth mechanism of the FeC2O4·2H2O nanowires was proposed based on a series of time-dependent experiments. The specific surface area and pore size distribution of the mesoporous α-Fe2O3 nanowires were calculated to be about 70.6 m2 g−1 and 2.5 nm, respectively. Furthermore, electrochemical measurements demonstrate that the as-prepared mesoporous α-Fe2O3 nanowire electrode delivers a high specific capacitance up to 267.5 F g−1 at 2 A g−1 and good cycle performance (87% capacitance retention under 2000 cycles). The excellent supercapacitor performance of the α-Fe2O3 nanowires can be ascribed mainly to the unique mesoporous structure with large specific surface area, which provide fast electron/ion transfer path as well as large reaction surface area.

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The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Funding

This work was supported by the Science and Technology Research Program of Chongqing Municipal Education Commission (Grant Nos. HZ2021013, KJQN202001341, KJQN202001304, and KJZD-K202001305) and the Natural Science Foundation of Chongqing (cstc2019jcyj-msxmX0670 and cstc2020jcyj-msxmX0103).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing, 402160, People’s Republic of China

    Huijie Wu & Wei Xiao

  2. School of Materials and Energy, Southwest University, Chongqing, 400715, People’s Republic of China

    Yuan Li

  3. School of Electronic Information and Electrical Engineering, Chongqing University of Arts and Sciences, Chongqing, 402160, People’s Republic of China

    Liangliang Tian

  4. Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Jing Song

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HW participated in the investigation, data curation, and writing of the original draft, YL participated in the conceptualization, writing, reviewing, & editing of the manuscript, and supervision. WX participated in the investigation. LT participated in the methodology. JS participated in the validation.

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Correspondence to Yuan Li.

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Wu, H., Li, Y., Xiao, W. et al. Preparation and electrochemical properties of mesoporous α-Fe2O3 nanowires for supercapacitor application. J Mater Sci: Mater Electron 34, 1098 (2023). https://doi.org/10.1007/s10854-023-10456-0

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