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Effect of annealing time on the microstructure, crystal quality and optoelectronic properties of Er-Ga2O3 films

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Abstract

The post-annealing process is an effective method to improve the properties of gallium oxide (Ga2O3) single crystal films. However, the studies on post-annealing of Ga2O3 films have been largely limited to the annealing temperature, with few reports of the annealing time. Here, we show the effect of annealing time on the Er-doped β-Ga2O3 (−201) epitaxial films deposited by pulsed laser deposition. The Ga2O3 film with a bandgap of ~ 4.98 eV and annealed at 900 °C for 15 min, exhibits the best crystal quality and optical property in comparison with the films before and after the annealing for 7 and 30 min in air. The epitaxial relationship between the film and substrate is Ga2O3 [010] ∥ GaN [−12−10] with Ga2O3 (−201) ∥ GaN (0001). Moreover, the resistivity of the 15 min-annealed Ga2O3 film, which is about 180 Ω·cm, still maintains a low level.

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References

  1. C. Zhou, Q. Ai, X. Chen, X. Gao, K. Liu, D. Shen, Chin. Phys. B 28, 048503 (2019)

    Article  CAS  Google Scholar 

  2. M. Hegde, I.D. Hosein, P.V. Radovanovic, J. Phys. Chem. C 119, 17450–17457 (2015)

    Article  CAS  Google Scholar 

  3. T. Miyata, T. Nakatani, T. Minami, J. Lumin. 87, 1183–1185 (2000)

    Article  Google Scholar 

  4. J. Hao, Z. Lou, I. Renaud, M. Cocivera, Thin Solid Films 467, 182–185 (2004)

    Article  CAS  Google Scholar 

  5. Y. Liu, L. Du, G. Liang, W. Mu, Z. Jia, M. Xu, Q. Xin, X. Tao, A. Song, IEEE Electron. Dev. Lett. 39, 1696–1699 (2018)

    Article  CAS  Google Scholar 

  6. S. Yu, G. Zhang, D. Carloni, Y. Wu, Ceram. Int. 46, 21757–21761 (2020)

    Article  CAS  Google Scholar 

  7. Y. Lv, J. Ma, W. Mi, C. Luan, Z. Zhu, H. Xiao, Vacuum 86, 1850–1854 (2012)

    Article  CAS  Google Scholar 

  8. X. Yang, X. Du, L. He, D. Wang, C. Zhao, J. Liu, J. Ma, H. Xiao, J. Mater. Sci. 55, 8231–8240 (2020)

    Article  CAS  Google Scholar 

  9. P. Wellenius, A. Suresh, J.V. Foreman, H.O. Everitt, J.M. Muth, Mat. Sci. Eng. B-Adv. 146, 252–255 (2008)

    Article  CAS  Google Scholar 

  10. Z. Chen, X. Wang, F. Zhang, S. Noda, K. Saito, T. Tanaka, M. Nishio, M. Arita, Q. Guo, Appl. Phys. Lett. 109, 022107 (2016)

    Article  Google Scholar 

  11. Z. Chen, D. Guo, P. Li, Z. Chen, W. Tang, Q. Guo, Appl. Phys. Exp. 12, 061009 (2019)

    Article  CAS  Google Scholar 

  12. W. Guo, J. Tai, J. Liu, J. Sun, J. Electron. Mater. 48, 5195–5201 (2019)

    Article  CAS  Google Scholar 

  13. G. Zhang, X. Guo, F. Ren, Y. Li, B. Liu, J. Ye, H. Ge, Z. Xie, R. Zhang, H. Tan, C. Jagadish, ACS Photonics 3, 1912–1918 (2016)

    Article  CAS  Google Scholar 

  14. X. Yang, X. Du, J. Liu, R. Chen, D. Wang, Y. Le, H. Zhu, B. Feng, J. Ma, H. Xiao, Ceram. Int. 47, 9597–9605 (2021)

    Article  CAS  Google Scholar 

  15. S.R. Yousefi, M. Masjedi-Arani, M.S. Morassaei, M. Salavati-Niasari, H. Moayedi, Int. J. Hydrogen Energy 44, 24005–24016 (2019)

    Article  CAS  Google Scholar 

  16. S.R. Yousefi, O. Amiri, M. Salavati-Niasari, Ultrason. Sonochem 58, 104619 (2019)

    Article  CAS  Google Scholar 

  17. S.R. Yousefi, H.A. Alshamsi, O. Amiri, M. Salavati-Niasari, J. Mol. Liq. 337, 116405 (2021)

    Article  CAS  Google Scholar 

  18. M.A. Mahdi, S.R. Yousefi, L.S. Jasim, M. Salavati-Niasari, Int. J. Hydrogen Energy 47, 14319–14330 (2022)

    Article  CAS  Google Scholar 

  19. S.R. Yousefi, A. Sobhani, M. Salavati-Niasari, Adv. Powder Technol. 28, 1258–1262 (2017)

    Article  CAS  Google Scholar 

  20. S.R. Yousefi, D. Ghanbari, M. Salavati-Niasari, J. Nanostruct. 6, 77–82 (2016)

    Google Scholar 

  21. S.R. Yousefi, M. Ghanbari, OAmiriZ. Marzhoseyni, P. Mehdizadeh, M. Hajizadeh-Oghaz, M. Salavati-Niasari, J. Am. Ceram. Soc. 104, 2952–2965 (2021)

    Article  CAS  Google Scholar 

  22. S.R. Yousefi, A. Sobhani, H.A. Alshamsic, M. Salavati-Niasari, RSC Adv. 11, 11500 (2021)

    Article  CAS  Google Scholar 

  23. C. Zhao, X. Yang, B. Wei, J. Liu, R. Chen, C. Luan, H. Xiao, Vacuum 182, 109669 (2020)

    Article  CAS  Google Scholar 

  24. Y. Le, X. Ma, D. Wang, H. Xiao, C. Luan, B. Zhang, J. Ma, Ceram. Int. 48, 26800–26805 (2022)

    Article  CAS  Google Scholar 

  25. D. Wang, L. He, Y. Le, X. Feng, C. Luan, H. Xiao, J. Ma, Ceram. Int. 46, 4568–4572 (2022)

    Article  Google Scholar 

  26. D.D. Hile, H.C. Swart, S.V. Motloung, R.E. Kroon, K.O. Egbo, L.F. Koao, J. Phys. Chem. Sol. 140, 10938 (2020)

    Article  Google Scholar 

  27. B. Zhang, C. Luan, D. Wang, H. Xiao, X. Feng, Y. Le, J. Ma, Ceram. Int. 48, 4312–4317 (2022)

    Article  CAS  Google Scholar 

  28. Y. Le, C. Luan, D. Wang, B. Zhang, H. Xiao, J. Ma, Mater. Lett. 302, 130395 (2021)

    Article  CAS  Google Scholar 

  29. S. Kumari, S. Chuhadiya, D. Suthar, M.D. Himanshu, N. Kannan, M.S. Kumari, Dhaka, J. Mater. Sci. 57, 19466–19489 (2022)

    Article  CAS  Google Scholar 

  30. D. Suthar, S.L. Himanshu, S. Patel, M.D. Chander, M.S. Kannan, Dhaka, J. Mater. Sci.: Mater. Electron. 32, 19070–19082 (2021)

    CAS  Google Scholar 

  31. G. Chasta, S.L. Himanshu, S. Patel, M.D. Chander, M.S. Kannan, Dhaka, J. Mater. Sci.: Mater. Electron. 33, 139–157 (2022)

    CAS  Google Scholar 

  32. L. He, C. Luan, X. Feng, H. Xiao, X. Yang, D. Wang, J. Ma, Mater. Res. Bull. 118, 110488 (2019)

    Article  CAS  Google Scholar 

  33. Y. Kajita, H. Nishinaka, M. Yoshimoto, CrystEngComm 24, 3239–3245 (2022)

    Article  CAS  Google Scholar 

  34. G. Greczynski, L. Hultman, Sci. Rep. 11, 11195 (2021)

    Article  CAS  Google Scholar 

  35. M. Yadav, A. Mondal, S. Das, S. Sharma, A. Bag, J. Alloy Compd. 819, 153052 (2020)

    Article  CAS  Google Scholar 

  36. A. Petitmangin, B. Gallas, C. Hebert, J. Perrière, L. Binet, P. Barboux, X. Portier, Appl. Surf. Sci. 278, 153–157 (2013)

    Article  CAS  Google Scholar 

  37. M. Tadjer, M. Mastro, N. Mahadik, M. Currie, V. Wheeler, J. Freitas, J. Greenlee, J. Hite, K. Hobart, C. Eddy, F. Kub, J. Electron. Mater. 45, 2031–2037 (2016)

    Article  CAS  Google Scholar 

  38. W. Mi, J. Ma, C. Luan, Y. Lv, H. Xiao, Z. Li, Mater. Lett. 87, 109–112 (2012)

    Article  CAS  Google Scholar 

  39. H. Yang, Y. Qian, C. Zhang, D.-S. Wuu, D.N. Talwar, H.-H. Lin, J.-F. Lee, L. Wan, K. He, Z. Feng, Appl. Surf. Sci. 479, 1246–1253 (2019)

    Article  CAS  Google Scholar 

  40. X. Liu, K. Li, X. Sun, Z. Shi, Z. Huang, Z. Li, L. Min, V. Botcha, X. Chen, X. Xu, D. Li, J. Alloy Compd. 793, 599–603 (2019)

    Article  CAS  Google Scholar 

  41. S. Khartsev, N. Nordell, M. Hammar, J. Purans, A. Hallén, Phys. Status Solidi B 258, 2000362 (2021)

    Article  CAS  Google Scholar 

  42. Y. An, L. Dai, Y. Wu, B. Wu, Y. Zhao, T. Liu, H. Hao, Z. Li, G. Niu, J. Zhang, Z. Quan, S. Ding, J. Adv. Dielect. 9, 1950032 (2019)

    Article  CAS  Google Scholar 

  43. J. Wang, Z. Wang, B. Huang, Y. Ma, Y. Liu, X. Qin, X. Zhang, Y. Dai, ACS Appl. Mater. Interfaces 4, 4024–4030 (2012)

    Article  CAS  Google Scholar 

  44. L. Dong, R. Jia, B. Xin, B. Peng, Y. Zhang, Sci. Rep. 7, 1–12 (2017)

    Article  Google Scholar 

  45. M. Yu, J. Lin, Z. Wang, J. Fu, S. Wang, H.J. Zhang, Y.C. Han, Chem. Mater. 14, 2224–2231 (2002)

    Article  CAS  Google Scholar 

  46. Z. Chen, K. Saito, T. Tanaka, Q. Guo, CrystEngComm 19, 4448–4458 (2017)

    Article  CAS  Google Scholar 

  47. L. Dong, R. Jia, C. Li, B. Xin, Y. Zhang, J. Alloy Compd. 712, 379–385 (2017)

    Article  CAS  Google Scholar 

  48. L. Dong, P. Li, Y. Zhao, Y. Miao, B. Peng, B. Xin, W. Liu, Appl. Surf. Sci. 602, 154382 (2022)

    Article  CAS  Google Scholar 

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Funding

This work is supported by the National Natural Science Foundation of China (61874067).

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Contributions

ZW: conceptualization, methodology, investigation, writing-original draft, data curation. ZZ: conceptualization, project administration, validation, writing - review & editing. XY: conceptualization, supervision, resources. JL: software, validation. HX: supervision, writing - review & editing, funding acquisition.

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Correspondence to Xiaokun Yang.

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Wang, Z., Zhang, Z., Yang, X. et al. Effect of annealing time on the microstructure, crystal quality and optoelectronic properties of Er-Ga2O3 films. J Mater Sci: Mater Electron 34, 897 (2023). https://doi.org/10.1007/s10854-023-10371-4

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