Abstract
The post-annealing process is an effective method to improve the properties of gallium oxide (Ga2O3) single crystal films. However, the studies on post-annealing of Ga2O3 films have been largely limited to the annealing temperature, with few reports of the annealing time. Here, we show the effect of annealing time on the Er-doped β-Ga2O3 (−201) epitaxial films deposited by pulsed laser deposition. The Ga2O3 film with a bandgap of ~ 4.98 eV and annealed at 900 °C for 15 min, exhibits the best crystal quality and optical property in comparison with the films before and after the annealing for 7 and 30 min in air. The epitaxial relationship between the film and substrate is Ga2O3 [010] ∥ GaN [−12−10] with Ga2O3 (−201) ∥ GaN (0001). Moreover, the resistivity of the 15 min-annealed Ga2O3 film, which is about 180 Ω·cm, still maintains a low level.
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References
C. Zhou, Q. Ai, X. Chen, X. Gao, K. Liu, D. Shen, Chin. Phys. B 28, 048503 (2019)
M. Hegde, I.D. Hosein, P.V. Radovanovic, J. Phys. Chem. C 119, 17450–17457 (2015)
T. Miyata, T. Nakatani, T. Minami, J. Lumin. 87, 1183–1185 (2000)
J. Hao, Z. Lou, I. Renaud, M. Cocivera, Thin Solid Films 467, 182–185 (2004)
Y. Liu, L. Du, G. Liang, W. Mu, Z. Jia, M. Xu, Q. Xin, X. Tao, A. Song, IEEE Electron. Dev. Lett. 39, 1696–1699 (2018)
S. Yu, G. Zhang, D. Carloni, Y. Wu, Ceram. Int. 46, 21757–21761 (2020)
Y. Lv, J. Ma, W. Mi, C. Luan, Z. Zhu, H. Xiao, Vacuum 86, 1850–1854 (2012)
X. Yang, X. Du, L. He, D. Wang, C. Zhao, J. Liu, J. Ma, H. Xiao, J. Mater. Sci. 55, 8231–8240 (2020)
P. Wellenius, A. Suresh, J.V. Foreman, H.O. Everitt, J.M. Muth, Mat. Sci. Eng. B-Adv. 146, 252–255 (2008)
Z. Chen, X. Wang, F. Zhang, S. Noda, K. Saito, T. Tanaka, M. Nishio, M. Arita, Q. Guo, Appl. Phys. Lett. 109, 022107 (2016)
Z. Chen, D. Guo, P. Li, Z. Chen, W. Tang, Q. Guo, Appl. Phys. Exp. 12, 061009 (2019)
W. Guo, J. Tai, J. Liu, J. Sun, J. Electron. Mater. 48, 5195–5201 (2019)
G. Zhang, X. Guo, F. Ren, Y. Li, B. Liu, J. Ye, H. Ge, Z. Xie, R. Zhang, H. Tan, C. Jagadish, ACS Photonics 3, 1912–1918 (2016)
X. Yang, X. Du, J. Liu, R. Chen, D. Wang, Y. Le, H. Zhu, B. Feng, J. Ma, H. Xiao, Ceram. Int. 47, 9597–9605 (2021)
S.R. Yousefi, M. Masjedi-Arani, M.S. Morassaei, M. Salavati-Niasari, H. Moayedi, Int. J. Hydrogen Energy 44, 24005–24016 (2019)
S.R. Yousefi, O. Amiri, M. Salavati-Niasari, Ultrason. Sonochem 58, 104619 (2019)
S.R. Yousefi, H.A. Alshamsi, O. Amiri, M. Salavati-Niasari, J. Mol. Liq. 337, 116405 (2021)
M.A. Mahdi, S.R. Yousefi, L.S. Jasim, M. Salavati-Niasari, Int. J. Hydrogen Energy 47, 14319–14330 (2022)
S.R. Yousefi, A. Sobhani, M. Salavati-Niasari, Adv. Powder Technol. 28, 1258–1262 (2017)
S.R. Yousefi, D. Ghanbari, M. Salavati-Niasari, J. Nanostruct. 6, 77–82 (2016)
S.R. Yousefi, M. Ghanbari, OAmiriZ. Marzhoseyni, P. Mehdizadeh, M. Hajizadeh-Oghaz, M. Salavati-Niasari, J. Am. Ceram. Soc. 104, 2952–2965 (2021)
S.R. Yousefi, A. Sobhani, H.A. Alshamsic, M. Salavati-Niasari, RSC Adv. 11, 11500 (2021)
C. Zhao, X. Yang, B. Wei, J. Liu, R. Chen, C. Luan, H. Xiao, Vacuum 182, 109669 (2020)
Y. Le, X. Ma, D. Wang, H. Xiao, C. Luan, B. Zhang, J. Ma, Ceram. Int. 48, 26800–26805 (2022)
D. Wang, L. He, Y. Le, X. Feng, C. Luan, H. Xiao, J. Ma, Ceram. Int. 46, 4568–4572 (2022)
D.D. Hile, H.C. Swart, S.V. Motloung, R.E. Kroon, K.O. Egbo, L.F. Koao, J. Phys. Chem. Sol. 140, 10938 (2020)
B. Zhang, C. Luan, D. Wang, H. Xiao, X. Feng, Y. Le, J. Ma, Ceram. Int. 48, 4312–4317 (2022)
Y. Le, C. Luan, D. Wang, B. Zhang, H. Xiao, J. Ma, Mater. Lett. 302, 130395 (2021)
S. Kumari, S. Chuhadiya, D. Suthar, M.D. Himanshu, N. Kannan, M.S. Kumari, Dhaka, J. Mater. Sci. 57, 19466–19489 (2022)
D. Suthar, S.L. Himanshu, S. Patel, M.D. Chander, M.S. Kannan, Dhaka, J. Mater. Sci.: Mater. Electron. 32, 19070–19082 (2021)
G. Chasta, S.L. Himanshu, S. Patel, M.D. Chander, M.S. Kannan, Dhaka, J. Mater. Sci.: Mater. Electron. 33, 139–157 (2022)
L. He, C. Luan, X. Feng, H. Xiao, X. Yang, D. Wang, J. Ma, Mater. Res. Bull. 118, 110488 (2019)
Y. Kajita, H. Nishinaka, M. Yoshimoto, CrystEngComm 24, 3239–3245 (2022)
G. Greczynski, L. Hultman, Sci. Rep. 11, 11195 (2021)
M. Yadav, A. Mondal, S. Das, S. Sharma, A. Bag, J. Alloy Compd. 819, 153052 (2020)
A. Petitmangin, B. Gallas, C. Hebert, J. Perrière, L. Binet, P. Barboux, X. Portier, Appl. Surf. Sci. 278, 153–157 (2013)
M. Tadjer, M. Mastro, N. Mahadik, M. Currie, V. Wheeler, J. Freitas, J. Greenlee, J. Hite, K. Hobart, C. Eddy, F. Kub, J. Electron. Mater. 45, 2031–2037 (2016)
W. Mi, J. Ma, C. Luan, Y. Lv, H. Xiao, Z. Li, Mater. Lett. 87, 109–112 (2012)
H. Yang, Y. Qian, C. Zhang, D.-S. Wuu, D.N. Talwar, H.-H. Lin, J.-F. Lee, L. Wan, K. He, Z. Feng, Appl. Surf. Sci. 479, 1246–1253 (2019)
X. Liu, K. Li, X. Sun, Z. Shi, Z. Huang, Z. Li, L. Min, V. Botcha, X. Chen, X. Xu, D. Li, J. Alloy Compd. 793, 599–603 (2019)
S. Khartsev, N. Nordell, M. Hammar, J. Purans, A. Hallén, Phys. Status Solidi B 258, 2000362 (2021)
Y. An, L. Dai, Y. Wu, B. Wu, Y. Zhao, T. Liu, H. Hao, Z. Li, G. Niu, J. Zhang, Z. Quan, S. Ding, J. Adv. Dielect. 9, 1950032 (2019)
J. Wang, Z. Wang, B. Huang, Y. Ma, Y. Liu, X. Qin, X. Zhang, Y. Dai, ACS Appl. Mater. Interfaces 4, 4024–4030 (2012)
L. Dong, R. Jia, B. Xin, B. Peng, Y. Zhang, Sci. Rep. 7, 1–12 (2017)
M. Yu, J. Lin, Z. Wang, J. Fu, S. Wang, H.J. Zhang, Y.C. Han, Chem. Mater. 14, 2224–2231 (2002)
Z. Chen, K. Saito, T. Tanaka, Q. Guo, CrystEngComm 19, 4448–4458 (2017)
L. Dong, R. Jia, C. Li, B. Xin, Y. Zhang, J. Alloy Compd. 712, 379–385 (2017)
L. Dong, P. Li, Y. Zhao, Y. Miao, B. Peng, B. Xin, W. Liu, Appl. Surf. Sci. 602, 154382 (2022)
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This work is supported by the National Natural Science Foundation of China (61874067).
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ZW: conceptualization, methodology, investigation, writing-original draft, data curation. ZZ: conceptualization, project administration, validation, writing - review & editing. XY: conceptualization, supervision, resources. JL: software, validation. HX: supervision, writing - review & editing, funding acquisition.
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Wang, Z., Zhang, Z., Yang, X. et al. Effect of annealing time on the microstructure, crystal quality and optoelectronic properties of Er-Ga2O3 films. J Mater Sci: Mater Electron 34, 897 (2023). https://doi.org/10.1007/s10854-023-10371-4
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DOI: https://doi.org/10.1007/s10854-023-10371-4