Skip to main content
Log in

Transparent conductivity in polycrystal bismuth thin films grown on glass by molecular beam epitaxy

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Bismuth (Bi) films were prepared using the molecular beam epitaxy (MBE) method and characterised using Raman spectroscopy, X-ray diffraction, ultraviolet-visible-near-infrared spectrophotometer, physical property measurement system and contact angle measurements. The experiment results demonstrated that Bi films with excellent transport characteristics were obtained via thickness adjustment. The Bi film exhibited excellent strong anisotropy at ~ 29 nm thickness. Meanwhile, the magnetoresistance (MR) was 20%, and the semimetal-semiconductor transition temperature was 54 K. The Bi film had satisfactory luminous transmittance, achieving a balance between light transmittance and electrical properties. Furthermore, the Bi film exhibits excellent hydrophobicity. This work suggests that Bi film become an excellent candidate for transparent conductive film materials and contact electrodes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data availability

The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. N. Marcano, S. Sangiao, C. Magén, L. Morellón, M.R. Ibarra, M. Plaza, L. Pérez, J.M. De Teresa, Role of the surface states in the magnetotransport properties of ultrathin bismuth films. Phys. Rev. B 82, 125326 (2010)

    Article  Google Scholar 

  2. T. Hirahara, T. Shirai, T. Hajiri, M. Matsunami, K. Tanaka, S. Kimura, S. Hasegawa, K. Kobayashi, Role of quantum and surface-state effects in the bulk Fermi-level position of ultrathin Bi films. Phys. Rev. Lett. 115, 106803 (2015)

    Article  CAS  Google Scholar 

  3. K. Zhu, L. Wu, X. Gong, S. Xiao, X. Jin, Quantum transport in the surface states of epitaxial Bi(111) thin films. Phys. Rev. B 94(12), 121401 (2016)

    Article  Google Scholar 

  4. P.J. de Visser, J. Levallois, M.K. Tran, J.-M. Poumirol, I.O. Nedoliuk, J. Teyssier, C. Uher, D. van der Marel, A.B. Kuzmenko, Suppressed magnetic circular dichroism and Valley-selective magnetoabsorption due to the effective mass anisotropy in bismuth. Phys. Rev. Lett. 117, 017402 (2016)

    Article  Google Scholar 

  5. D. Abdelbarey, J. Koch, P. Kröger, P. Yogi, C. Tegenkamp, H. Pfnür, Magnetoconductance in epitaxial bismuth quantum films: beyond weak (anti)localization. Phys. Rev. B 104, 075431 (2021)

    Article  CAS  Google Scholar 

  6. S. Sivaramakrishnan, V.S. Muthukumar, S. Sivasankara Sai, K. Venkataramanaiah, J. Reppert, A.M. Rao, M. Anija, R. Philip, N. Kuthirummal, Nonlinear optical scattering and absorption in bismuth nanorod suspensions. Appl. Phys. Lett. 91, 093104 (2007)

    Article  Google Scholar 

  7. S. Lee, J.H. Lee, M. Kim, J. Kim, M.-J. Song, H.-I. Jung, W. Lee, Bi nanowire-based thermal biosensor for the detection of salivary cortisol using the Thomson effect. Appl. Phys. Lett. 103, 143114 (2013)

    Article  Google Scholar 

  8. D. Su, S. Dou, G. Wang, Bismuth: a new anode for the Na-ion battery. Nanomater. Energy 12, 88–95 (2015)

    Article  CAS  Google Scholar 

  9. C. Tan, X. Cao, X.-J. Wu, Q. He, J. Yang, X. Zhang, J. Chen, W. Zhao, S. Han, G.H. Nam, M. Sindoro, H. Zhang, Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 117, 6225 (2017)

    Article  CAS  Google Scholar 

  10. V. Jovanovski, S.B. Hočevar, B. Ogorevc, Bismuth electrodes in contemporary electroanalysis. Curr. Opin. Electrochem. 3, 114–122 (2017)

    Article  CAS  Google Scholar 

  11. Y. Zhou, M. Zhang, Z. Guo, L. Miao, S.T. Han, Z. Wang, X. Zhang, H. Zhang, Z. Peng, Recent advances in black phosphorus-based photonics, electronics, sensors and energy devices. Mater. Horiz. 4(6), 997 (2017)

    Article  CAS  Google Scholar 

  12. L. Lu, W. Wang, L. Wu, X. Jiang, Y. Xiang, J. Li, D. Fan, H. Zhang, All-optical switching of two continuous waves in few layer bismuthene based on spatial cross-phase modulation. ACS Photonics 4(11), 2852–2861 (2017)

    Article  CAS  Google Scholar 

  13. Y. Wang, W. Huang, J. Zhao, H. Huang, C. Wang, F. Zhang, J. Liu, J. Li, M. Zhang, H. Zhang, A bismuthene-based multifunctional all-optical phase and intensity modulator enabled by photothermal effect. J. Mater. Chem. C 7, 871–878 (2019)

    Article  CAS  Google Scholar 

  14. M.-A. Shahbazi, L. Faghfouri, M.P.A. Ferreira, P. Figueiredo, H. Maleki, F. Sefat, J. Hirvonen, H.A. Santos, The versatile biomedical applications of bismuth-based nanoparticles and composites: therapeutic, diagnostic, biosensing, and regenerative properties. Chem. Soc. Rev. 49, 1253–1321 (2020)

    Article  CAS  Google Scholar 

  15. K. Fan, Y.F. Jia, Y.F. Ji, P.Y. Kuang, B.C. Zhu, X.Y. Liu, J.G. Yu, Curved surface boosts electrochemical CO2 reduction to formate via bismuth nanotubes in a wide potential window. ACS Catal. 10, 358–364 (2020)

    Article  CAS  Google Scholar 

  16. X. Liu, S. Zhang, S. Guo, B. Cai, S.A. Yang, F. Shan, M. Pumera, H. Zeng, Advances of 2D bismuth in energy sciences. Chem. Soc. Rev. 49, 263–285 (2020)

    Article  CAS  Google Scholar 

  17. W. Huang, J. Zhu, M. Wang, L. Hu, Y. Tang, Y. Shu, Z. Xie, H. Zhang, Emerging mono-elemental bismuth nanostructures: controlled synthesis and their versatile applications. Adv. Funct. Mater. 31, 2007584 (2021)

    Article  CAS  Google Scholar 

  18. F.Y. Yang, K. Liu, C.L. Chien, P.C. Searson, Large magnetoresistance and finite-size effects in electrodeposited single-crystal Bi thin films. Phys. Rev. Lett. 82, 3328–3331 (1999)

    Article  CAS  Google Scholar 

  19. S.L. Cho, Y. Kim, A.J. Freeman, G.K.L. Wong, J.B. Ketterson, L.J. Olafsen, I. Vurgaftman, J.R. Meyer, C.A. Hoffmann, Large magnetoresistance in post annealed Bi thin films. Appl. Phys. Lett. 79, 3651–3653 (2001)

    Article  CAS  Google Scholar 

  20. T. Nagao, J. Sadowski, M. Saito, S. Yaginuma, Y. Fujikawa, T. Kogure, T. Ohno, Y. Hasegawa, S. Hasegawa, T. Sakurai, Nanofilm allotrope and phase transformation of ultrathin Bi film on Si(111)-7 × 7. Phys. Rev. Lett. 93, 105501 (2004)

    Article  CAS  Google Scholar 

  21. D.H. Kim, S.H. Lee, J.K. Kim, G.H. Lee, Structure and electrical transport properties of bismuth thin films prepared by RF magnetron sputtering. Appl. Surf. Sci. 252, 3525–3531 (2006)

    Article  CAS  Google Scholar 

  22. L. Kumari, S.J. Lin, J.H. Lin, Y.R. Ma, P.C. Lee, Y. Liou, Effects of deposition temperature and thickness on the structural properties of thermal evaporated bismuth thin films. Appl. Surf. Sci. 253, 5931–5938 (2007)

    Article  CAS  Google Scholar 

  23. X.K. Duan, J.Y. Yang, W. Zhu, X.A. Fan, C.J. Xiao, Structure and electrical properties of bismuth thin films prepared by flash evaporation method. Mater. Lett. 61, 4341–4343 (2007)

    Article  CAS  Google Scholar 

  24. X. Sun, H. Zhao, J. Chen, W. Zhong, B. Zhu, L. Tao, Effects of the thickness and laser irradiation on the electrical properties of e-beam evaporated 2D bismuth. Nanoscale 13, 2648–2657 (2021)

    Article  CAS  Google Scholar 

  25. R.N. Wenzel, Resistance of solid surfaces to wetting by water. Ind. Eng. Chem. 28, 988–994 (1936)

    Article  CAS  Google Scholar 

  26. A.B.D. Cassie, S. Baxter, Wettability of porous surfaces. Trans. Faraday Soc. 40, 546–550 (1944)

    Article  CAS  Google Scholar 

  27. J. Zheng, S. Bao, Y. Guo, P. Jin, Natural hydrophobicity and reversible wettability conversion of flat anatase TiO2 thin film. ACS Appl. Mater. Interfaces 6, 1351–1355 (2014)

    Article  CAS  Google Scholar 

  28. L. Feng, S. Li, Y. Li, H. Li, L. Zhang, J. Zhai, Y. Song, B. Liu, L. Jiang, D. Zhu, Super-hydrophobic surfaces: from natural to artificial. Adv. Mater. 14, 1857–1860 (2002)

    Article  CAS  Google Scholar 

  29. J. Toudert, M.J. de Castro, R. Serna, Exploring the optical potential of nano-bismuth: tunable surface plasmon resonances in the near ultraviolet-to-near infrared range. J. Phys. Chem. C 116(38), 20530–20539 (2012)

    Article  CAS  Google Scholar 

  30. J. Toudert, R. Serna, I. Camps, J. Wojcik, P. Mascher, E. Rebollar, T.A. Ezquerra, Unveiling the far infrared-to-ultraviolet optical properties of bismuth for applications in plasmonics and nanophotonics. J. Phys. Chem. C 121(6), 3511–3521 (2017)

    Article  CAS  Google Scholar 

  31. J. Toudert, R. Serna, Interband transitions in semi-metal, semiconductors, and topological insulators: a new driving force for plasmonics and nanophotonics. Opt. Mater. Express 7(7), 2299–2325 (2017)

    Article  CAS  Google Scholar 

  32. Y. Tian, J. Toudert, Nanobismuth: fabrication, optical, and plasmonic properties-emerging applications. J. Nanotechnol. (2018). https://doi.org/10.1155/2018/3250932

    Article  Google Scholar 

  33. J. Toudert, R. Serna, C. Deeb, E. Rebollar, Optical properties of bismuth nanostructures towards the ultrathin film regime. Opt. Mater. Express 7, 2924–2936 (2019)

    Article  Google Scholar 

Download references

Funding

This work was supported by the China Postdoctoral Science Foundation (2021M700093) and National Natural Science Foundation of China (52103038).

Author information

Authors and Affiliations

Authors

Contributions

NW: conceptualization, methodology, investigation, validation, data curation, writing - original draft, writing - review & editing, funding acquisition. TZ: formal analysis, writing - original draft, writing - review & editing. XL: conceptualization, resources, supervision, writing - review & editing. HZ: investigation. JZ: Investigation, validation.

Corresponding author

Correspondence to Nan Wang.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, N., Zhang, T., Liu, X. et al. Transparent conductivity in polycrystal bismuth thin films grown on glass by molecular beam epitaxy. J Mater Sci: Mater Electron 34, 134 (2023). https://doi.org/10.1007/s10854-022-09592-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10854-022-09592-w

Navigation