Abstract
Materials with synergistic functionality are of great importance in consumer electronics. We report on the preparation and assessments of Te @ PANI composite for energy conversion and storage application. Initially, (5–15%) Te @ PANI composites were synthesized by the facile, room temperature, time and cost-effective solid-state synthesis technique followed by characterizations using Fourier transform infra-red, UV-Visible, energy dispersive spectroscopic including X-ray diffractometry and field electron scanning microscopy. Te exfoliates polymeric segments of PANI by bonding benzenoid rings through sulphonated impurity sites which have a profound impact on symmetry molecular bond vibrations. Its analysis is presented. In photophysical application, both dark and luminescent I-V measurements have been performed that showed a linear variation with minimum photo-resistance offered by 10% composite and reaching current > 10 mA under 1.5 V biased conditions. In storage response, Te @ PANI supercapacitor devices are dominating in inductive coupling over capacitive coupling by ten times. Corresponding shunt impedance is seen to be favourably lower for 10% composition, and respective charge transfer impedance has also followed identical behaviour over other classes of samples. The quality factor of the device for 10% is found to be almost twelve times better. However, at a low scan rate (10 mV/s), the presence of Te has changed the tendency of ion migration, thereby, reducing the magnitude of ion current by about three times with an increase in Te from 5 to 15%. Thus, fabricated composite demonstrated synergistic aspects of energy.
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Acknowledgements
Authors PR and PSA are thankful to Nilesh G. Saykar for his help in recording I-V data and to Sathish Natarajan (Scientist, CSIR-AMPRI, Bhopal) for performing the RAMAN measurement. Author PR also thanks to the University grant commission, India, for awarding the SRF fellowship.
Funding
This study was supported by the University Grants Commission, 1282/(CSIR-UGC NET DEC. 2018) to Pinki Rani.
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PR: prepared samples, characterized, implemented for application, optimised and demonstrating the application, wrote draft manuscript. YJ: assisted experimental work, implemented experimental work, collected data. KKH and RB made facility electrochemical available. PSA: generated idea, provided theme, made overall coordination, prepared final manuscript draft.
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Rani, P., Jewariya, Y., Haldar, K.K. et al. Synergistic photophysical and electrochemical response of Te @ PANI for energy harvesting. J Mater Sci: Mater Electron 34, 8 (2023). https://doi.org/10.1007/s10854-022-09414-z
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DOI: https://doi.org/10.1007/s10854-022-09414-z