Abstract
Alkaline earth-based double perovskite composites are novel perovskite compounds that have been the recent topic of interest for many material physicists. Since not much work has been reported in this particular field of study; hence, we took up the task of analyzing the multifunctional and multiferroic properties of Mg2(Fe0.85Ni0.15)NbO6. The frequency-dependent dielectric, impedance, and tangent loss characterizations were performed to infer the capacitive and semiconducting properties of the sample. The magnetic study revealed the weak ferromagnetic characteristics of the composite, particularly induced by structural distortions. The nonzero P−E hysteresis loop at room temperature indicates the ferroelectric polarizations present in the compound. The optical band gap was estimated by extrapolating the Tauc plot of ultraviolet−visible spectroscopy covering the UV to the visible range of the electromagnetic spectra. The conductivity analysis was performed following the frequency-dependent ac conductivity which showed very good high-frequency ac conductivity of the ceramic.
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References
K. Leng, Q. Tang, Y. Wei, Li. Yang, Y. Xie, Wu. Zhiwei, X. Zhu, AIP Adv. 10, 120701 (2020). https://doi.org/10.1063/5.0031196
Q. Tang, X. Zhu, Nanomaterials 12, 224 (2022). https://doi.org/10.3390/nano12020244
P. Kayser, M.J. Martínez-Lope, J.A. Alonso, M. Retuerto, M. Croft, A. Ignatov, M.T. Fernández-Díaz, Eur J Inorg Chem. (2014). https://doi.org/10.1002/ejic.201301080
D.D. Khalyavin, J.P. Han, A.M. Senos, P.Q. Mantas, Sci. Forum 455, 30–34 (2004). https://doi.org/10.4028/www.scientific.net/msf.455-456.30. (Trans Tech Publications, Ltd)
L. Skutina, E. Filonova, D. Medvedev, A. Maignan, Cells. Mater. 14(7), 1715 (2021). https://doi.org/10.3390/ma14071715
R. VaradwajPradeep, H.M. Marques, Front. Chem. (2020). https://doi.org/10.3389/fchem.2020.00796
R.S. Lamba, P. Basera, S. Bhattacharya, S. Sapra, Phys. Chem. Lett. 10(17), 5173–5181 (2019). https://doi.org/10.1021/acs.jpclett.9b02168
IlariaCarlomagno AbhisekBandyopadhyay, M. Laura Simonelli, A.E. MorettiSala, C. Meneghini, S. Ray, Phys. Rev. B 100, 064416 (2019). https://doi.org/10.1103/PhysRevB.100.064416
I.D. SayantikaBhowal, Phys. Rev. B 97, 024406 (2018). https://doi.org/10.1103/PhysRevB.97.024406
N.V. Urusova, M.A. Semkin, E.A. Filonova, M. Kratochvilova, D.S. Neznakhin, J.-G. Park, A.N. Pirogov, J. Phys.: Conf. Ser. 1389, 012131 (2019). https://doi.org/10.1088/1742-6596/1389/1/012131
M. Rabiei, A. Palevicius, A. Monshi, S. Nasiri, A. Vilkauskas, G. Janusas, Nanomaterials 10(9), 1627 (2020). https://doi.org/10.3390/nano10091627
J. Smit, H.P.J. Wijn, Adv. Electr. Electron Phys. 6, 69–136 (1954). https://doi.org/10.1016/S0065-2539(08)60132-8
K. Jawahar, R.N.P. Choudhary, Matter. Lett. 62, 911 (2008)
C.G. Koops, Phys. Rev. 83, 121 (1951). https://doi.org/10.1103/PhysRev.83.121
N. Rezlescu, E. Rezlescu, Phys. Stat. Sol. A 23, 575 (1974). https://doi.org/10.1002/pssa.2210230229
S.H. Kim, K.D. Park, H.S. Lee, Energies 14, 275 (2021). https://doi.org/10.3390/en14020275
D.K. Mahato, A. Dutta, T.P. Sinha, Bull. Mater. Sci. 34(3), 455–462 (2011)
J.W. Chen, K.R. Chiou, A.C. Hsueh, C.R. Chang, RSC Adv. 9, 12319–12324 (2019)
S. Pattanayak, B.N. Parida, P.R. Das, R.N.P. Choudhary, Appl. Phys. A 112, 387–395 (2013)
J. Plocharski, W. Wieczoreck, Solid State Ion. 28, 979–982 (1982)
M.A.L. Nobre, S. Lanfredi, J. Phys. Chem. Solid. 62, 1999 (2001)
S. Behera, B.N. Parida, P. Nayak, P.R. Das, J. Mater. Sci. Mater. Electron. 24, 1132 (2013)
C.K. Suman, K. Prasad, R.N.P. Choudhary, J. Mater. Sci. 41, 369 (2006)
T.S. Irvine, D.C. Sinclair, A.R. West, Adv. Mater. 2, 132 (1990)
M. Siekierski, W. Wieczorek, Solid State Ionics 60(1–3), 67–71 (1993). https://doi.org/10.1016/0167-2738(93)90276-9
H. Yang, F. Yan, Y. Lin, T. Wang, F. Wang, Sci. Rep. 7, 8726 (2017). https://doi.org/10.1038/s41598-017-06966-7
G. Blasse, J. Chem. Phys. 45, 2356 (1966)
H.S. Kim, L. Bi, G.F. Dionne, C.A. Ross, H.J. Paik, phys Rev. B. 77, 214436 (2008)
Z.X. Cheng, X.L. Wang, S.X. Dou, H. Kimura, K. Ozawa, Phys. Rev. B 77, 092101 (2008)
C. Kursun, M. Gogebakan, E. Uludag, M.S. Bozgeyik, F.S. Uludag, Sci. Rep. 8, 13083 (2018). https://doi.org/10.1038/s41598-018-31458-7
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by [SM], [SS], [SB] and [BNP]. The first draft of the manuscript was written by [SM] and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Mohanty, S., Sen, S., Behera, S. et al. Multiferroic and optical characteristics of Mg2(Fe0.85Ni0.15)NbO6 for possible energy storage application. J Mater Sci: Mater Electron 33, 23770–23780 (2022). https://doi.org/10.1007/s10854-022-09135-3
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DOI: https://doi.org/10.1007/s10854-022-09135-3