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Analysing the dielectric properties of ZnO doped PVDF/PMMA blend composite

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Abstract

Composite films of polyvinylidene fluoride (PVDF)/polymethyl methacrylate (PMMA) blend filled with zinc oxide in 0.5%, 1%, 2%, and 4% wt concentration were prepared by solution-casting technique. The values of impedance parameters, viz. capacitance (C) and dissipation factor (D), were measured using impedance analyser (Wanyne Kerr 6500B) and from this data the effect of doping levels on the dielectric properties, viz. complex dielectric function, electrical conductivity and electric modulus of these films were investigated in the frequency range 102–106 Hz at ambient temperature. It was observed that the dielectric constant (ε), AC conductivity (σAC) and loss tangent (tanδ) increase significantly with increase in ZnO content. A direct correlation between the dielectric parameter and the mean relaxation time of polymer chain segmental dynamics has been observed and it can be inferred that varying amount of metal oxide filler can be used to tailor the dielectric properties of these materials for their use in microelectronics.

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Data availability

The datasets generated during this study are available from the corresponding author on a reasonable request.

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Acknowledgements

We acknowledge Prof. (Dr.) Mirza S. Baig, IIT—Indore and Dr. Balram Tripathi, Department of Physics, S.S. Jain Subodh PG (Autonomous) College, for providing experimental facilities and technical support to find the structure of my samples with Impedance spectroscopy and its use.

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The Authors declares that no funds, grants or other support were received during the preparation of this manuscript.

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Authors and Affiliations

  1. S S Jain Subodh P G College, Jaipur, India

    Farah Deeba

  2. School of Applied Sciences, Suresh GyanVihar University, Jaipur, India

    Farah Deeba & Ankur Jain

  3. Department of Physics, Agrawal P. G. College, Jaipur, India

    Ankit K. Gupta & Minal Bafna

  4. CentralSalt & Marine Chemical Research Institute, Bhavnagar, Gujrat, India

    Vaibhav Kulshrestha

  5. Center for Renewable Energy and Storage, Suresh GyanVihar University, Jaipur, India

    Ankur Jain

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  1. Farah Deeba
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Contributions

All authors contributed to the study, conception and design of the manuscript. Material preparation, data collection, characterization and analysis were performed by FD, AKG, VK, MB and AJ. The first draft of the manuscript was written by FD and all authors contributed for the modified final versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Ankur Jain.

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Deeba, F., Gupta, A.K., Kulshrestha, V. et al. Analysing the dielectric properties of ZnO doped PVDF/PMMA blend composite. J Mater Sci: Mater Electron 33, 23703–23713 (2022). https://doi.org/10.1007/s10854-022-09129-1

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