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P2-Na0.7Ni0.25Mn0.75O2 micro-sheets with high capacity as advanced cathode materials for sodium-ion batteries

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Abstract

In this paper, a series of NaxNi0.25Mn0.75O2 (x = 0.6–0.9) have been designed, synthesized and applied as cathode materials of rechargeable sodium-ion batteries. The increase of sodium content (x) can greatly improve the theoretical specific capacities of the Na–Ni–Mn–O materials, but also cause the structural evolution and even induce the formation of impurity phase, which are unfavourable to the electrochemical properties. Electrochemical tests show that the formed Na0.7Ni0.25Mn0.75O2 can deliver the highest reversible capacity of up to 162 mAh g−1 at 0.2 C and capacity retention of about 60% after 100 cycles, indicating that only the as-prepared Na0.7Ni0.25Mn0.75O2 micro-sheets with P2-phase achieve the best balance of structural stability and high capacity during the sodiation/desodiation reaction.

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The datasets generated during and/or analysed during the current study are included in the manuscript and available from the corresponding author on reasonable request.

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Acknowledgements

This work was supported by the Natural Science Foundation of Chongqing Province (cstc2020jcyj-msxmX0445), "Zeng Sumin Cup" scientific and technological innovation project of School of materials and energy, Southwest University (zsm202013, zsm2021021) and Program for Innovation Team Building at Institutions of Higher Education in Chongqing (XDJK2019AA002).

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Authors and Affiliations

  1. School of Materials and Energy, Southwest University, Chongqing, 400715, China

    Qijie Li, Xi Wang, Keyuan Zhang, Feng Xiong & Jingang Yang

  2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin, 300071, China

    Jingang Yang

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  1. Qijie Li
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  2. Xi Wang
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  3. Keyuan Zhang
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  4. Feng Xiong
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Contributions

All authors contributed to the study conception and design. QL and JY design article, design experiments and summarize data; QL, XW and KZ complete the experiment and test and analyse the obtained samples, article writing; FX collect and analyse the literature; all authors read and approved the final manuscript.

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Correspondence to Jingang Yang.

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Li, Q., Wang, X., Zhang, K. et al. P2-Na0.7Ni0.25Mn0.75O2 micro-sheets with high capacity as advanced cathode materials for sodium-ion batteries. J Mater Sci: Mater Electron 33, 23623–23629 (2022). https://doi.org/10.1007/s10854-022-09121-9

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  • DOI: https://doi.org/10.1007/s10854-022-09121-9

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