Abstract
The presence of composite in the nanofluid resultant is essential to provide a significant methylene blue (MB) removal property in industrial waste water. Silver oxide (Ag2O) nanoparticles (NPs) placed over zinc oxide (ZnO) NPs had a significant increase in photocatalytic activity. The Ag2O NPs doped ZnO NPs were synthesised in the current study by utilising Millingtonia hortensis flower extract and a simple green synthesis procedure. The floral extract is a fantastic reducing and stabilizing agent. ZnO has been doped along with Ag2O Nanofluid (NF) (volumes of ZnO 10 ml, 15 ml, 20 ml, and 25 ml). The crystalline nature of the produced material was investigated using powder XRD analysis. To confirm the presence of silver in nanofluids, the EDAX spectrum and UV–Vis spectral analysis were employed. The EDAX spectrum established the materials’ compositions, while the FESEM analysis revealed the various surface morphologies of the generated materials. ZnO/Ag2O (NPs) catalysts degraded the organic dye MB. ZnO/Ag2O NPs (25 ml Ag2O NF) degrade at a rate of 63 percent after 120 min of irradiation, due to their large surface area. The typical particle size of synthesised nanoparticles is 16–17 nm. The photocatalytic activities are enhanced when particles from the flower are extracted, according to the characterization data.
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The datasets generated during and/or analyzed during the current study are available from the corresponding author on request.
References
S. Asha, C. Hentry, M.R. Bindhu, A.M. Al-Mohaimeed, M.R.A. Gawwad, M.S. Elshikh, Improved photocatalytic activity for degradation of textile dyeing waste water and thiazine dyes using PbWO4 nanoparticles synthesized by co-precipitation method. Environ. Res. 200, 111721 (2021)
M.B. Tahir, A. Ahmad, T. Iqbal, M. Ijaz, S. Muhammad, S.M. Siddeeg, Advances in photo-catalysis approach for the removal of toxic personal care product in aqueous environment. Dev. Sustain. 22, 6029–6052 (2020)
M.I. Khan, M.N. Akhtar, N. Ashraf, J. Najeeb, H. Munir, T.I. Awan, M.B. Tahir, M.R. Kabli, Green synthesis of magnesium oxide nanoparticles using Dalbergia sissoo extract for photocatalytic activity and antibacterial efficacy. Appl. Nanosci. 10, 2351–2364 (2020)
K. Banupriya, A. Revathi, D. Sudha, R. Umarani, Tetrapropylammonium tribromocupurate complex [(C3H7)4N]CuBr3(II)—synthesis, thermal and spectral characterization. Mater. Today Proc. 45, 8024–8028 (2021)
S.G. Shelar, V.K. Mahajan, S.P. Patil, G.H. Sonawane, Effect of doping parameters on photocatalytic degradation of methylene blue using Ag doped ZnO nanocatalyst. SN Appl. Sci. 5, 1–10 (2020)
T.A. Kurniawan et al., Functionalizing TiO2 with graphene oxide for enhancing photocatalytic degradation of methylene blue (MB) in contaminated wastewater. J. Environ. Manag. 270, 110871 (2020)
C.M. Lee, P. Palaniandy, I. Dahlan, Pharmaceutical residues in aquatic environment and water remediation by TiO2 heterogeneous photocatalysis: a review. Environ. Earth Sci. 76, 1–19 (2017)
M. Ijaz, M. Zafar, T. Iqbal, Green synthesis of silver nanoparticles by using various extracts: a review. Inorg. Nano-Met. Chem. 51, 744–755 (2020)
D. Sudha, S. Vairam, S. Sarathbabu, N. Senthil Kumar, R. Sivasamy, S. Jone Kirubavathy, 2-Methylimidazolium pyridine-2, 5-dicarboxylato zinc (II) dihydrate: synthesis, characterization, DNA interaction, anti-microbial, anti-oxidant and anti-breast cancer studies. J. Coord. Chem. 74(16), 2701–2719 (2021)
V. Sivaprakash, R. Narayanan, Anodic synthesis of TiO2 nanotubes influence of water content and the analysis of the nano-mechanical application. J. Bio- Tribo-Corros. 6, 1–9 (2020)
A. Di Mauro, M.E. Fragala, V. Privitera, G. Impellizzeri, ZnO for application in photocatalysis: from thin films to nanostructures. Mater. Sci. Semicond. Process. 69, 44–51 (2017)
T. Cheng, H. Gao, G. Liu, Z. Pu, S. Wang, Z. Yi, X. Wu, H. Yang, Preparation of core-shell heterojunction photocatalysts by coating CdS nanoparticles onto Bi4Ti3O12 hierarchical microspheres and their photocatalytic removal of organic pollutants and Cr (VI) ions. Colloids Surf. A Physicochem. Eng. Asp. 633, 127918 (2022)
D. Zhu et al., Seed-mediated growth of heterostructured Cu1.94S-MS (M= Zn, Cd, Mn) and alloyed CuNS2 (N = In, Ga) nanocrystals for use in structure-and composition-dependent photocatalytic hydrogen evolution. Nanoscale 12, 6111–6120 (2020)
S.E. Laouini, A. Bouafia, A.V. Soldatov, H. Algarni, M.L. Tedjani, G.A.M. Ali, A. Barhoum, Green synthesized of Ag/Ag2O nanoparticles using aqueous leaves extracts of Phoenix dactylifera L. and their azo dye photodegradation. Membranes 11, 468 (2021)
E. Vasilaki, M. Vamvakaki, N. Katsarakis, Complex ZnO–TiO2 core–shell flower-like architectures with enhanced photocatalytic performance and superhydrophilicity without UV irradiation. Langmuir 34, 9122–9132 (2018)
C.B. Ong, L.Y. Ng, A.W. Mohammad, A review of ZnO nanoparticles as solar photocatalysts: synthesis, mechanisms and applications. Renew. Sustain. Energy Rev. 81, 536–551 (2018)
S. Pahal, R. Boranna, G.R. Prashanth, M.M. Varma, Simplifying molecular transport in polyelectrolyte multilayer thin films. Macromol. Chem. Phys. 223(1), 2100330 (2022)
S.H. Mohamed, E.R. Shaaban, Microstructural, optical and photocatalytic properties of CdS doped TiO2 thin films. Physica B 406, 4327–4331 (2011)
S.H. Mohamed, M. El-Hagary, S. Althoyaib, Growth of β-Ga2O3 nanowires and their photocatalytic and optical properties using Pt as a catalyst. J. Alloys Compd. 537, 291–296 (2012)
C. Yang, J. Qin, Z. Xue, M. Ma, X. Zhang, R. Liu, Rational design of carbon-doped TiO2 modified g-C3N4 via in-situ heat treatment for drastically improved photocatalytic hydrogen with excellent photostability. Nano Energy 41, 1–9 (2017)
S.A. Khan et al., Synthesis of TiO2/graphene oxide nanocomposites for their enhanced photocatalytic activity against methylene blue dye and ciprofloxacin. Composites Part B Eng. 175, 107120 (2019)
O.A. Oyewo, A. Adeniyi, B.B. Sithole, M.S. Onyango, Sawdust-based cellulose nanocrystals incorporated with ZnO nanoparticles as efficient adsorption media in the removal of methylene blue dye. ACS Omega 5, 18798–18807 (2020)
R. Syah et al., CuMoO4/ZnO nanocomposites: novel synthesis, characterization, and photocatalytic performance. J. Nanostruct. 11, 73–80 (2021)
F. Yu et al., ZnO/biochar nanocomposites via solvent free ball milling for enhanced adsorption and photocatalytic degradation of methylene blue. J. Hazard. Mater. 415, 125511 (2021)
M. Zarrabi, M. Haghighi, R. Alizadeh, Sonoprecipitation dispersion of ZnO nanoparticles over graphene oxide used in photocatalytic degradation of methylene blue in aqueous solution: influence of irradiation time and power. Ultrason. Sonochem. 48, 370–382 (2018)
Rajasulochana K, Ramasamy Raja V, Suganthi A, Rajarajan M (n.d.). Fabrication of hetero junction p-LaNiO3 modified n-TiO2 as visible light active catalyst for photocalatytic degradation of 4-chloro phenol. Int J Res Anal Rev
H. Zhou et al., In-situ preparation of silver salts/collagen fiber hybrid composites and their photocatalytic and antibacterial activities. J. Hazard. Mater. 359, 274–280 (2018)
D. Sudha, A. Ramasubbu, Synthesis and characterization of Zn–Al, Mg–Al layered double hydroxides intercalated polymer nanocomposites. Asian J. Chem. 25(1), S120 (2013)
R. Vinayagam, R. Selvaraj, P. Arivalagan, T. Varadavenkatesan, Synthesis, characterization and photocatalytic dye degradation capability of Calliandra haematocephala-mediated zinc oxide nanoflowers. J. Photochem. Photobiol. B 203, 111760 (2020)
A. Nazir et al., Zinc oxide nanoparticles fabrication using Eriobotrya japonica leaves extract: photocatalytic performance and antibacterial activity evaluation. Arab. J. Chem. 14, 103251 (2021)
L. Chen et al., Green synthesis of zinc oxide nanoparticles from root extract of Scutellaria baicalensis and its photocatalytic degradation activity using methylene blue. Optik 184, 324–329 (2019)
T. Varadavenkatesan, E. Lyubchik, S. Pai, A. Pugazhendhi, R. Vinayagam, R. Selvaraj, Photocatalytic degradation of rhodamine B by zinc oxide nanoparticles synthesized using the leaf extract of Cyanometra ramiflora. J. Photochem. Photobiol. B 199, 111621 (2019)
M.I. Din, M. Tariq, Z. Hussain, R. Khalid, Single step green synthesis of nickel and nickel oxide nanoparticles from Hordeum vulgare for photocatalytic degradation of methylene blue dye. Inorg. Nano-Met. Chem. 50, 292–297 (2020)
S. Kwon, M. Fan, A.T. Cooper, H. Yang, Photocatalytic applications of micro-and nano-TiO2 in environmental engineering. Crit. Rev. Environ. Sci. Technol. 38, 197–226 (2008)
B.A. Bhanvase, T.P. Shende, S.H. Sonawane, A review on graphene–TiO2 and doped graphene–TiO2 nanocomposite photocatalyst for water and wastewater treatment. Environ. Technol. Rev. 6, 1–14 (2017)
Y. Dong, X. Fei, Effect of isopropanol on crystal growth and photocatalytic properties regulation of anatase TiO2 single crystals. Mater. Technol. 35, 102–111 (2020)
A. Revathi, P.N. Palanisamy, Kinetics, isotherm and thermodynamic studies on the adsorption of methylene blue dye by iron doped activated carbon. Digest J. Nanomater. Biostruct. 17, 431–441 (2022)
S.B. Jaffri, K.S. Ahmad, Neoteric environmental detoxification of organic pollutants and pathogenic microbes via green synthesized ZnO nanoparticles. Environ. Technol. 40(28), 3745–3761 (2018)
M. Khatami, S. Iravani, Green and eco-friendly synthesis of nanophotocatalysts: an overview. Comments Inorg. Chem. 41, 133–187 (2021)
N. Rana, S. Chand, A.K. Gathania, Band gap engineering of ZnO by doping with Mg. Phys. Scr. 90, 085502 (2015)
N. Rana, S. Chand, A.K. Gathania, Green synthesis of zinc oxide nano-sized spherical particles using Terminalia chebula fruits extract for their photocatalytic applications. Int. Nano Lett. 6, 91–98 (2016)
R. Azadeh, Synthesis and characterization of hydroxyapatite nanocrystal and gelatin doped with Zn2+ and cross linked by glutaraldehyde. Int. J. Phys. Sci. 7(20), 2768–2774 (2012)
S. Yadav, N. Kumar, B. Mari, A. Mittal, V. Jangra, A. Sharma, K. Kumari, Ag/ZnO nano-structures synthesized by single-step solution combustion approach for the photodegradation of Cibacron Red and Triclopyr. Appl. Nanosci. 11(7), 1977–1991 (2021)
M.A. Ahmed, U. Seddik, N. Okasha, N.G. Imam, One-dimensional nanoferroic rods; synthesis and characterization. J. Mol. Struct. 1099, 330–339 (2015)
F. Haque, T. Daeneke, K. Kalantar-Zadeh, J.Z. Ou, Two-dimensional transition metal oxide and chalcogenide-based photocatalysts. Nano-Micro Lett. 10, 1–27 (2018)
S.H. Mohamed, M. El-Hagary, S. Althoyaib, Photocatalytic and optical properties of nanocomposite TiO2–ZnO thin films. Eur. Phys. J. Appl. Phys. 57, 20301–20306 (2012)
Q. Cheng, W. Yang, Q. Chen, J. Zhu, D. Li, L. Fu, L. Zhou, Fe-doped zirconia nanoparticles with highly negative conduction band potential for enhancing visible light photocatalytic performance. Appl. Surf. Sci. 530, 147291 (2020)
N. Rana, K.S. Ghosh, S. Chand, A.K. Gathania, Investigation of ZnO nanoparticles for their applications in wastewater treatment and antimicrobial activity. Indian J. Pure Appl. Phys. 56(1), 19–25 (2018)
S. Yadav, A. Mittal, S. Sharma, K. Kumari, N.S. Chauhan, N. Kumar, Low temperature synthesized ZnO/Al2O3 nano-composites for photocatalytic and antibacterial applications. Semicond. Sci. Technol. 35(5), 055008 (2020)
V. Kumari, A. Mittal, J. Jindal, S. Yadav, N. Kumar, S-, N-and C-doped ZnO as semiconductor photocatalysts: a review. Front. Mater. Sci. 13(1), 1–22 (2019)
V. Kumari, S. Yadav, A. Mittal, K. Kumari, B. Mari, N. Kumar, Surface Plasmon response of Pd deposited ZnO/CuO nanostructures with enhanced photocatalytic efficacy towards the degradation of organic pollutants. Inorg. Chem. Commun. 1201, 108241 (2020)
Acknowledgements
We would like to thanks the department of chemistry, Vellalar College of engineering and technology, Erode, Department of Mechanical engineering, Sathyabama Institute of Science and Technology, Chennai, Department of chemistry, KPR Institute of Engineering and Technology, Coimbatore and Centre for environmental research, Kongu Engineering College, Erode for providing the necessary facility to complete the research.
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Suganya, R., Revathi, A., Sudha, D. et al. Evaluation of structural, optical properties and photocatalytic activity of Ag2O coated ZnO nanoparticles. J Mater Sci: Mater Electron 33, 23224–23235 (2022). https://doi.org/10.1007/s10854-022-09086-9
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DOI: https://doi.org/10.1007/s10854-022-09086-9