Abstract
Ni0.5−xMgxZn0.5Fe2O4 (x = 0.00, 0.05, 0.10 and 0.15) samples were prepared by the sol–gel method. The samples were characterized by X-ray diffraction, field emission scanning electron microscopy, vibrating sample magnetometer and LCR meter. XRD results confirmed that the samples were free of impurities. The grain size continued to increase with the doping of Mg2+ ions. According to the VSM analysis of Ni0.5−xMgxZn0.5Fe2O4, the saturation magnetization (Ms) of the samples can increase to 94.80 emu/g by Mg2+ doping. In addition, the Ni0.5−xMgxZn0.5Fe2O4 samples also showed dielectric behavior that can be explained by polarization theory. Moreover, ZnFe2O4 sample showed favorable nonlinear optical absorption characteristics due to the internal magnetic interactions and the distribution of cations in the sublattices. These results indicated that the samples involved in this work have potential applications in high-density recording media and optical limiting devices.
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References
M. Adnan, M. Usman, M.A. Akram, S. Javed, S. Ali, I. Ahmad, M. Islam, Study of magnetic and dielectric properties of ZnFe2O4/CoCr2O4 nanocomposites produced using sol-gel and hydrothermal processes. J. Alloy Compd. 865, 158953 (2021)
K. Patil, S. Kadam, P. Lokhande, S. Balgude, P. More, The effects of cobalt and magnesium co-doping on the structural and magnetic properties of ZnFe2O4 synthesized using a sonochemical process. Solid State Commun. 337, 114435 (2021)
B.N. Sahu, S.C. Sahoo, N. Venkataramani, S. Prasad, R. Krishnan, Observation of extraordinarily large magnetization in CoFe2O4/ZnFe2O4 bilayers. J. Magn. Magn. Mater. 523, 167629 (2021)
K. Kombaiah, J.J. Vijaya, L.J. Kennedy, M. Bououdina, K. Kaviyarasu, R.J. Ramalingam, M.A. Munusamy, A. AlArfaj, Effect of Cd2+ concentration on ZnFe2O4 nanoparticles on the structural, optical and magnetic properties. Optik 135, 190–199 (2017)
D.G. Chen, X.G. Tang, J.B. Wu, W. Zhang, Q.X. Liu, Y.P. Jiang, Effect of grain size on the magnetic properties of superparamagnetic Ni0.5Zn0.5Fe2O4 nanoparticles by co-precipitation process. J. Magn. Magn. Mater. 323, 1717–1721 (2011)
I. Ahmada, T. Abbas, M.U. Islam, A. Maqsood, Study of cation distribution for Cu-Co nanoferrites synthesized by the sol-gel method. Ceram. Int. 39, 6735–6741 (2013)
A. Hussain, T. Abbas, S.B. Niazi, Preparation of Ni1 – xMnxFe2O4 ferrites by sol-gel method and study of their cation distribution. Ceram. Int. 39, 1221–1225 (2013)
H. Kavas, A. Baykal, M.S. Toprak, Y. Köseoḡlu, M. Sertkol, B. Aktas, Cation distribution and magnetic properties of Zn doped NiFe2O4 nanoparticles synthesized by PEG-assisted hydrothermal route. J. Alloy Compd. 479, 49–55 (2009)
M. Houshiar, L. Jamilpanah, Effect of Cu dopant on the structural, magnetic and electrical properties of Ni-Zn ferrites. Mater. Res. Bull. 98, 213–218 (2018)
S.E. Shirsath, B.G. Toksha, R.H. Kadam, S.M. Patange, D.R. Mane, G.S. Jangam, A. Ghasemi, Doping effect of Mn2+ on the magnetic behavior in Ni-Zn ferrite nanoparticles prepared by sol-gel auto-combustion. J. Phys. Chem. Solids 71, 1669–1675 (2010)
Z. Peng, X. Fu, H. Ge, Z. Fu, C. Wang, L. Qi, H. Miao, Effect of Pr3+ doping on magnetic and dielectric properties of Ni-Zn ferrites by ‘‘one-step synthesis’’. J. Magn. Magn. Mater. 323, 2513–2518 (2011)
M. Saravanan, T.C. Sabari, Girisun, Nonlinear optical absorption and optical limiting properties of cadmium ferrite. Mater. Chem. Phys. 160, 413e419 (2015)
M. Saravanan, T.C. Sabari, Girisun, Enhanced nonlinear optical absorption and optical limiting properties of superparamagnetic spinel zinc ferrite decorated reduced graphene oxide nanostructures. Appl. Surf. Sci. 392, 904–911 (2017)
J.J. Thomas, S. Krishnan, K. Sridharan, R. Philip, N. Kalarikkal, A comparative study on the optical limiting properties of different nano spinel ferrites with Z-scan technique. Mater. Res. Bull. 47, 1855–1860 (2012)
S. Yuvaraj, N. Manikandan, G. Vinitha, Effect of Zn2+ ions on third order nonlinear optical behavior and power limiting properties of manganese ferrite nanoparticles. Photonic Nanostruct. 45, 100922 (2021)
N. Rezlescu, C. Doroftei, E. Rezlescu, P.D. Popa, Structure and humidity sensitive electrical properties of the Sn4+ and/or Mo6+ substituted Mg ferrite. Sens. Actuat B-Chem 115, 589–595 (2006)
L. Lva, P. Cheng, Y. Wang, L. Xu, B. Zhang, C. Lv, J. Ma, Y. Zhang, Sb-doped three-dimensional ZnFe2O4 macroporous spheres for N-butanol chemiresistive gas sensors. Sens. Actuat B-Chem 320, 128384 (2020)
Y. Xiang, Y. Huang, B. Xiao, X. Wu, G. Zhang, Magnetic yolk-shell structure of ZnFe2O4 nanoparticles for enhanced visible light photo-Fenton degradation towards antibiotics and mechanism study. Appl. Surf. Sci. 513, 145820 (2020)
S. Chinnapaiyan, T. Chen, S. Chen, Z.A. Alothman, M.A. Ali, S.M. Wabaidur, F. Al-Hemaid, S. Lee, W. Chang, Ultrasonic-assisted preparation and characterization of magnetic ZnFe2O4/ g-C3N4 nanomaterial and their applications towards electrocatalytic reduction of 4-nitrophenol. Ultrason. Sonochem 68, 105071 (2020)
T. Tanaka, R. Shimazu, H. Nagai, M. Tada, T. Nakagawa, A. Sandhu, H. Handa, M. Abe, Preparation of spherical and uniform-sized ferrite nanoparticles with diameters between 50 and 150 nm for biomedical applications. J. Magn. Magn. Mater. 321, 1417–1420 (2009)
A. Ghasemi, M.R. Loghman-Estarki, S. Torkian, M. Tavoosi, The microstructure and magnetic behavior of spark plasma sintered iron/nickel zinc ferrite nanocomposite synthesized by the complex sol-gel method. Compos. Part. B-Eng 175, 107179 (2019)
N. Aggarwal, S.B. Narang, Magnetic characterization of Nickel-Zinc spinel ferrites along with their microwave characterization in Ku band. J. Magn. Magn. Mater. 513, 167052 (2020)
A. Ahangari, S. Raygan, A. Ataie, Capabilities of nickel zinc ferrite and its nanocomposite with CNT for adsorption of arsenic (V) ions from wastewater. J. Environ. Chem. Eng. 7, 103493 (2019)
F.A. Hezam, N.O. Khalifa, O. Nur, M.A. Mustafa, Synthesis and magnetic properties of Ni0.5MgxZn0.5–xFe2O4 (0.0 ≤ x ≤ 0.5) nanocrystalline spinel ferrites. Mater. Chem. Phys. 257, 123770 (2021)
M. Naeem, N.A. Shah, I.H. Gul, A. Maqsood, Structural, electrical and magnetic characterization of Ni-Mg spinel ferrites. J. Alloy Compd. 487, 739–743 (2009)
N. Singh, A. Agarwal, S. Sanghi, P. Singh, Effect of magnesium substitution on dielectric and magnetic properties of Ni-Zn ferrite. Phys. B 406, 687–692 (2011)
S.B. Somvanshi, M.V. Khedkar, P.B. Kharat, K.M. Jadhav, Influential diamagnetic magnesium (Mg2+) ion substitution in nano-spinel zinc ferrite (ZnFe2O4): Thermal, structural, spectral, optical and physisorption analysis. Ceram. Int. 46, 8640–8650 (2020)
P.K. Roy, J. Bera, Effect of Mg substitution on electromagnetic properties of (Ni0.25Cu0.20Zn0.55)Fe2O4 ferrite prepared by auto combustion method. J. Magn. Magn. Mater. 298, 38–42 (2006)
M. Salman, M. Khan, S. Saleem, S. Ali, F. Hussain, R. Muhammad, A. Khesro, Y. Abdullah, Ling, Non-stoichiometric zinc ferrite nanostructures: dielectric, magnetic, optical and photoelectrochemical properties. Mater. Today Commun. 28, 102662 (2021)
A. Aslam, A.U. Rehman, N. Amin, M.A.u. Nabi, Q.u.a Abdullah, N.A. Morley, M.I. Arshad, H.T. Ali, M. Yusuf, Z. Latif, K. Mehmood, Lanthanum doped Zn0.5Co0.5LaxFe2–xO4 spinel ferrites synthesized via coprecipitation route to evaluate structural, vibrational, electrical, optical, dielectric, and thermoelectric properties. J. Phys. Chem. Solids 154, 110080 (2021)
M.A. Khan, M.Q.u. Zaman, A. Majeed, M.N. Akhtar, W. Abbas, Structural, spectral, dielectric and magnetic properties of Sr2CuxNi2 – xFe28 – xCrxO46 (0 ≤ x ≥ 0.5) ferrites synthesized via micro-emulsion route. Mater. Chem. Phys. 259, 124066 (2021)
G. Sarveena, A. Kumar, R.K. Kumar, K.M. Kotnala, M. Batoo, Singh, Investigation of structural, magnetic and Mössbauer properties of Co2+ and Cu2+ substituted Ni-Zn nanoferrites. Ceram. Int. 42, 4993–5000 (2016)
M. Kavanloui, B. Hashemi, Effect of B2O3 on the densification and magnetic properties of Li-Zn ferrite. Mater Des. 32, 4257–4261 (2011)
C. Liu, Z. Lan, X. Jiang, Z. Yu, K. Sun, L. Li, P. Liu, Effects of sintering temperature and Bi2O3 content on microstructure and magnetic properties of LiZn ferrites. J. Magn. Magn. Mater. 320, 1335–1339 (2008)
L. Sun, Q. Ni, E. Cao, Y. Zhang, W. Hao, L. Ju, Effect of Zn2+ doping on the structural, magnetic and dielectric properties of MnFe2O4 prepared by the sol-gel method. J. Mater. Sci-Mater El 29, 29:5356–5362 (2018)
M.A. Dar, V. Verma, S.P. Gairola, W.A. Siddiqui, R.K. Singh, R.K. Kotnala, Low dielectric loss of Mg doped Ni-Cu-Zn nano-ferrites for power applications. Appl. Surf. Sci. 258, 5342–5347 (2012)
J. Kurian, M.J. Mathew, Structural, optical and magnetic studies of CuFe2O4, MgFe2O4 and ZnFe2O4 nanoparticles prepared by hydrothermal/solvothermal method. J. Magn. Magn. Mater. 451, 121–130 (2018)
C. He, B. Zou, Z. Wu, Y. Nie, Third order optical nonlinearities in ZnFe2O4 nanocrystals. Opt. Commun. 281, 851–854 (2008)
Acknowledgements
This work was supported by National Natural Science Foundation of China (NSFC) (No. 11804006), Natural Science Foundation of Shanxi Province (Nos. 201901D111126 and 201901D111117).
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FM and JH performed the experiment; LS contributed significantly to analysis and manuscript preparation; FM performed the data analyses and wrote the manuscript; EC and YZ contributed to the conception of the study; LJ helped perform the analysis with constructive discussions.
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Ma, F., Sun, L., Han, J. et al. Magnetic, dielectric and nonlinear optical absorption studies of nickel–zinc ferrite with Mg2+ doping. J Mater Sci: Mater Electron 33, 22410–22420 (2022). https://doi.org/10.1007/s10854-022-09018-7
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DOI: https://doi.org/10.1007/s10854-022-09018-7