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An electrochemical and magnetic approach for /H2SO4/HNO3/chitosan functionalized multi-wall carbon nanotubes stable solutions

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Abstract

The aim of the research was to evaluate the effects of sulfonitric and CS (CS) treatment in multilayer carbon nanotubes (MWCNT) on their electrochemical and magnetic properties. Thermogravimetric analysis (TG) showed an increase in thermal properties for CS functionalized MWCNT when compared in sulfonitric medium. High resolution transmission electron microscopy (HRTEM) images revealed a reduction in the average diameter of functionalized MWCNT in the presence of CS in addition to decreasing their interlayer spaces. As evidenced by X-ray Diffraction (XRD) patterns. In addition, X-ray photoelectron spectroscopy (XPS) spectra proved the functional groups inclusion of CS and sulfonitric solution on the (carbon nanotubes) CNT matrix. Unlike pristine MWCNT solutions which are unstable in aqueous media, functionalization with acidic solutions and contributed to its potential stabilization. The results obtained by Raman Spectroscopy prove the functionalization through the insertion of functional groups in the walls of the nanotubes. The electroanalysis showed higher capacitance values by mass and by area for samples functionalized with acids and that the addition of CS during functionalization increases the resistance to current flow, causing an insulating effect.

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The data that support the findings of this study are available on request from the corresponding author.

References

  1. A.G. Olabi, Q. Abbas, A. Al Makky, M.A. Abdelkareem, Energy 248, 123617 (2022)

    Article  CAS  Google Scholar 

  2. B.H.S. Felipe, R.L.B. Cabral, R. Ladchumananandasivam, A. Zille, S. Kim, P.B.A. Fechine, J.H.O. Nascimento, J. Market. Res. 18, 2435 (2022)

    CAS  Google Scholar 

  3. R.L.B. Cabral, F.M.F. Galvão, K.K.O. de Souto Silva, B.H.S. Felipe, N.F. de Andrade Neto, P.B. de Almeida Fechine, A. Zille, S. Kim, J.H.O. do Nascimento, J. Appl. Polym. Sci. 139, e52381 (2022)

    Article  CAS  Google Scholar 

  4. S.R. Yousefi, M. Ghanbari, O. Amiri, Z. Marzhoseyni, P. Mehdizadeh, M. Hajizadeh-Oghaz, M. Salavati-Niasari, J. Am. Ceram. Soc. 104, 2952 (2021)

    Article  CAS  Google Scholar 

  5. S.R. Yousefi, H.A. Alshamsi, O. Amiri, M. Salavati-Niasari, J. Mol. Liq. 337, 116405 (2021)

    Article  CAS  Google Scholar 

  6. H. Yang, W. Xu, X. Liang, Y. Yang, Y. Zhou, Microchim. Acta 187, 1 (2020)

    Article  CAS  Google Scholar 

  7. O. Angelsky, V. Ivashko, P. Maksimyak, in Low-Dimensional Materials and Devices 2020 (International Society for Optics and Photonics, 2020), p. 1146512.

  8. M.M. Charithra, J.G. Manjunatha, J. Electrochem. Sci. Eng. 10, 29 (2020)

    Article  CAS  Google Scholar 

  9. Y.J. Sa, J.H. Kim, S.H. Joo, Angew. Chem. Int. Ed. 58, 1100 (2019)

    Article  CAS  Google Scholar 

  10. H. Mao, M. Qiu, T. Zhang, X. Chen, X. Da, W. Jing, Y. Fan, Appl. Surf. Sci. 497, 143786 (2019)

    Article  CAS  Google Scholar 

  11. R. Shoukat, M.I. Khan, Microsystem Technologies 1 (2019)

  12. M.A. Saleemi, Y.L. Kong, P.V.C. Yong, E.H. Wong, J. Drug Deliv. Sci. Technol. 59, 101855 (2020)

    Article  CAS  Google Scholar 

  13. K.K. Markose, M. Jasna, P.P. Subha, A. Antony, M.K. Jayaraj, Sol. Energy 211, 158 (2020)

    Article  CAS  Google Scholar 

  14. A.A. Isari, F. Hayati, B. Kakavandi, M. Rostami, M. Motevassel, E. Dehghanifard, Chem. Eng. J. 392, 123685 (2020)

    Article  CAS  Google Scholar 

  15. J. Ben, Z. Song, X. Liu, W. Lü, X. Li, Nanoscale Res. Lett. 15, 1 (2020)

    Article  CAS  Google Scholar 

  16. X. Gao, W. Yin, X. Liu, Mater. Res. Bull. 138, 111246 (2021)

    Article  CAS  Google Scholar 

  17. R. Teixeira-Santos, M. Gomes, L.C. Gomes, F.J. Mergulhão, IScience 24, 102001 (2021)

    Article  CAS  Google Scholar 

  18. S.-S. Park, E.-J. An, S.-B. Lee, W. Chun, N.-J. Kim, J. Ind. Eng. Chem. 18, 443 (2012)

    Article  CAS  Google Scholar 

  19. G. Qu, Y. Bai, Y. Zhang, Q. Jia, W. Zhang, B. Yan, Carbon N Y 47, 2060 (2009)

    Article  CAS  Google Scholar 

  20. Z. Amirsardari, R.M. Aghdam, M. Salavati-Niasari, S. Shakhesi, J. Therm. Anal. Calorim. 120, 1535 (2015)

    Article  CAS  Google Scholar 

  21. F.A. Girardi, G.E. Bruch, C.S. Peixoto, L. Dal Bosco, S.K. Sahoo, C.O.F. Gonçalves, A.P. Santos, C.A. Furtado, C. Fantini, D.M. Barros, J. Appl. Toxicol. 37, 214 (2017)

    Article  CAS  Google Scholar 

  22. K. Fujita, S. Obara, J. Maru, S. Endoh, Toxicol. Mech. Methods 30, 477 (2020)

    Article  CAS  Google Scholar 

  23. M.R. Azari, Y. Mohammadian, J. Pourahmad, F. Khodagholi, Y. Mehrabi, Environ. Res. 183, 109219 (2020)

    Article  CAS  Google Scholar 

  24. J. Czarnecka, M. Wiśniewski, N. Forbot, P. Bolibok, A.P. Terzyk, K. Roszek, Materials 13, 2060 (2020)

    Article  CAS  Google Scholar 

  25. M. Rezazadeh Azari, Y. Mohammadian, Environ. Sci. Pollut. Res. 27, 15401 (2020)

    Article  CAS  Google Scholar 

  26. A.J. Taylor-Just, M.D. Ihrie, K.S. Duke, H.Y. Lee, D.J. You, S. Hussain, V.K. Kodali, C. Ziemann, O. Creutzenberg, A. Vulpoi, Part. Fibre Toxicol. 17, 1 (2020)

    Article  CAS  Google Scholar 

  27. E.K.-H. Chow, M. Gu, J. Xu, in Nanoparticles for Biomedical Applications (Elsevier, 2020), pp. 223–242.

  28. Y. You, N. Wang, L. He, C. Shi, D. Zhang, Y. Liu, L. Luo, T. Chen, Dalton Trans. 48, 1569 (2019)

    Article  CAS  Google Scholar 

  29. S. Taghavi, A.H. Nia, K. Abnous, M. Ramezani, Int. J. Pharm. 516, 301 (2017)

    Article  CAS  Google Scholar 

  30. Y. Seo, C. Park, J. Son, K. Lee, J. Hwang, Y. Jo, D. Lee, M. S. Khan, S. G. Chavan, and Y. Choi, JoVE, e57384 (2018)

  31. H.-B. Kim, B. Jin, D.K. Patel, J.-W. Kim, J. Kim, H. Seonwoo, K.-T. Lim, IEEE Trans. Nanobiosci. 18, 463 (2019)

    Article  Google Scholar 

  32. P.A. Christy, A.J. Peter, S. Arumugam, C.W. Lee, P.S. Prakash, Mater. Chem. Phys. 240, 122207 (2020)

    Article  CAS  Google Scholar 

  33. I. Younes, M. Rinaudo, Mar. Drugs 13, 1133 (2015)

    Article  CAS  Google Scholar 

  34. S. Gómez, N.M. Rendtorff, E.F. Aglietti, Y. Sakka, G. Suarez, Chem. Phys. Lett. 689, 135 (2017)

    Article  CAS  Google Scholar 

  35. J. Razzokov, P. Marimuthu, K. Saidov, O. Ruzimuradov, S. Mamatkulov, Curr. Comput.-Aided Drug Des. 11, 1174 (2021)

    CAS  Google Scholar 

  36. S. Gholizadeh, F. Moztarzadeh, N. Haghighipour, L. Ghazizadeh, F. Baghbani, M.A. Shokrgozar, Z. Allahyari, Int. J. Biol. Macromol. 97, 365 (2017)

    Article  CAS  Google Scholar 

  37. S. Mallakpour, E. Azadi, C.M. Hussain, New J. Chem. 45, 3756 (2021)

    Article  CAS  Google Scholar 

  38. M. Azmana, S. Mahmood, A.R. Hilles, A. Rahman, M.A. Bin Arifin, S. Ahmed, Int. J. Biol. Macromol. 185, 832 (2021)

    Article  CAS  Google Scholar 

  39. N. Kittana, M. Assali, W.-H. Zimmermann, N. Liaw, G.L. Santos, A. Rehman, S. Lutz, Int. J. Nanomed. 16, 989 (2021)

    Article  Google Scholar 

  40. K.S. Wisdom, I.A. Bhat, T.I. Chanu, P. Kumar, G.-B. Pathakota, S.K. Nayak, P. Walke, R. Sharma, Int. J. Biol. Macromol. 155, 697 (2020)

    Article  CAS  Google Scholar 

  41. T.A. Saleh, Appl. Surf. Sci. 257, 7746 (2011)

    Article  CAS  Google Scholar 

  42. Z. Wu, W. Feng, Y. Feng, Q. Liu, X. Xu, T. Sekino, A. Fujii, M. Ozaki, Carbon N Y 45, 1212 (2007)

    Article  CAS  Google Scholar 

  43. H. Qiu, J. Yang, in Industrial Applications of Carbon Nanotubes (Elsevier, 2017), pp. 47–69.

  44. Y. Zhang, S. Huang, RSC Adv. 6, 26210 (2016)

    Article  CAS  Google Scholar 

  45. N. Hsan, P.K. Dutta, S. Kumar, N. Das, J. Koh, J. CO2 Util. 41, 101237 (2020)

    Article  CAS  Google Scholar 

  46. V.Y. Zenou, S. Bakardjieva, Mater. Charact. 144, 287 (2018)

    Article  CAS  Google Scholar 

  47. Y.N. Kulchin, Y.A. Zinin, V.A. Kolchinskiy, Pac. Sci. Rev. A: Nat. Sci. Eng. 17, 38 (2015)

    Google Scholar 

  48. A. Aryaei, A.H. Jayatissa, A.C. Jayasuriya, J. Biomed. Mater. Res., Part A 102, 2704 (2014)

    Article  CAS  Google Scholar 

  49. M.S. Dresselhaus, G. Dresselhaus, M. Hofmann, Vib. Spectrosc. 45, 71 (2007)

    Article  CAS  Google Scholar 

  50. S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Carbon 45, 1558 (2007)

    Article  CAS  Google Scholar 

  51. A.C. Ferrari, J. Robertson, Philos. Trans. R. Soc. Lond. Ser. A: Math. Phys. Eng. Sci. 362, 2477 (2004)

    Article  CAS  Google Scholar 

  52. E. Flahaut, C. Laurent, A. Peigney, Carbon N Y 43, 375 (2005)

    Article  CAS  Google Scholar 

  53. D. Luo, G. Zhang, J. Liu, X. Sun, J. Phys. Chem. C 115, 11327 (2011)

    Article  CAS  Google Scholar 

  54. Y. Jiang, H. Zhang, Y. Wang, M. Chen, S. Ye, Z. Hou, L. Ren, PLoS ONE 8, e65756 (2013)

    Article  CAS  Google Scholar 

  55. P. Yadav, R. Ajore, L.M. Bharadwaj, J. Nanotechnol. Online 5, (2009)

  56. J.H. Yoon, S.-M. Kim, H.J. Park, Y.K. Kim, D.X. Oh, H.-W. Cho, K.G. Lee, S.Y. Hwang, J. Park, B.G. Choi, Biosens. Bioelectron. 150, 111946 (2020)

    Article  CAS  Google Scholar 

  57. C.A. Schneider, W.S. Rasband, K.W. Eliceiri, Nat. Methods 9, 671 (2012)

    Article  CAS  Google Scholar 

  58. S.-T. Kang, J.-Y. Seo, S.-H. Park, Adv. Mater. Sci. Eng. 2015, (2015)

  59. D.G. Zarate-Triviño, E. Prokhorov, G. Luna-Bárcenas, J. Mendez-Nonell, J.B. González-Campos, E. Elizalde-Peña, J.D. Mota-Morales, P. Santiago-Jacinto, M. Terrones, S. Gómez-Salazar, Mater. Chem. Phys. 155, 252 (2015)

    Article  CAS  Google Scholar 

  60. E.R. Edwards, E.F. Antunes, E.C. Botelho, M.R. Baldan, E.J. Corat, Appl. Surf. Sci. 258, 641 (2011)

    Article  CAS  Google Scholar 

  61. H.J. Park, M. Park, J.Y. Chang, H. Lee, Nanotechnology 19, 335702 (2008)

    Article  CAS  Google Scholar 

  62. I. Montes-Zavala, E.O. Castrejón-González, V. Rico-Ramírez, E. Pérez, D.A. Santamaría-Razo, J.A. González-Calderón, J. Dispers. Sci. Technol. 42, 1338 (2021)

    Article  CAS  Google Scholar 

  63. D. Shao, J. Hu, X. Wang, Plasma Processes Polym. 7, 977 (2010)

    Article  CAS  Google Scholar 

  64. Y.-B. Choi, H.-S. Kim, W.-Y. Jeon, B.-H. Lee, U.S. Shin, H.-H. Kim, Biochem. Eng. J. 144, 227 (2019)

    Article  CAS  Google Scholar 

  65. P. Cañete-Rosales, V. Ortega, A. Álvarez-Lueje, S. Bollo, M. González, A. Ansón, M.T. Martínez, Electrochim. Acta 62, 163 (2012)

    Article  CAS  Google Scholar 

  66. W. Feng, Y. Li, P. Ji, AIChE J. 58, 285 (2012)

    Article  CAS  Google Scholar 

  67. I.V. Novikov, M.A. Pigaleva, E.E. Levin, S.S. Abramchuk, A.V. Naumkin, H. Li, A. Pich, M.O. Gallyamov, Colloid Polym. Sci. 298, 1135 (2020)

    Article  CAS  Google Scholar 

  68. S. Gómez, N.M. Rendtorff, E.F. Aglietti, Y. Sakka, G. Suárez, Appl. Surf. Sci. 379, 264 (2016)

    Article  CAS  Google Scholar 

  69. Z. Wang, Y. Yan, X. Shen, T. Qian, J. Wang, Q. Sun, C. Jin, Polymers 10, 341 (2018)

    Article  CAS  Google Scholar 

  70. J.H. Chen, W.Z. Li, D.Z. Wang, S.X. Yang, J.G. Wen, Z.F. Ren, Carbon N Y 40, 1193 (2002)

    Article  CAS  Google Scholar 

  71. S. Wei, W.P. Kang, J.L. Davidson, J.H. Huang, Diam. Relat. Mater. 17, 906 (2008)

    Article  CAS  Google Scholar 

  72. B.-W. Kim, H.-G. Chung, B.-K. Min, H.-G. Kim, W. Kim, Bull. Korean Chem. Soc. 31, 3697 (2010)

    Article  CAS  Google Scholar 

  73. C.-Y. Ma, S.-C. Huang, P.-H. Chou, W. Den, C.-H. Hou, Chemosphere 146, 113 (2016)

    Article  CAS  Google Scholar 

  74. Y.-H. Liu, T.-C. Yu, Y.-W. Chen, C.-H. Hou, ACS Sustain. Chem. Eng. 6, 3196 (2017)

    Article  CAS  Google Scholar 

  75. L.E. Helseth, J. Energy Storage 35, 102304 (2021)

    Article  Google Scholar 

  76. S. Karthikeyan, B. Narenthiran, A. Sivanantham, L.D. Bhatlu, T. Maridurai, Mater. Today: Proc. 46, 3984 (2021)

    CAS  Google Scholar 

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Acknowledgements

The authors too wish to acknowledge some financial support from: Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES), and the Laboratório Multiusuário de Microscopia de Alta Resolução – LabMic for the HRTEM micrographs.

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Authors and Affiliations

  1. Postgraduate Program in Mechanical Engineering, Center of Technology, Federal University of Rio Grande do Norte, Av. Sen. Salgado Filho, 3000, Natal, RN, CEP 59072-970, Brazil

    E. B. N. Holanda, R. Ladchumananandasivam & J. H. O. Nascimento

  2. Postgraduate Program in Textile Engineering, Center of Technology, Federal University of Rio Grande do Norte, Av. Sen. Salgado Filho, 3000, Natal, RN, CEP 59072-970, Brazil

    R. L. B. Cabral, F. M. F. Galvão & J. H. O. Nascimento

  3. LSQM – Laboratory of Chemical Synthesis of Materials – Department of Materials Engineering, Federal University of Rio Grande do Norte – UFRN, P.O. Box 1524, Natal, RN, Brazil

    N. F. A. Neto

  4. Environmental and Applied Electrochemical Laboratory, School of Science and Technology, Federal University of Rio Grande do Norte, Lagoa Nova, Natal, CEP 59078-970, Brazil

    J. E. L. Santos & E. V. Santos

  5. Department of Phisics, Federal University of Rio Grande do Norte, Natal, RN, 59078-900, Brazil

    F. Bohn

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  1. E. B. N. Holanda
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Contributions

E.B.N.H: Conceptualization, methodology, validation, formal analysis, investigation, resources, writing—original draft preparation. R.L.B.C: Formal analysis, writing—original draft preparation, writing—review and editing and visualization. R.L.: Validation and formal analysis. N.F.A.N: Formal analysis, writing—original draft preparation and visualization. J.E.L.S: Investigation and data curation. E. V. S.: Validation and data curation. F. M. F. G.: Investigation and data curation, F.B.: Investigation and data curation. J.H.O.N: Conceptualization, formal analysis, resources, data curation, writing—original draft preparation, writing—review and editing, visualization, supervision and funding acquisition.

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Holanda, E.B.N., Cabral, R.L.B., Ladchumananandasivam, R. et al. An electrochemical and magnetic approach for /H2SO4/HNO3/chitosan functionalized multi-wall carbon nanotubes stable solutions. J Mater Sci: Mater Electron 33, 21409–21424 (2022). https://doi.org/10.1007/s10854-022-08933-z

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