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Development of solvate ionic liquid immobilized MCM-41 ionogel electrolytes for lithium battery

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Abstract

Compared to liquid electrolytes, solid electrolytes have shown better performance on safety requirements and energy densities. However, the further application of solid electrolytes is still limited due to the large interface resistance between electrolyte and electrode. In this study, a quasi-solid electrolyte prepared by ordered mesoporous MCM-41 (Mobil Composition of Matter No. 41) was developed to solve this problem. For this electrolyte, the solvated ionic liquids could be immobilized within inorganic mesoporous material by coupled molecular sieve. The electrochemical characteristics, including lithium-ion conductivity at ambient temperature, ion mobility, resistance for lithium dendrite, corrosion resistance, and interfacial resistance between electrolyte and electrode were all improved significantly. This resulted in enhanced electrochemical performance, including high room temperature lithium-ion conductivity, improved ion migration number, enhanced lithium dendrite resistance, good corrosion resistance, and low interfacial resistance between electrolyte and electrode. Moreover, the long shelf life of the prepared electrolytes, of over 1 year, increases the product’s convenience and provides an opportunity. The assembly cell of Li|LiFePO4 displayed discharge capacity of 126 mAh/g with capacity retention of 88% after more than 1500 cycles, demonstrating high electrochemical performance and promising application.

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Data availability

The data that support the finding of this study are available from the corresponding author upon reasonable request.

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Funding

This work was supported by entrepreneurial Program of Foshan National Hi-tech Industrial Development Zone.

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Authors and Affiliations

  1. School of Mechanical and Electrical Engineering, Guangzhou University, 510006, Guangzhou, China

    Bowen Xie & Heming He

  2. School of Civil Engineering, Guangzhou University, 510006, Guangzhou, China

    Shuangyan Lu & Wenshi Zheng

  3. School of Chemistry and Chemical Engineering, Guangzhou University, 510006, Guangzhou, China

    Jiawei Cai, Zhangxin Lai & Zhihui Ding

Authors
  1. Shuangyan Lu
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  2. Jiawei Cai
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  3. Wenshi Zheng
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  4. Zhangxin Lai
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  5. Bowen Xie
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  6. Zhihui Ding
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  7. Heming He
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Contributions

SL was responsible for the experimental testing, writing and design of the article. JC was responsible for experimental testing. WZ was responsible for the collection of data, and ZL was responsible for the making of schematic diagrams. BX was responsible for characterization tests. ZD was responsible for correcting information. HH was responsible for the design and control of the article. The first draft of the manuscript was written by SL and all authors commented on previous versions of the manuscript. All authors have read and approved the final manuscript.

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Correspondence to Heming He.

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Lu, S., Cai, J., Zheng, W. et al. Development of solvate ionic liquid immobilized MCM-41 ionogel electrolytes for lithium battery. J Mater Sci: Mater Electron 33, 18621–18631 (2022). https://doi.org/10.1007/s10854-022-08713-9

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  • DOI: https://doi.org/10.1007/s10854-022-08713-9

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