Abstract
The sensing performance of gas sensitive materials can be improved by adjusting their microstructure and electronic structure. In this work, ZnSnO3–NiO heterostructures are synthesized by co-precipitation and annealing treatment. The crystal structure, morphology and surface chemical composition of the samples are characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. Subsequently, the performance of the sensors based on the above samples is tested. The results show that the sensor has the best performance when the molar ratio of Ni/Zn is 1:2. Specifically, the 2ZnSnO3–NiO-based sensor shows not only high response value (21.1) and fast response speed (1 s) to 100 ppm acetone at 260 °C, but also good repeatability and long-term stability. In addition, the improved gas sensing mechanism is analyzed in detail. Therefore, ZnSnO3–NiO heterostructures are expected to be a candidate material for the detection of acetone gas.
Similar content being viewed by others
Data availability
The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.
References
X.M. Zhang, Z.J. Dong, S.R. Liu, Y. Shi, Y.H. Dong, W. Feng, Sens. Actuators B Chem. 243, 1224 (2017)
M. Righettoni, A. Tricoli, S.E. Pratsinis, Anal. Chem. 82, 3571 (2010)
C.H. Deng, J. Zhang, X.F. Yu, W. Zhang, X.M. Zhang, J. Chromatogr. 810, 269 (2004)
J.Z. Zhang, Y. Yan, J. Mater. Sci. 52, 13711 (2017)
J. Sun, Q. Wei, P. Song, Z. Yang, Q. Wang, J. Mater. Sci. Mater. Electron. 31, 838 (2019)
X.X. Huang, Z.Y. Tang, Z.P. Tan, S.H. Sheng, Q. Zhao, J. Mater. Sci. Mater. Electron. 32, 11857 (2021)
J. Cao, N.R. Zhang, S.M. Wang, H.M. Zhang, J. Colloid Interface Sci. 577, 19 (2020)
L.Y. Du, P.D. Xiao, Y. Liu, C.B. Zhai, D.X. Wang, M.Z. Zhang, J. Alloys Compd. 828, 154463 (2020)
M. Akbari-Saatlu, M. Procek, C. Mattsson, G. Thungstrom, H.E. Nilsson, W.J. Xiong, B.Q. Xu, Y. Li, H.H. Radamson, Nanomaterials 10, 2215 (2020)
K.Y. Lee, J.C. Hsleh, C.A. Chen, W.L. Chen, H.F. Meng, C.J. Lu, S.F. Hong, H.W. Zan, Sens. Actuators B Chem. 326, 128988 (2021)
J. Casanova-Chafer, R. Garcia-Aboal, P. Atienzar, E. Llobet, Chem. Commun. 56, 8956 (2020)
M.K. Lo, S.Y. Lee, K.S. Chang, J. Phys. Chem. C 119, 5218 (2015)
Y.T. Ma, Q.S. Xie, X. Liu, Y.C. Zhao, D.Q. Zeng, L.S. Wang, Y. Zheng, D.L. Peng, Electrochim. Acta 182, 327 (2015)
L. Wang, X. Li, Q.Q. Li, Y.H. Zhao, R.C. Che, ACS Appl. Mater. Interfaces 10, 22602 (2018)
T.T. Zhou, T. Zhang, R. Zhang, Z. Lou, J.N. Deng, L.L. Wang, ACS Appl. Mater. Interfaces 9, 14525 (2017)
D. Wang, X.X. Pu, X. Yu, L.P. Bao, Y. Chen, J.C. Xu, S.N. Han, Q.X. Ma, X.Y. Wang, J. Colloid Interface Sci. 608, 1074 (2022)
B.S. Sa, C.A. Zito, T.M. Perfecto, D.P. Volanti, Sens. Actuators B Chem. 338, 129869 (2021)
Y. Xiong, W.W. Xu, Z.Y. Zhu, Q.Z. Xue, W.B. Lu, D.G. Ding, L. Zhu, Sens. Actuators B Chem. 253, 523 (2017)
D.R. Miller, S.A. Akbar, P.A. Morris, Sens. Actuators B Chem. 204, 250 (2014)
S. Yu, X. Jia, J. Yang, S. Wang, Y. Li, H. Song, Mater. Lett. 291, 129531 (2021)
C. Jin, H. Kim, S. An, C. Lee, Ceram. Int. 38, 5973 (2012)
K. Xu, W. Zhao, X. Yu, S. Duan, W. Zeng, Physica E 117, 113825 (2020)
M. Yang, J. Lu, X. Wang, H. Zhang, F. Chen, J. Sun, J. Yang, Y. Sun, G. Lu, Sens. Actuators B Chem. 313, 127965 (2020)
M. Ullah, H. Lv, Z. Liu, X. Bai, J. Chen, Y. Zhang, J. Wang, B. Sun, L. Li, K. Shi, Appl. Surf. Sci. 550, 149368 (2021)
H.Y. Liu, Z.Y. Wang, G.L. Cao, G.F. Pan, X.L. Yang, M.Y. Qiu, C.X. Sun, J.K. Shao, Z.H. Li, H. Zhang, Mater. Sci. Semicond. Process. 141, 106435 (2022)
D. Meng, T.T. Qiao, G.S. Wang, Y.B. Shen, X.G. San, Y.B. Pan, F.L. Meng, Appl. Surf. Sci. 577, 151877 (2022)
L.Y. Du, K.K. Gu, M.M. Zhu, J. Zhang, M.Z. Zhang, Sens. Actuators B Chem. 288, 298 (2019)
T.Y. Yang, K.K. Gu, M.M. Zhu, Q. Lu, C.B. Zhai, Q. Zhao, X.D. Yang, M.Z. Zhang, Sens. Actuators B Chem. 279, 410 (2019)
H. Wang, X.Z. Yuan, Y. Wu, G.M. Zeng, W.G. Tu, C. Sheng, Y.C. Deng, F. Chen, J.W. Chew, Appl. Catal. B Environ. 209, 543 (2017)
Y.D. Wang, T. Cheng, Electrochim. Acta 54, 3510 (2009)
S.L. Bai, Y. Tian, Y.H. Zhao, H. Fu, P.G. Tang, R.X. Tang, D.Q. Li, A.F. Chen, C.C. Liu, Sens. Actuators B Chem. 259, 908 (2018)
D. Meng, D.Y. Liu, G.S. Wang, Y.B. Shen, X.G. San, M. Li, F.L. Meng, Sens. Actuators B Chem. 273, 418 (2018)
Q. Chen, S.Y. Ma, H.Y. Jiao, G.H. Zhang, H. Chen, X.L. Xu, H.M. Yang, Z. Qiang, Ceram Int. 43, 1617 (2017)
J.R. Huang, X.J. Xu, C.P. Gu, W.Z. Wang, B.Y. Geng, Y.F. Sun, J.H. Liu, Sens. Actuators B Chem. 171–172, 572 (2012)
Y.J. Chen, L. Yu, Q. Li, Y. Wu, Q.H. Li, T.H. Wang, Nanotechnology 23, 415501 (2012)
L.Z. Lu, A.Q. Zhang, Y.H. Xiao, F.L. Gong, D.Z. Jia, F. Li, Mater Sci. Eng B. 177, 942 (2012)
C. Liu, B.Q. Wang, T. Liu, P. Sun, Y. Gao, F.M. Liu, G.Y. Lu, Sens. Actuators B Chem. 235, 294 (2016)
K. Jain, R.P. Pant, S.T. Lakshmikumar, Sens. Actuators B Chem. 113, 823 (2006)
Funding
The work was funded by the Natural Science Foundation of Shanxi Province (Grant No. 202103021223004), Fundamental Research Fund of Taiyuan University (Grant No. 21TYKQ21).
Author information
Authors and Affiliations
Contributions
The Conceptualization, Data curation, Formal analysis, Investigation, Methodology, Writing—original draft and Writing—review and editing were performed by LD. The Investigation and Formal analysis were performed by HS.
Corresponding author
Ethics declarations
Conflict of interest
The authors have no relevant financial or non-financial interest to disclose.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Du, L., Sun, H. Facile fabrication and enhanced gas sensing properties of ZnSnO3/NiO heterostructures. J Mater Sci: Mater Electron 33, 15734–15741 (2022). https://doi.org/10.1007/s10854-022-08475-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-022-08475-4