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One-pot synthesis of Mn-doped goethite composite for enhanced supercapacitor performance and charge storage mechanism

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Abstract

A simplistic synthesis of Mn & Fe (manganese & iron)-based composites with high surface area for energy storage application is presented here. We have successfully synthesized Mn-doped iron oxide composite through co-precipitation method. Nanorod-shaped particles with high surface area is formed with uniform distribution of Fe, Mn, & O. The nanocomposite is then used as electrodes in supercapacitor study. The obtained nanostructures have less than 100 nm particle size with surface area of 153 m2 g−1. The composite exhibits high specific capacitance of ~ 387.9 F g−1 at 2.5 A g−1 current density with corresponding specific power density of 1250 W kg−1 and energy density of ~ 146 Wh kg−1. Further the electrode materials were also demonstrated using Trasatti and Dunn’s method revealing the diffusion-controlled storage process as being dominant in the contribution towards the total capacitance for the supercapacitor. The results indicate that Mn-doped iron oxide nanorods have great potential as energy storage material.

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All data generated or analysed during the current study are available from the corresponding author on reasonable request.

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Acknowledgements

RB is thankful to DST Inspire Division (Govt. of India) for Inspire Fellowship.

Funding

The authors are thankful to Ministry of Science and Technology, Department of Science and Technology, India and CSIR-Institute of Minerals and Materials Technology, Bhubaneswar Odisha for financial support.

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Authors and Affiliations

  1. Hydro and Electrometallurgy Department, CSIR-Institute of Minerals and Materials Technology, Pin-751013, Bhubaneswar, India

    Rasmita Barik & Mamata Mohapatra

  2. School of Nanoscience and Technology, Indian Institute of Technology, Kharagpur, India

    Biraj K. Satpathy

  3. Chemical and Metallurgical Engineering & Chemistry, School of Engineering and Information Technology, Murdoch University, 90 South Street, Murdoch, Perth, WA, 6150, Australia

    Aleksandar N. Nikoloski

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  1. Rasmita Barik
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Contributions

Conceptualization, methodology, experiments, electrochemical analysis, and writing are done by RB. BKS helped in carrying out electrochemical analysis. ANN revised the manuscript. Conceptualization, methodology, and writing are done by MM. All authors have given approval to the final version of the manuscript.

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Correspondence to Mamata Mohapatra.

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Barik, R., Satpathy, B.K., Nikoloski, A.N. et al. One-pot synthesis of Mn-doped goethite composite for enhanced supercapacitor performance and charge storage mechanism. J Mater Sci: Mater Electron 33, 11661–11675 (2022). https://doi.org/10.1007/s10854-022-08123-x

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