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Preparation and dielectric properties of multilayer Ag@FeNi-MOF/PVDF composites

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Abstract

Ag@FeNi-MOF/PVDF multilayer polymer nanocomposites with high dielectric properties were designed and prepared in this paper, and their theoretical simulation was carried out through COMSOL Multiphysics 5.4, which verified the advantages of multilayer structure design. Ag@FeNi-MOF two-dimensional hybrid nanosheets were prepared by hydrothermal reaction in the experiment, which were doped into PVDF matrix as fillers to obtain monolayer films, and then combined with pure PVDF film by hot pressing to achieve multilayer structure. The results showed that the multilayer structure could effectively improve the energy storage density and breakdown field strength. When the number of film layers were 1, 3, 5 and 7, the energy storage density were 8.01, 8.482, 8.822 and 9.467 J/cm3, and the breakdown field strength were 2239, 2500, 2700 and 2850 kV/cm. Compared with layer 1, the energy storage density of layer 7 increased by 18.1%, and the breakdown field strength increased by 27.3%. This study proved that the multilayer structure design had positive significance in improving the dielectric properties of polymer nanocomposites.

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Data availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Acknowledgements

First of all, we would like to thank Professor Weng Ling for his kind guidance. Professor Weng is the guiding light and guides on my scientific research road, and the strong backing for my scientific research achievements. Weng teacher wisdom agile, self-discipline and enterprising, is a good example of my study. Thank Mr. Weng for his hard work and painstaking effort in correcting all my papers, regardless of the cost. Weng teacher's teachings such as spring weathering Yu peach and plum, moisten things silent sprinkle Chunhui, so that I benefit for life. We would like to thank Mr. Zhu Xingsong and Mr. Wang Cheng, the experimental teachers of polymer major, for their help in the test. Thanks to Mr. Chen Hongtao, Mr. Ma Chengguo and Mr. Liu Junwang of the Analysis and Testing Center of the School of Materials for their help in analysis and testing.

Funding

This work was funded by the National Natural Science Foundation of China (No. 51677045), the outstanding young talents project of Harbin University of Science and Technology (2019-KYYWF-0206), and the Harbin Science and Technology Innovation Talents Project (No. 2016RAQXJ059).

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Authors and Affiliations

  1. College of Material Science and Engineering, Harbin University of Science and Technology, No. 4 Linyuan Road, Xiangfang District, Harbin, 150040, Heilongjiang, People’s Republic of China

    Xingyu Shen, Chao Han, Xinwei Tao, Mingting Zhang, Dandan Meng, Ling Weng, Junwang Liu & Lizhu Guan

  2. Key Laboratory of Engineering Dielectric and Its Application, Harbin University of Science and Technology, Ministry of Education, Harbin, 150040, People’s Republic of China

    Ling Weng

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  1. Xingyu Shen
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Contributions

The first three authors of this paper have made significant contributions to this paper, and the same contributions. XS: responsible for experimental design, writing-review & editing, CH, XT: analysis of experimental data, writing-review & editing, MZ, DM: investigation, visualization, LW, LG: resources, supervision, JL: data curation.

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Correspondence to Ling Weng, Junwang Liu or Lizhu Guan.

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Shen, X., Han, C., Tao, X. et al. Preparation and dielectric properties of multilayer Ag@FeNi-MOF/PVDF composites. J Mater Sci: Mater Electron 33, 5311–5324 (2022). https://doi.org/10.1007/s10854-022-07722-y

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