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Facile synthesis, morphological, structural, photocatalytic, and optical properties of ZnFe2O4 nanostructures

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Abstract

Spinel ferrite ZnFe2O4 nanostructures have been prepared as sunlight responsive photocatalysts via facile co-precipitation method. The structural, morphological, and optical responses were diligently characterized using XRD, Raman spectroscopy, FESEM, and UV–Vis absorption spectroscopy, respectively. FESEM studies revealed nanoparticles and porous-like nanoparticle aggregates, found to be of cubic spinel ZnFe2O4 from XRD and Raman studies. Crystallite size varied from 5 to 13.6 nm, whereas band gap changed from 1.89 to 1.95 eV with CTAB concentration variation. ZnFe2O4 nanostructures were employed for sunlight-assisted photodegradation of organic pollutants such as MB, MG, and MO dyes in water. The synthesized ZnFe2O4 nanoparticle aggregates with porous-like morphology with crystallite size of 9.2 nm showed superior photocatalytic response and decomposed 80.4% of MB dye in only 40 min. The superiority of the porous-like ZnFe2O4 nanoparticle aggregates was mainly ascribed to its optimal crystallite size, narrower band gap, and improved sunlight utilization efficiency. A plausible mechanism of photocatalytic oxidation of dye supported by scavenger studies has also been proposed. The synthesized ZnFe2O4 nanostructures have easy magnetic recycling property along with excellent photocatalytic capability and hold potential for the treatment of contaminated water.

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References

  1. H. Anwer, A. Mahmood, J. Lee, K.H. Kim, J.W. Park, A.C.K. Yip, Nano Res. 12, 955–972 (2019)

    Article  CAS  Google Scholar 

  2. E.M. Dias, C. Petit, J. Mater. Chem. A 3, 22484–22506 (2015)

    Article  CAS  Google Scholar 

  3. S. Choudhary, K. Sahu, A. Bisht, R. Singhal, S. Mohapatra, Appl. Surf. Sci. 503, 144102–144112 (2020)

    Article  CAS  Google Scholar 

  4. F.A. Jumeri, H.N. Lim, S.N. Ariffin, N.M. Huang, P.S. Teo, S.O. Fatin, C.H. Chia, I. Harrison, Ceram. Int. 40, 7057–7065 (2014)

    Article  CAS  Google Scholar 

  5. F. Xu, Y. Shen, L. Sun, H. Zeng, Y. Lu, Nanoscale 3, 5020–5025 (2011)

    Article  CAS  Google Scholar 

  6. S. Malato, P. Fernández-Ibáñez, M.I. Maldonado, J. Blanco, W. Gernjak, Catal. Today 147, 1–59 (2009)

    Article  CAS  Google Scholar 

  7. G. Moussavi, M. Mahmoudi, Chem. Eng. J. 152, 1–7 (2009)

    Article  CAS  Google Scholar 

  8. A.N. Kagalkar, R.V. Khandare, S.P. Govindwar, RSC Adv. 5, 80505–80514 (2015)

    Article  CAS  Google Scholar 

  9. L. Wang, J. Li, Y. Wang, L. Zhao, Q. Jiang, Chem. Eng. J. 181, 72–79 (2012)

    Article  CAS  Google Scholar 

  10. Q. Sun, K. Li, S. Wu, B. Han, L. Sui, L. Dong, New J. Chem. 181, 1942–1952 (2020)

    Article  Google Scholar 

  11. S.S. Phugare, D.C. Kalyani, A.V. Patil, J.P. Jadhav, J. Hazard. Mater. 186, 713–723 (2011)

    Article  CAS  Google Scholar 

  12. X. Zhang, J. Qin, Y. Xue, P. Yu, B. Zhang, L. Wang, R. Liu, Sci. Rep. 4, 4596–4604 (2014)

    Article  CAS  Google Scholar 

  13. K. Tezuka, M. Kogure, Y.J. Shan, Catal. Commun. 48, 11–14 (2014)

    Article  CAS  Google Scholar 

  14. S. Xuan, W. Jiang, X. Gong, Y. Hu, Z. Chen, J. Phys. Chem. C 113, 553–558 (2009)

    Article  CAS  Google Scholar 

  15. S.K. Cushing, F. Meng, J. Zhang, B. Ding, C.K. Chen, C.J. Chen, R.S. Liu, A.D. Bristow, P. Zheng, J. Bright, N. Wu, ACS Catal. 7, 1742–1748 (2017)

    Article  CAS  Google Scholar 

  16. D. Jassby, J.F. Budarz, M. Wiesner, Environ. Sci. Technol. 46, 6934–6941 (2012)

    Article  CAS  Google Scholar 

  17. S. Choudhary, K. Sahu, A. Bisht, S. Mohapatra, Appl. Surf. Sci. 541, 148484–148495 (2021)

    Article  CAS  Google Scholar 

  18. A. Ajmal, I. Majeed, R.N. Malik, H. Idriss, M.A. Nadeem, RSC Adv. 4, 37003–37026 (2014)

    Article  CAS  Google Scholar 

  19. S. Choudhary, A. Bisht, S. Mohapatra, Ceram. Int. 47, 3833–3841 (2021)

    Article  CAS  Google Scholar 

  20. T. Soltani, M.H. Entezari, Ultrason. Sonochem. 20, 1245–1253 (2013)

    Article  CAS  Google Scholar 

  21. M. Shahid, L. Jingling, Z. Ali, I. Shakir, M.F. Warsi, R. Parveen, M. Nadeem, Mater. Chem. Phys. 139, 566–571 (2013)

    Article  CAS  Google Scholar 

  22. P. Bhattacharya, S. Dhibar, G. Hatui, A. Mandal, T. Das, C.K. Das, RSC Adv. 4, 17039–17053 (2014)

    Article  CAS  Google Scholar 

  23. S. Chakraborty, M. Pal, New J. Chem. 42, 7188–7196 (2018)

    Article  CAS  Google Scholar 

  24. H. Yang, X. Bai, P. Hao, J. Tian, Y. Bo, X. Wang, H. Liu, Sens. Actuators B Chem. 280, 34–40 (2019)

    Article  CAS  Google Scholar 

  25. C.M. Park, Y.M. Kim, K.H. Kim, D. Wang, C. Su, Y. Yoon, Chemosphere 221, 392–402 (2019)

    Article  CAS  Google Scholar 

  26. R. Sharma, P. Thakur, M. Kumar, P. Sharma, V. Sharma, J. Alloys Compd. 746, 532–539 (2018)

    Article  CAS  Google Scholar 

  27. Z. Zhang, Y. Wang, Q. Tan, Z. Zhong, F. Su, J. Colloid Interface Sci. 398, 185–192 (2013)

    Article  CAS  Google Scholar 

  28. R. Shu, G. Zhang, J. Zhang, X. Wang, M. Wang, Y. Gan, J. Shi, J. He, J. Alloys Compds. 736, 1–11 (2018)

    Article  CAS  Google Scholar 

  29. E. Casbeer, V.K. Sharma, X.Z. Li, Sep. Purif. Technol. 87, 1–14 (2012)

    Article  CAS  Google Scholar 

  30. P. Jing, J. Li, L. Pan, J. Wang, X. Sun, Q. Liu, J. Hazard. Mater. 284, 163–170 (2015)

    Article  CAS  Google Scholar 

  31. V.A.F. Samson, S.B. Bernadsha, M. Mahendiran, K.L. Lawrence, J. Madhavan, M.V.A. Raj, S. Prathap, J. Mater. Sci. Mater. Electron. 31, 6574–6585 (2020)

    Article  CAS  Google Scholar 

  32. H.Y. He, J. Lu, Sep. Purif. Technol. 172, 374–381 (2017)

    Article  CAS  Google Scholar 

  33. M. Pal, R. Rakshit, K. Mandal, ACS Appl. Mater. Interfaces 6, 4903–4910 (2014)

    Article  CAS  Google Scholar 

  34. A. Behera, D. Kandi, S.M. Majhi, S. Martha, K. Parida, Beilstein J. Nanotechnol. 9, 436–446 (2018)

    Article  CAS  Google Scholar 

  35. S. Mohan, B. Subramanian, G. Sarveswaran, J. Mater. Chem. C 2, 6835–6842 (2014)

    Article  CAS  Google Scholar 

  36. Y. Cao, X. Lei, Q. Chen, C. Kang, W. Li, B. Liu, J. Photochem. Photobiol. A 364, 794–800 (2018)

    Article  CAS  Google Scholar 

  37. N. Sapna, V. Budhiraja, S.K. Singh, Ceram. Inter. 45, 1067–1076 (2019)

    Article  CAS  Google Scholar 

  38. R. Dom, R. Subasri, N.Y. Hebalkar, A.S. Chary, P.H. Borse, RSC Adv. 2, 12782–12791 (2012)

    Article  CAS  Google Scholar 

  39. M. Dhiman, R. Sharma, V. Kumar, S. Singhal, Ceram. Int. 42, 12594–12605 (2016)

    Article  CAS  Google Scholar 

  40. X. Li, Y. Hou, Q. Zhao, L. Wang, J. Colloid Interface Sci. 358, 102–108 (2012)

    Article  CAS  Google Scholar 

  41. S. Wu, Y. Xu, X. Li, R. Tong, L. Chen, Y. Han, J. Wu, X. Zhang, Inorg. Chem. 57, 15481–15488 (2018)

    Article  CAS  Google Scholar 

  42. P.M. Kibasomba, S. Dhlamini, M. Maaza, C.-P. Liu, M.M. Rashad, D.A. Ryan, B.W. Mwakikunga, Results Phys. 9, 628–635 (2018)

    Article  Google Scholar 

  43. Z. Wang, D. Schiferl, Y. Zhao, H.S. O’Neill, J. Phys. Chem. Solids 64, 2517–2523 (2003)

    Article  CAS  Google Scholar 

  44. M. Rívero, A.D. Campo, Á. Mayoral, E. Mazario, J. Sánchez-Marcos, A. Muñoz-Bonilla, RSC Adv. 6, 40067–40076 (2016)

    Article  Google Scholar 

  45. X.M. Sun, X. Chen, Z.X. Deng, Y.D. Li, Mater. Chem. Phys. 78, 99–104 (2002)

    Article  CAS  Google Scholar 

  46. Y. Sun, W. Wang, L. Zhang, S. Sun, E. Gao, Mater. Lett. 98, 124–127 (2013)

    Article  CAS  Google Scholar 

  47. X. Zhu, F. Zhang, M. Wang, J. Ding, S. Sun, J. Bao, C. Gao, Appl. Surf. Sci. 319, 83–89 (2014)

    Article  CAS  Google Scholar 

  48. B.S. Surendra, T.R. Shashi Shekhar, M. Veerabhadraswamy, H.P. Nagaswarupa, S.C. Prashantha, G.C. Geethanjali, C. Likitha, Chem. Phys. Lett. 745, 137286–137296 (2020)

    Article  CAS  Google Scholar 

  49. G.K. Pradhan, S. Martha, K.M. Parida, ACS Appl. Mater. Interfaces 4, 707–713 (2012)

    Article  CAS  Google Scholar 

  50. L. Han, X. Zhou, L. Wan, Y. Deng, S. Zhan, J. Environ. Chem. Eng. 2, 123–130 (2014)

    Article  CAS  Google Scholar 

  51. M.I.A.A. Maksoud, G.S. El-Sayyad, A.M. El-Khawaga, M.A. Elkodous, A. Abokhadra, M.A. Elsayed, M. Gobara, L.I. Soliman, H.H. El-Bahnasawy, A.H. Ashour, J. Hazard. Mater. 399, 12300 (2020)

    Google Scholar 

  52. N.G. Yadav, L.S. Chaudhary, P.A. Sakhare, T.D. Dongale, P.S. Patil, A.D. Sheikh, J. Colloid Interface Sci. 527, 289–297 (2018)

    Article  CAS  Google Scholar 

  53. Y. Xiang, Y. Huang, B. Xiao, X. Wu, G. Zhang, Appl. Surf. Sci. 513, 145820–145832 (2020)

    Article  CAS  Google Scholar 

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Acknowledgements

The authors thank Vishal Bhardwaj for his help in sample preparation and are thankful to Dr. R. Singhal for Raman measurements. The authors thank DST, New Delhi for providing Shimadzu UV-3600 plus spectrophotometer under FIST (SR/FST/PSI-167/2011(C)). SC gratefully acknowledges DST, New Delhi for INSPIRE fellowship (DST/INSPIRE Fellowship/2016/IF160775).

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Authors and Affiliations

  1. University School of Basic and Applied Sciences, Guru Gobind Singh Indraprastha University, Dwarka, New Delhi, 110078, India

    Shipra Choudhary, Aditi Bisht & Satyabrata Mohapatra

  2. CSIR - Institute of Minerals and Materials Technology, Bhubaneswar, 751013, Odisha, India

    Manas Kumar Dalai

  3. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India

    Manas Kumar Dalai

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  1. Shipra Choudhary
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Choudhary, S., Bisht, A., Dalai, M.K. et al. Facile synthesis, morphological, structural, photocatalytic, and optical properties of ZnFe2O4 nanostructures. J Mater Sci: Mater Electron 32, 27429–27440 (2021). https://doi.org/10.1007/s10854-021-07119-3

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