Skip to main content
SpringerLink
Log in

Facile synthesis of Ti3C2TX–MXene composite with polyhedron Fe3O4/ carbonyl iron toward microwave absorption

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Two-dimensional materials have already been considered as promising microwave absorbing materials due to their unique and charming layered structure. However, it is difficult to achieve excellent absorption performance at a thin thickness. Herein, the polyhedral Fe3O4 was prepared in-situ using sheet-shaped carbonyl iron powder, which not only retained the sheet-like structure of carbonyl iron powder but also formed polyhedral Fe3O4 on the surface. By tuning the ratio of Ti3C2TX/carbonyl iron powder/Fe3O4 microwave absorption capabilities in terms of the minimum reflection loss (RL) value and absorber thickness could be readily optimized. This result is verified by the explanation of the quarter-wavelength law and impedance matching degree. Specifically, when the thickness of the C–F–M 10% composite material is 2.2 mm, the minimum RL value at 9.16 GHz is − 52.1 dB, and the effective absorption bandwidth is 3.32 GHz. The thickness of the C–F–M 15% composite is 2.0 mm, the minimum RL value at 11.12 GHz is − 49.9 dB, and the effective absorption bandwidth is 4.59 GHz. Therefore, Ti3C2TX composite material is expected to become a candidate material for ultra-thin and lightweight absorbers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. S.Y. Bao, Y.J. Wang, Z.S. Wei, W.W. Yang, Y.S. Yu, Y.Y. Sun, J. Hazard. Mater. 416, 125825 (2021)

    Article  CAS  Google Scholar 

  2. S. Bao, W. Yang, Y. Wang, Y. Yu, Y. Sun, J. Hazard. Mater. 409, 124470 (2020)

    Article  CAS  Google Scholar 

  3. H. Liu, M. Shen, P. Zhou, Z. Guo, X. Liu, W. Yang, M. Gao, M. Chen, H. Guan, N.P. Padture, Nanoscale 13, 9315 (2021)

    Article  CAS  Google Scholar 

  4. Y. Chen, H.B. Zhang, Y. Yang, M. Wang, A. Cao, Z.Z. Yu, Adv. Funct. Mater. 26, 447 (2016)

    Article  CAS  Google Scholar 

  5. S.T. Hsiao, C.C. Ma, H.W. Tien, W.H. Liao, Y.S. Wang, S.M. Li, C.Y. Yang, S.C. Lin, R.B. Yang, ACS Appl. Mater. Interfaces 7, 2817 (2015)

    Article  CAS  Google Scholar 

  6. O. Balci, E.O. Polat, N. Kakenov, C. Kocabas, Nat. Commun. 6, 1 (2015)

    Google Scholar 

  7. P. He, M.S. Cao, W.Q. Cao, J. Yuan, Nano-Micro Lett. 13, 1 (2021)

    Article  CAS  Google Scholar 

  8. P. He, X.X. Wang, Y.Z. Cai, J.C. Shu, Q.L. Zhao, J. Yuan, M.S. Cao, Nanoscale 11, 6080 (2019)

    Article  CAS  Google Scholar 

  9. P. Liu, V. Ng, Z. Yao, J. Zhou, Y. Lei, Z. Yang, H. Lv, L.B. Kong, ACS Appl. Mater. Interfaces 9, 1640 (2017)

    Google Scholar 

  10. H. Liao, X. Guo, P. Wan, G. Yu, Adv. Funct. Mater. 29, 1904507 (2019)

    Article  CAS  Google Scholar 

  11. S.A. Mirkhani, A. Shayesteh Zeraati, E. Aliabadian, M. Naguib, U. Sundararaj, ACS Appl. Mater. Interfaces 11, 18599 (2019)

    Article  CAS  Google Scholar 

  12. S.J. Kim, J. Choi, K. Maleski, K. Hantanasirisakul, H.T. Jung, Y. Gogotsi, C.W. Ahn, ACS Appl. Mater. Interfaces 11, 32320 (2019)

    Article  CAS  Google Scholar 

  13. C.J. Zhang, B. Anasori, A. Seral-Ascaso, S.H. Park, N. McEvoy, A. Shmeliov, G.S. Duesberg, J.N. Coleman, Y. Gogotsi, V. Nicolosi, Adv. Mater. 29, 4848 (2017)

    CAS  Google Scholar 

  14. S. Seyedin, S. Uzun, A. Levitt, B. Anasori, G. Dion, Y. Gogotsi, J.M. Razal, Adv. Funct. Mater. 30, 1910504 (2020)

    Article  CAS  Google Scholar 

  15. M.R. Lukatskaya, S. Kota, Z. Lin, M.Q. Zhao, N. Shpigel, M.D. Levi, J. Halim, P.L. Taberna, M.W. Barsoum, P. Simon, Y. Gogotsi, Nat. Energy 2, 1 (2017)

    Article  CAS  Google Scholar 

  16. B. Lyu, M. Kim, H. Jing, J. Kang, C. Qian, S. Lee, J.H. Cho, ACS Nano. 13, 11392 (2019)

    Article  CAS  Google Scholar 

  17. B. Anasori, M.R. Lukatskaya, Y. Gogotsi, Nat. Rev. Mater. 2, 1 (2017)

    Article  CAS  Google Scholar 

  18. J. Pang, R.G. Mendes, A. Bachmatiuk, L. Zhao, H.Q. Ta, T. Gemming, H. Liu, Z. Liu, M.H. Rummeli, Chem. Soc. Rev. 48, 72 (2019)

    Article  CAS  Google Scholar 

  19. J. Ran, G. Gao, F.T. Li, T.Y. Ma, A. Du, S.Z. Qiao, Nat. Commun. 8, 13907 (2017)

    Article  CAS  Google Scholar 

  20. L. Liang, G. Han, Y. Li, B. Zhao, B. Zhou, Y. Feng, J. Ma, Y. Wang, R. Zhang, C. Liu, ACS Appl. Mater. Interfaces 11, 25399 (2019)

    Article  CAS  Google Scholar 

  21. M. Han, X. Yin, H. Wu, Z. Hou, C. Song, X. Li, L. Zhang, L. Cheng, ACS Appl. Mater. Interfaces 8, 21011 (2016)

    Article  CAS  Google Scholar 

  22. Y. Qing, W. Zhou, F. Luo, D. Zhu, Ceram. Int. 42, 16412 (2016)

    Article  CAS  Google Scholar 

  23. X. Zhang, H. Wang, R. Hu, C. Huang, W. Zhong, L. Pan, Y. Feng, T. Qiu, C. Zhang, J. Yang, Appl. Surf. Sci. 484, 383 (2019)

    Article  CAS  Google Scholar 

  24. X. Meng, Y. Liu, G. Han, W. Yang, Y. Yu, Carbon 162, 356 (2020)

    Article  CAS  Google Scholar 

  25. G. Han, R. Sui, Y. Yu, L. Wang, W. Yang, J. Magn. Magn. Mater. 528, 167824 (2021)

    Article  CAS  Google Scholar 

  26. M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M.W. Barsoum, Adv. Mater. 23, 4248 (2011)

    Article  CAS  Google Scholar 

  27. L. Shi, Y. Zhao, Y. Li, X. Han, T. Zhang, Appl. Surf. Sci. 416, 329 (2017)

    Article  CAS  Google Scholar 

  28. R. Gupta, A.K. Sood, P. Metcalf, J.M. Honig, Phys. Rev. B 65, 104430 (2002)

    Article  CAS  Google Scholar 

  29. I.R. Beattie, T.R. Gilson, J. Chem. Soc. A Inorg. Phys. Theor. 6, 980 (1970)

    Article  Google Scholar 

  30. O.N. Shebanova, P. Lazor, J. Chem. Phys. 119, 6100 (2003)

    Article  CAS  Google Scholar 

  31. O.N. Shebanova, P. Lazor, J. Raman Spectrosc. 34, 845 (2003)

    Article  CAS  Google Scholar 

  32. X.W. Yin, L.F. Cheng, L.T. Zhang, N. Travitzky, P. Greil, Int. Mater. Rev. 62, 1 (2016)

    Google Scholar 

  33. Z.Y. Peijiang Liu, J. Zhou, RSC Adv. 5, 93739 (2015)

    Article  CAS  Google Scholar 

  34. Y. Xu, J. Luo, W. Yao, J. Xu, T. Li, J. Alloy. Compd. 636, 310 (2015)

    Article  CAS  Google Scholar 

  35. C. Fourn, S. Lasquellec, C. Brosseau, J. Appl. Phys. 102, 1277 (2007)

    Article  CAS  Google Scholar 

  36. P. Liu, Z. Yao, V.M.H. Ng, J. Zhou, L.B. Kong, Mater. Lett. 248, 214 (2019)

    Article  CAS  Google Scholar 

  37. B. Wen, M. Cao, M. Lu, W. Cao, H. Shi, J. Liu, X. Wang, H. Jin, X. Fang, W. Wang, J. Yuan, Adv. Mater. 26, 3484 (2014)

    Article  CAS  Google Scholar 

  38. M. Cao, X. Wang, W. Cao, X. Fang, B. Wen, J. Yuan, Small 14, 1800987 (2018)

    Article  CAS  Google Scholar 

  39. Y. Liu, Y. Fu, L. Liu, W. Li, J. Guan, G. Tong, ACS Appl. Mater. Interfaces 10, 16511 (2018)

    Article  CAS  Google Scholar 

  40. Y. Du, W. Liu, R. Qiang, X. Han, Y. Wang, ACS Appl. Mater. Interfaces 6, 12997 (2014)

    Article  CAS  Google Scholar 

  41. X. Sun, J. He, G. Li, J. Tang, H. Xue, J. Mater. Chem. C 1, 765 (2012)

    Article  CAS  Google Scholar 

  42. B. Lu, X.L. Dong, H. Huang, X.F. Zhang, X.G. Zhu, J.P. Lei, J.P. Sun, J. Magn. Magn. Mater. 320, 1106 (2008)

    Article  CAS  Google Scholar 

  43. M. Wu, Y.D. Zhang, S. Hui, T.D. Xiao, G.W. Taylor, Appl. Phys. Lett. 80, 4404 (2002)

    Article  CAS  Google Scholar 

  44. X. Liu, G. Geng, D.Y. Zhang, Z., D., Appl. Phys. Lett. 92, 243110 (2008)

    Article  CAS  Google Scholar 

  45. P. Liu, Z. Yao, J. Zhou, Z. Yang, L.B. Kong, J. Mater. Chem. C 4, 9738 (2016)

    Article  CAS  Google Scholar 

  46. P. Liu, Z. Yao, V.M.H. Ng, J. Zhou, L.B. Kong, K. Yue, Compos. Part A Appl. Sci. Manuf 115, 371 (2018)

    Article  CAS  Google Scholar 

  47. X. Tian, F. Meng, F. Meng, X. Chen, Y. Guo, Y. Wang, W. Zhu, Z. Zhou, ACS Appl. Mater. Interfaces 9, 15711 (2017)

    Article  CAS  Google Scholar 

  48. Z. Ma, Y. Zhang, C.T. Cao, J. Yuan, Q.F. Liu, J.B. Wang, Phys. B Condens. Matter 406, 4620 (2011)

    Article  CAS  Google Scholar 

  49. T. Wu, Y. Liu, X. Zeng, T. Cui, G. Tong, ACS Appl. Mater. Interfaces 8, 7370 (2016)

    Article  CAS  Google Scholar 

  50. J. Xiang, J. Li, X. Zhang, Q. Ye, J. Xu, X. Shen, J. Mater. Chem. A 2, 16905 (2014)

    Article  CAS  Google Scholar 

  51. Y. Cheng, P. Hu, S. Zhou, L. Yan, B. Sun, X. Zhang, W. Han, Carbon 132, 430 (2018)

    Article  CAS  Google Scholar 

  52. D. Ding, Y. Wang, X. Li, R. Qiang, P. Xu, W. Chu, X. Han, Y. Du, Carbon 111, 722 (2017)

    Article  CAS  Google Scholar 

  53. Y. Li, X. Zhou, J. Wang, Q. Deng, M. Li, S. Du, Y.-H. Han, J. Lee, Q. Huang, RSC Adv. 7, 24698 (2017)

    Article  CAS  Google Scholar 

  54. W. Feng, H. Luo, Y. Wang, S. Zeng, L. Deng, X. Zhou, H. Zhang, S. Peng, RSC Adv. 8, 2398 (2018)

    Article  CAS  Google Scholar 

  55. B. Fan, N. Li, B. Dai, S. Shang, L. Guan, B. Zhao, X. Wang, Z. Bai, R. Zhang, Adv. Powder Technol. 31, 808 (2020)

    Article  CAS  Google Scholar 

  56. L.L. Adebayo, H. Soleimani, N. Yahya, Z. Abbas, F.A. Wahaab, R.T. Ayinla, H. Ali, Ceram. Int. 46, 1249 (2020)

    Article  CAS  Google Scholar 

  57. M. Ren, F. Li, B. Wang, J. Wei, Q. Yu, J. Magn. Magn. Mater. 513, 167259 (2020)

    Article  CAS  Google Scholar 

  58. H. Yang, J. Dai, X. Liu, Y. Lin, J. Wang, L. Wang, F. Wang, Mater. Chem. Phys. 200, 179 (2017)

    Article  CAS  Google Scholar 

  59. Y. Wang, X. Wu, W. Zhang, C. Luo, J. Li, Q. Wang, Q. Wang, Mater. Chem. Phys. 209, 23 (2018)

    Article  CAS  Google Scholar 

  60. P. Liu, V.M.H. Ng, Z. Yao, J. Zhou, L.B. Kong, Mater. Lett. 229, 286 (2018)

    Article  CAS  Google Scholar 

  61. G. Cui, X. Sun, G. Zhang, Z. Zhang, H. Liu, J. Gu, G. Gu, Mater. Lett. 252, 8 (2019)

    Article  CAS  Google Scholar 

  62. P. Liu, S. Chen, M. Yao, Z. Yao, V.M.H. Ng, J. Zhou, Y. Lei, Z. Yang, L.B. Kong, Mater. Sci. Semicond. Process. 112, 105008 (2020)

    Article  CAS  Google Scholar 

  63. Y. Tong, M. He, Y. Zhou, X. Zhong, L. Fan, T. Huang, Q. Liao, Y. Wang, J. Mater. Sci.: Mater. Electron. 29, 8078 (2018)

    CAS  Google Scholar 

Download references

Acknowledgements

This work is supported by the research team of electrode material design and application of supercapacitor of Xi’an University of Architecture and Technology.

Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Xi’an University of Architecture and Technology, Xi’an, 710055, China

    Dan Jin, Yuguo Du, Xiaolong Yang & Tiantian Chen

Authors
  1. Dan Jin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuguo Du
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xiaolong Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Tiantian Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dan Jin.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jin, D., Du, Y., Yang, X. et al. Facile synthesis of Ti3C2TX–MXene composite with polyhedron Fe3O4/ carbonyl iron toward microwave absorption. J Mater Sci: Mater Electron 32, 23762–23775 (2021). https://doi.org/10.1007/s10854-021-06683-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-021-06683-y

Search

Navigation