Abstract
Currently, the TiO2/CdS photoanodes based dye-sensitized solar cells (DSSCs) have shown extraordinary developments in the photo-conversion efficiency. In this report, pristine TiO2, CdS and various molar ratios of TiO2/CdS photoanodes were prepared by one step microwave irradiation route and followed by doctor blade method. The sheet-like morphology of the TiO2 and CdS nanoparticles were clearly evident from the SEM and TEM images. A significant reduction bandgap with enhanced light absorption and rapid prevention of electron hole pair was explored by UV-DRS and PL studies. The photocurrent density–voltage (J–V) and electrochemical impedance (EIS) characteristics were analyzed for assembled solar cell. The photo-conversion efficiency of 12.8% was obtained with the configuration TiO2/CdS (200 mg) that represent a 2.5-fold increment compared to bare TiO2 (5.33%) as well as commercial Pt (6.11%). The experimental results are discussed.
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Revathi, M., jeyakumari, A.P. Fabrication of TiO2/CdS heterostructure photoanodes and optimization of light scattering to improve the photovoltaic performance of dye-sensitized solar cells (DSSCs). J Mater Sci: Mater Electron 32, 11921–11930 (2021). https://doi.org/10.1007/s10854-021-05822-9
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DOI: https://doi.org/10.1007/s10854-021-05822-9