Abstract
Ba6Ca3Al2Si6O24:Ce3+/Tb3+/Na+ phosphors were prepared via a solid-state reaction at 1150 °C in air. In addition to appropriate peak positions, X-ray diffraction analysis also revealed that single-phase phosphors contained a trigonal crystal system with R \(\overline{3}\) H symmetry. The particle morphology of the Ba6Ca3Al2Si6O24:Ce3+/Tb3+ phosphors co-doped with Na+ ions was observed by scanning electron microscopy. Multiphonon relaxation and cross relaxation between two adjacent Tb3+ ions in the Ba6Ca3Al2Si6O24 host structure were exploited with examining the excitation and emission photoluminescence spectra of the Ba6−3q/2TbqCa3Al2Si6O24 and Ba6−(q+r)TbqNarCa3Al2Si6O24 phosphors. Co-doping of the Ba6Ca3Al2Si6O24:Tb3+ lattice with Na+ and Ce3+ led to enhanced green emission. The mechanism for the energy transfer from Ce3+ to Tb3+ in the intense green Ba5.85−3q/2Ce0.1TbqCa3Al2Si6O24 and Ba5.8−2qCe0.1TbqNa0.1+qCa3Al2Si6O24 phosphors was determined. Moreover, the desired Commission Internationale de l’Eclairage coordinates of the phosphors were monitored from blue to green regions. Thermal quenching was observed with an increase in temperature from 298 to 448 K, and the activation energy of the Tb3+ transition was calculated. The estimated relative quantum efficiency and internal quantum efficiency were obtained for the Ba5.4Ce0.1Tb0.2Na0.3Ca3Al2Si6O24 phosphors.
Similar content being viewed by others
References
A.J. Wilkins, C. Clark, Modulation of light from fluorescent lamps. Lighting Res. Technol. 22, 103–109 (1990)
T. Welker, Recent developments of phosphors for fluorescent lamps and cathode-ray tube. J. Lumin. 48, 49–56 (1991)
T. Hirajimaa, K. Sasakia, A. Bissomboloa, H. Hiraib, M. Hamadac, M. Tsunekawa, Feasibility of an efficient recovery of rare earth-activated phosphors from waste fluorescent lamps through dense-medium centrifugation. Sep. Purif. Technol. 44, 197–204 (2005)
S. Ye, F. Xiao, Y.X. Parn, Y.Y. Ma, Q.Y. Zhang, Phosphors in phosphor-converted white light-emitting diodes: recent advances in materials, techniques and properties. Mater. Sci. Eng. R 71, 1–34 (2010)
E.F. Schubert, J.K. Kim, Solid-state light sources getting smart. Science 308, 1274–1278 (2005)
Y.-C. Lin, M. Karlsson, M. Bettinelli, Inorganic phosphor materials for lighting. Top. Curr. Chem. Z 374, 21 (2016)
W. Van Schaik, S. Lizzo, W. Smit, G. Blasse, Influence of impurities on the luminescence quantum efficiency of (La, Ce, Tb)PO4. J. Electro. Soc. 140, 216–222 (1993)
Z. An, S. Che, Y. Song, X. Zhang, R. Dong, D. Zhang, X. Zhou, Z. Shi, H. Zou, Ca(Mg0.8Al2)(Si1.8Al0.2)O6:Ce3+,Tb3+ phosphors: structure control, density-functional theory calculation, and luminescence property for pc-wLED application. Inorg. Chem. 59, 4790–4799 (2020)
J. Zheng, X. Wu, Q. Ren, Y. Ren, O. Hai, Luminescence properties, energy transfer and thermal stability of blue-green color tunable Sr3Y(BO3)3:Ce3+, Tb3+ phosphors. Opt. Laser Technol. 123, 105900 (2020)
Y. Zou, X. Min, Z. Liu, L. Yu, B. Liu, Photoluminescent properties and energy transfer mechanism of Tb3+-Ce3+ doped CaSi2O2N2 oxynitride phosphors. Mater. Res. Bull. 124, 110769 (2020)
M. Xia, W. Zhao, J. Zhong, P. Shi, Z. Liao, X. Liu, J. Song, L. Luo, L. Ma, Z. Nie, Tunable luminescence of blue-green emitting NaBaBO3:Ce3+, Tb3+ phosphors for near-UV light emitting diodes. J. Lumin. 220, 116957 (2020)
S. Yang, S. Park, Promising green Sr5B3O9F: Ce3+/ Tb3+/Na+ phosphors for NUV executable LED applications. J. Alloys Compd. 834, 155094 (2020)
W. Yang, S. Park, Predominant green emission of Ce3+–Tb3+ activated Y7O6F9 phosphors. RSC Adv. 6, 12652–12656 (2016)
D.V. Deyneko, V.A. Morozov, A.A. Vasin, S.M. Aksenov, Y.Y. Dikhtya, S.Y. Stefanovich, B.I. Lazoryak, The crystal site engineering and turning of cross-relaxation in green-emitting β-Ca3(PO4)2-related phosphors. J. Lumin. 232, 117196 (2020)
B. Zhang, S. Ying, L. Han, J. Zhang, B. Chen, Color-tunable phosphor of Sr3YNa(PO4)2F:Tb3+via interionic cross-relaxation energy transfer. RSC Adv. 8, 25378–25386 (2018)
B.V. Ratnam, M. Jayasimhadri, G.B. Kumar, K. Jang, S.S. Kim, Y.I. Lee, J.M. Lim, D.S. Shin, T.K. Song, Synthesis and luminescent features of NaCaPO4:Tb3+ green phosphor for near UV-based LEDs. J Alloys Compd. 564, 100–104 (2013)
Z. Xia, R.-S. Liu, Tunable blue-green color emission and energy transfer of Ca2Al3O6F:Ce3+, Tb3+ phosphors for near-UV white LEDs. J. Phys. Chem. C 116, 15604–15609 (2012)
M. Chen, Z. Xia, Q. Liu, Luminescence properties and energy transfer of Ce3+/Tb3+ co-doped Ca6Ba(PO4)4O phosphor for near-UV pumped light-emitting diodes. J. Mater. Chem. C 3, 4197–4204 (2015)
J. Sun, J. Sun, Tunable color of Ce3+/Tb3+-codoped Ba3Sr4(BO3)3F5 phosphors for near-UV-pumped LEDs. J. Mater. Sci. 51, 1985–1995 (2016)
X. Fu, L. Fang, S. Niu, H. Zhang, Luminescence properties and energy transfer investigations of SrMgSi2O6:Ce, Tb phosphors. J. Lumin. 142, 163–166 (2013)
S. Lee, S. Park, Preparation and luminescent properties of Tb3+ and Tb3+–Ce3+ doped Ba9Y2Si6O24 phosphors. J. Lumin. 143, 215–218 (2013)
S. Yang, S. Park, Ca2+-substitution effects in Ba9-xCaxAl2Si6O24:Ce3+, Na+ phosphors. Opt. Mater. 99, 109548 (2020)
L.H. Wang, L.F. Schneemeyer, R.J. Cava, T. Siegrist, A new barium scandium silicate: Ba9Sc2(SiO4)6. J. Solid State Chem. 113, 211–214 (1994)
Y. Kim, S. Park, Preparation and luminescent properties of Eu-substituted barium–yttrium orthosilicate phosphors. Opt. Mater. 36, 458–462 (2013)
S. Yang, T.J. Shin, S. Park, Luminescent-center tuning for Ba6Ca3YAlSi6O24:Ce3+, Na+ orthosilicate phosphors. J. Alloys Compd. 777, 572–577 (2019)
X. Li, Z. Yang, L. Guan, J. Guo, Y. Wang, Q. Guo, Synthesis and luminescence properties of CaMoO4:Tb3+, R+ (Li+, Na+, K+). J. Alloy Compd. 478, 684–686 (2009)
J. Chen, C. Li, Z. Hui, Y. Liu, Mechanisms of Li+ ions in the emission enhancement of KMg4(PO4)3:Eu2+ for white light emitting diodes. Inorg. Chem. 56, 1144–1151 (2017)
S. Shin, S. Park, Luminescence enhancement and site-dependent energy transfer of Ba5(B2O5)2F2: Ce3+/Tb3+/Na+ phosphors. Opt. Mater. 108, 110189 (2020)
K. Ueda, T. Aoki, Y. Shimizu, F. Massuyeau, Luminescence and location of Gd3+ or Tb3+ ions in perovskite-type LaScO3. Inorg. Chem. 57, 8718–8721 (2018)
C.C. Lin, R.S. Liu, Y.S. Tang, S.F. Hu, Full-color and thermally stable KSrPO4: Ln ( Ln = Eu, Tb, Sm ) phosphors for white-light-emitting diodes. J. Electrochem. Soc. 155, J248–J251 (2008)
Y. Tian, N. Feng, M. Wierzbicka-Wieczorek, P. Huang, L. Wang, Q. Shi, C. Cui, Energy transfer-induced tunable emission color and thermal quenching of Ca3Y(PO4)3: Eu2+, Mn2+ phosphor for NUV-pumped white LEDs. Dyes and Pig. 131, 91–99 (2016)
W. Lü, X. Zhang, Y. Wang, Z. Hao, Y. Liu, Y. Luo, X. Wang, J. Zhang, Luminescence investigation and thermal stability study of Eu2+ and Eu2+–Mn2+ codoped (Ba, Sr)Mg2Al6Si9O30 phosphor. J. Alloys Compd. 513, 430–435 (2012)
M. Noh, S.-H. Cho, S. Park, Tunable luminescence in Bi3+ and Eu3+ co-doped Sr3AlO4F oxyfluorides phosphors. J. Lumin. 161, 343–346 (2015)
D.S. Xing, M.L. Gong, X.Q. Qiu, D.J. Yang, K.W. Cheah, Bluish green barium aluminate phosphor for PDP application. Mater. Lett. 60, 3217–3220 (2006)
H. Yun, S. Park, Blue-white-orange tunable Ba6Ca3YAlSi6O24:Eu2+, Mn2+ phosphors for NUV-pumped LEDs. Opt. Mater. 86, 600–605 (2018)
Z. Xia, R.S. Liu, K.W. Huang, V. Drozd, Ca2Al3O6F:Eu2+: a green-emitting oxyfluoride phosphor for white light-emitting diodes. J. Mater. Chem. 22, 15183–15189 (2012)
C. Liu, Z. Xia, Z. Lian, J. Zhou, Q. Yan, Structure and luminescence properties of green-emitting NaBaScSi2O7:Eu2+ phosphors for near-UV-pumped light emitting diodes. J. Mater. Chem. C 1, 7139–7147 (2013)
Acknowledgements
This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the ministry of Education, Science and Technology (Grant No. NRF-2018R1D1A3B07048543). This work was supported by the BB21+ Project in 2018.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Shin, S., Park, S. Luminescent behavior of Tb3+ transitions in green Ba6Ca3Al2Si6O24:Ce3+/ Tb3+/Na+ phosphors. J Mater Sci: Mater Electron 32, 4311–4320 (2021). https://doi.org/10.1007/s10854-020-05174-w
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-05174-w