Abstract
The selenium (Se)-modified 0.5BiFeO3–0.5(BaSr)TiO3 was synthesized employing a high-temperature solid-state technique. Structural analysis (through Rietveld refinement) of the room-temperature X-ray diffraction pattern and data of the material confirms the tetragonal (P4mm) symmetry of the compound. Studies of scanning electron micrograph (SEM) and energy dispersive X-ray spectroscopy (EDS) data reveal the nature and characteristics (i.e., size, shape and distribution of grains, grain boundaries, voids and presence of elements, etc.,) of surface morphology and structure of the compound. Detailed analysis of temperature and frequency dependence of dielectric and impedance data exhibits the relaxor type of ferroelectric behavior and semiconductor (negative temperature coefficient of resistance) nature of the material. The material is found to have high resistivity and low dielectric (tangent) loss. Study of the temperature dependence of leakage current characteristics (i.e., electric field dependent current density) shows the leaky behavior of the material. The Se-modified 0.5BiFeO3–0.5(BaSr)TiO3 (BFBST), compared to its components (BFBST and pure BiFeO3), material possesses different types of conduction process, like space charge limited (SCLC), Ohmic, Hopping type. Poole–Frenkel emission (PFE) and Schottky emission (SE) fitted data give an evidence/idea about the bulk-limited and interface-limited conduction mechanism present in the system. The energy gap values (Eg) of Se substituted BFBST and BiFeO3 are found to be 0.55 eV and 0.78 eV, respectively, in the low-temperature range.
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References
N.A. Hill, J. Phys. Chem. B 104, 6694–6709 (2000)
G.A. Smolenskii, V. Isupov, A. Agranovskaya, N. Kranik, Sov. Phys. Solid State 2, 2651–2654 (1961)
P. Fischer, M. Polomska, I. Sosnowska, M. Szymanski, J. Phys. C 13, 1931–1940 (1980)
M. Luo, S.P. Lin, Y. Zheng, B. Wang, Appl. Phys. Lett. 101, 062902 (2012). https://doi.org/10.1063/1.4742897
M.R. Suchomel, P.K. Daviesa, J. Appl. Phys. 96(8), 4405–4410 (2004). https://doi.org/10.1063/1.1789267
H.N. Lee, H.M. Christen, M.F. Chisholm, C.M. Rouleau, D.H. Lowndes, Nature 433(7027), 395–399 (2005)
P. Wu, X. Ma, Y. Li, V. Gopalan, L.Q. Chen, Appl. Phys. Lett. 100, 092905-4 (2012). https://doi.org/10.1063/1.3691172
W.M. Zhu, H.Y. Guo, Z.-G. Ye, Phys Rev B: Condens. Mater. Phys. 78(1), 014401 (2008). https://doi.org/10.1103/PhysRevB.78.014401
H.L.W. Chan, M.C. Cheung, C.L. Choy, Study on BaTiO3/P(VDF-TrFE) 0–3 composites. Ferroelectrics 224(1), 113–120 (1999). https://doi.org/10.1080/00150199908210557
Y. Bai, Z.-Y. Cheng, V. Bharti, H.S. Xu, Q.M. Zhang, Appl. Phys. Lett. 76(25), 3804–3806 (2000). https://doi.org/10.1063/1.126787
A.P. Ramirez, M.A. Subramanian, M. Gardel, G. Blumberg, D. Li, T. Vogt, S.M. Shapiro, Solid State Commun. 115(5), 217–220 (2000). https://doi.org/10.1016/S0038-1098(00)00182-4
A.R. Makhdoom, M.J. Akhtar, M.A. Rafiq, M.M. Hassan, Ceram. Int. 38, 3829–3834 (2012)
F. Suhua, X. Xie, F. Zhang, X. Guo, S. Yang, L. Zhang, J. Mater. Sci.: Mater. Electron. 27, 6854–6858 (2016)
L.Y. Wang, D.H. Wang, H.B. Huang, Z.D. Han, Q.Q. Cao, B.X. Gu, Y.W. Du, J. Alloys Compd. 46, 1–3 (2009)
M.R. Islam, M.S. Islam, M.A. Zubair, H.M. Usama, M.S. Azam, A. Sharif, J. Alloy. Compd. 735, 2584–2596 (2018). https://doi.org/10.1016/j.jallcom.2017.11.323
M. Basith, A. Billah, M. Jalil, N. Yesmin, M.A. Sakib, E.K. Ashik, S.E.H. Yousuf, S.S. Chowdhury, M.S. Hossain, S.H. Firoz, J. Alloy. Compd. 694, 792–799 (2017)
M. Rangi, A. Agarwal, S. Sanghi, R. Singh, S. Meena, A. Das, AIP Adv. 4(8), 087121 (2014)
S. Godara, B. Kumar, Ceram. Int. 41(5), 6912–6919 (2015)
R. Das, S. Sharma, K. Mandal, J. Magn. Magn. Mater. 401, 129–137 (2016)
M. Pastora, P.K. Bajpaia, R.N.P. Choudhary, J. Phys. Chem. Solids 68, 1914–1920 (2007). https://doi.org/10.1016/j.jpcs.2007.05.024
S. Sahoo, R.N.P Choudhary and B.K Mathur, AIP Conf. Proc. https://doi.org/10.1063/1.3027175
S.O. Leontsevw, R.E. Eitel, J. Am. Ceram. Soc. 92(12), 2957–2961 (2009). https://doi.org/10.1111/j.1551-2916.2009.03313.x
L.F. Zhu, B.P. Zhang, Z.C. Zhang, S. Li, L.J. Wang, L.J. Zheng, J. Mater. Sci. Mater. Electron. 29, 2307–2315 (2018). https://doi.org/10.1007/s10854-017-8147-0
B. Mohanty, B.N. Parida, R.K. Parida, J. Mater. Sci. Mater. Electron. 30(2), 1–8 (2019). https://doi.org/10.1007/s10854-019-01250-y
P. Murugavel, J.-H. Lee, J.Y. Jo, H.Y. Sim, J.-S. Chung, Y. Jo, M.-H. Jung, J. Phys. Condens. Matter 20, 415208 (2008). https://doi.org/10.1088/0953-8984/20/41/415208. (6 pp)
Y. Wei, C. Jin, Y. Zeng, X. Wang, D. Gao, X. Wang, Ceram. Int. 43(12), 17220–17224 (2017). https://doi.org/10.1016/j.ceramint.2017.09.030
W. Cai, S. Zhong, C. Fu, G. Chen, X. Deng, Mater. Res. Bull. 50, 259–267 (2014). https://doi.org/10.1016/j.materresbull.2013.11.029
S. Rizwan, M. Umar, Z.U.D. Babar, S.U. Awan, M.A.U. Rehman, AIP Adv. 9, 055025 (2019). https://doi.org/10.1063/1.5095468
Z. Al-Shadidi, I.H. Khdayer, J Mater Chem Technol 2(2), 56–63 (2014)
L.H. Gaabour, J Mater Res Technol (2020). https://doi.org/10.1016/j.jmrt.2020.02.057
R. Shekhawat, R. Rangappa, R. Karuppannan, AIP Conf. Proc. 1953(1), 090086 (2018). https://doi.org/10.1063/1.5032933
R. Singh, B. Suthar, A. Bhargava, AIP Conf. Proc. (1953). https://doi.org/10.1063/1.5032759
A.S. Hassanien, A.A. Akl, Super-latt. Microstruct. 89, 153–169 (2016). https://doi.org/10.1016/j.spmi.2015.10.044
X.-N. Cao, S. Lian, Y. Tong, W. Lin, L. Jia, Y. Fanga, X. Wang, Chem. Commun. (2019). https://doi.org/10.1039/c9cc08665js
C. Zhang, H. Tao, Y. Dai, X. He, K. Hang, Progress Nat. Sci. Mater. Int. 24, 671–675 (2014). https://doi.org/10.1016/j.pnsc.2014.10.012
F.-R. Yang, Y. Li, X.-H. Zhang, M. Wang, H.-R. Guo, W.-J. Ruan, Bioorg. Med. Chem. Lett. 25, 3592–3596 (2015). https://doi.org/10.1016/j.bmcl.2015.06.075
X. Liu, S. Xu, X. Ding, D. Yue, J. Bian, X. Zhang, G. Zhang, P. Gao, Int. J. Biol. Macromol. (2019). https://doi.org/10.1016/j.ijbiomac.2019.10.078
S. Sharma, V. Singh, A. Anshul, J.M. Siqueiros, R.K. Dwivedi, J. Appl. Phys. 123, 204102 (2018). https://doi.org/10.1063/1.5023682
J. Pala, S. Kumara, L. Singha, M. Singha, A. Singh, J. Magn. Magn. Mater. 441, 339–347 (2017). https://doi.org/10.1016/j.jmmm.2017.05.047
A. Singh, C. Moriyoshi, Y. Kuroiwa, D. Pandey, Phys. Rev. B 88, 024113 (2013). https://doi.org/10.1103/PhysRevB.88.024113
R. Mouta, R.X. Silva, C.W.A. Paschoal, Acta Cryst. B69, 439–445 (2013). https://doi.org/10.1107/S2052519213020514
R.D. Shannon, Acta Crystallogr. A 32, 751–767 (1976)
Y.Q. Jia, J. Solid State Chem. 95, 184–187 (1991)
P. Debye, W. Ramm, Ann. Phys. 28, 28–34 (1937). https://doi.org/10.1002/andp.19364200107
K.S. Cole, R.H. Cole, J. Chem. Phys. 9(4), 341–351 (1941). https://doi.org/10.1063/1.1750906
M. Trainer, Eur. J. Phys. 21, 459–464 (2000)
L.E. Cross, Ferroelectrics 76(1), 241–267 (2011). https://doi.org/10.1080/00150198708016945
C.W. Ahn, J. Korean Phys. Soc. 68(12), 1481–1494 (2016). https://doi.org/10.3938/jkps.68.1481
M. Wu, L. Fang, L. Liu, X. Zhou, Y. Huang, Y. Li, Mater. Chem. Phys. 132(2–3), 1015–1018 (2012)
C. Mao, X. Dong, G. Wang, S. Cao, C. Yao, K. Uchino, J. Am. Ceram. Soc. 93(12), 4011–4014 (2010). https://doi.org/10.1111/j.1551-2916.2010.04224.x
K. Auromun, R.N.P. Choudhary, Structural. Ceram. Int. 45, 20762–20773 (2019). https://doi.org/10.1016/j.ceramint.2019.07.062
J. Kuwata, K. Uchino, S. Nomura, Jpn. J. Appl. Phys. 21, 1298–1302 (1982). https://doi.org/10.1143/JJAP.21.1298
D.P. Almond, A.R. West, Solid State Ionics 11(1), 57–64 (1983)
S.K. Rout, A. Hussian, J.S. Lee, I.W. Kim, S.I. Woo, J. Alloy. Compd. 477(1), 706–711 (2009). https://doi.org/10.1016/j.jallcom.2008.10.125
S. Sahoo, P.K. Mahapatra, R.N.P. Choudhary, J. Phys. D: Appl. Phys. 49, 035302 (2016). https://doi.org/10.1088/0022-3727/49/3/035302
S.Q. Jan, M. Usman, M.N.-U. Haq, A. Mumtaz, J. Alloys Compd. 735, 1893–1900 (2017). https://doi.org/10.1016/j.jallcom.2017.11.275/e2004-00357-8
A.K. Tagantsev, Vogel-Fulcher relationship for the dielectric permittivity of relaxor ferroelectrics. Phys. Rev. Lett. 72, 1100–1103 (1994). https://doi.org/10.1103/PhysRevLett.72.1100
I.O. Troyanchuk, S.V. Trukhanov, D.D. Khalyavin, H. Szymczak, J. Magn. Magn. Mater. 208, 217–220 (2000). https://doi.org/10.1016/S0304-8853(99)00529-6
S.V. Trukhanov, A.V. Trukhanov, A.N. Vasil’ev, A. Maignan, H. Szymczak, JETP Lett. 85, 507–512 (2007). https://doi.org/10.1134/S0021364007100086
S.V. Trukhanov, I.O. Troyanchuk, N.V. Pushkarev, H. Szymczak, JETP 95, 308–315 (2002). https://doi.org/10.1134/1.1506439
S.V. Trukhanov, L.S. Lobanovski, M.V. Bushinsky, V.A. Khomchenko, N.V. Pushkarev, I.O. Tyoyanchuk, A. Maignan, D. Flahaut, H. Szymczak, R. Szymczak, Eur. Phys. J. B 42, 51–61 (2004). https://doi.org/10.1140/epjb/e2004-00357-8
L. Cai, R. Pattnaik, J. Lundeen, J. Toulouse, Phys. Rev. B 98, 134113-12 (2018). https://doi.org/10.1103/PhysRevB.98.134113
J. Macutkevic, J. Banys, A. Bussmann-Holder, A.R. Bishop, Phys. Rev. B 83(18), 184301–184306 (2011). https://doi.org/10.1103/physrevb.83.184301s
K. Prabakar, S.P. Mallikarjun Rao, J. Alloys Compd. 437(1–2), 302–310 (2007). https://doi.org/10.1016/j.jallcom.2006.07.108
R. Das, R.N.P. Choudhary, Solid State Sci. 87, 1–8 (2019). https://doi.org/10.1016/j.solidstatesciences.2018.10.020
A. Satapathy, E. Sinha, B.K. Sonu, S.K. Rout, J. Alloy. Compd. 811, 152042–152048 (2019). https://doi.org/10.1016/j.jallcom.2019.152042
A. Dutta, C. Bharti, T.P. Sinha, Indian J. Eng. Mater. Sci. 15(2), 181–186 (2008)
A. Rouahi, A. Kahouli, F. Challali, M.P. Besland, C. Vall’ee, B. Yangui, S. Salimy, A. Goullet, A. Sylvestre, J. Phys. D Appl. Phys. 46, 065308 (2013). https://doi.org/10.1088/0022-3727/46/6/065308. (7 pp)
A. Rouahi, A. Kahouli, A. Sylvestre, B. Yangui, J. Alloys Compd. 529, 84–88 (2012). https://doi.org/10.1016/j.jallcom.2012.02.137
S. Pattanayak, R.N.P. Choudhary, Ceram. Int. 41(8), 9403–9410 (2015). https://doi.org/10.1016/j.ceramint.2015.03.318
N. Jiang, M. Tian, L. Lue, Q. Zheng, D. Lin, J. Electron. Mater. 45(1), 291–300 (2016). https://doi.org/10.1007/s11664-015-4062-4
D.B. Strukov, G.S. Snider, D.R. Stewart, R.S. Williams, Nature 453, 80–83 (2008). https://doi.org/10.1038/nature06932
K. Jena, S. Satapathy, J. Mohanty, Phys. Chem. Chem. Phys. 21, 15854–15860 (2019). https://doi.org/10.1039/c9cp02528f
S.T. Chang, J.Y. Lee, Appl. Phys. Lett. 80(4), 655–657 (2012). https://doi.org/10.1063/1.1436527
F.-C. Chiu, Adv. Mater. Sci. Eng. (2014). https://doi.org/10.1155/2014/578168
S. Sharma, M.P. Cruz, J.M. Siqueiros, O. Raymond Herrera, V.E. Alvarez, R.K. Dwivedi, J. Mater. Sci. Mater. Electron. 30(8), 7447–7459 (2019). https://doi.org/10.1007/s10854-019-01058-w
Y. Zhang, Z. Chen, W. Cao, Z. Zhang, Appl. Phys. Lett. 111(1–4), 172902 (2017). https://doi.org/10.1063/1.4998187
Y. Zhang, P. Qiu, Y. Pan, J. Lin, F. Wang, Y. Tang, X. He, D. Sun, J. Mater. Sci. Eng. A 6(9–10), 270–276 (2016). https://doi.org/10.17265/2161-6213/2016.9-10.005
Z. Yao, C. Xu, H. Liu, H. Hao, M. Cao, Z. Wang, Z. Song, W. Hu, A. Ullah, J. Mater. Sci. Mater. Electron. 25, 4975–4982 (2014). https://doi.org/10.1007/s10854-014-2260-0
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Auromun, K., Choudhary, R.N.P. Structural, dielectric, and electrical characteristics of selenium-modified BiFeO3–(BaSr)TiO3 ceramics. J Mater Sci: Mater Electron 31, 13415–13433 (2020). https://doi.org/10.1007/s10854-020-03896-5
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DOI: https://doi.org/10.1007/s10854-020-03896-5