Abstract
In this work, we demonstrate that CuI films can be obtained by the liquid–phase iodination method with the chemical reaction time only being 1 min between Cu3N and aqueous iodine solution at room temperature. This is a simple and eco-friendly method with high transparency and low resistivity. The Cu3N precursors were prepared by reactive DC magnetron sputtering using different N2 partial pressures. The effect of nitrogen content of precursor (Cu3N) on the structural, electrical, and optical properties of CuI thin films was discussed. Electronegativity property was used to explain the growth mechanism of CuI films prepared by different nitrogen content in the precursor. By growing the CuI films with a N2:Ar gas ratio of 5:2, the average transmittance achieved was 75% in the visible spectral range, and the lowest resistivity achieved was 3.67 × 10–2 Ω cm. These results suggest that the liquid iodination method using Cu3N film as precursor (N2:Ar gas ratio of 5:2) was suitable for preparing high-quality CuI films for application in transparent electronics.
Similar content being viewed by others
References
S. Gharibzadeh, A. Moshaii, B.A. Nejand, V. Ahmadi, Mater. Lett. 202, 154 (2017)
G.C. Lin, F.Z. Zhao, Y. Zhao, D.Y. Zhang, L.X. Yang, X. Xue, X.H. Wang, C. Qu, Q.S. Li, L. Zhang, Materials 9, 990 (2016)
C. Yang, M. Kneiβ, F.L. Schein, M. Lorenz, M. Grundmann, Sci. Rep. 6, 21937 (2016)
N. Yamada, Y. Kondo, R. Ino, Phys. Status Solidi A. 216, 1700782 (2018)
H. Sakamoto, S. Igarashi, M. Uchida, K. Niume, M. Nagai, Org. Electron. 13, 514 (2012)
M. Rusop, T. Shirata, P.M. Sirimanne, T. Soga, T. Jimbo, M. Umeno, Appl. Surf. Sci. 252, 7389 (2006)
H. Iimori, S. Yamane, T. Kitamura, K. Murakoshi, A. Imanishi, Y. Nakato, J. Phys. Chem. C 112, 11586 (2008)
P. Stakhira, V. Cherpak, D. Volynyuk, F. Ivastchyshyn, Z. Hotra, V. Tataryn, G. Luka, Solid Films 518, 7016 (2010)
C. Yang, M. Kneiβ, M. Lorenz, M. Grundmann, Proc. Natl. Acad. Sci. USA 113, 12929 (2016)
B.L. Zhu, X.Z. Zhao, Phys. Status Solidi A 208, 91 (2011)
M. Grundmann, F.L. Schein, M. Lorenz, T. Böntgen, J. Lenzner, H. Von Wenckstern, Phys. Status Solidi A 210, 1671 (2013)
F.L. Schein, H.V. Wenckstern, M. Grundmann, Appl. Phys. Lett. 102, 092109 (2013)
N. Yamada, R. Ino, Y. Ninomiya, Chem. Mater. 28, 4971 (2016)
M. Wang, H. Wei, T. Wu, C. Yang, P. Han, F. Juan, Y. Chen, F. Xu, B. Cao, Phys. B 573, 45 (2019)
N. Posopa, A. Sakulkalavek, N. Chanlek, J. Kaewkhao, R. Sakdanuphab, Superlattices Microstruct. 141, 106501 (2020)
F.J. Genga, L. Yang, B. Dai, S. Guoa, G. Gao, L. Xu, J. Han, A. Bolshakov, J. Zhu, Surf. Coat. Technol. 361, 396 (2019)
M. Zi, J. Li, Z. Zhang, X. Wang, J. Han, X. Yang, Z. Qiu, H. Gong, Z. Ji, B. Cao, Phys. Status Solidi A 212, 1466 (2015)
S.G. Wang, Q. Zhang, S.F. Yoon, J. Ahn, Q. Wang, D.J. Yang, Q. Zhou, N.L. Yue, Adv. Opt. Mater. 24, 509 (2003)
S. Inudo, M. Miyake, T. Hirato, Phys. Status Solidi A 210, 2395 (2013)
Acknowledgements
This work is supported by the King Mongkut’s Institute of Technology Ladkrabang (KMITL: Grant Number KREF146202), Thailand.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Khumtong, T., Chanlek, N., Klongratog, B. et al. Optimization of the nitrogen content for room temperature rapid synthesis of CuI thin films via liquid iodination method using Cu3N film as precursor. J Mater Sci: Mater Electron 31, 9486–9491 (2020). https://doi.org/10.1007/s10854-020-03489-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-020-03489-2