Skip to main content
Log in

2.0-µm and 4.1-µm mid-infrared broadband emission enhancement in Ho3+/Yb3+ co-doped tellurite–germanate glasses

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Ho3+/Yb3+ co-doped tellurite–germanate glasses with lower phonon energy (771 cm−1) were prepared by conventional melt-quenching method. The prepared samples were characterized by emission spectra, differential scanning calorimeter (DSC) curve, X-ray diffraction (XRD) pattern, and Raman spectra. The DSC curve shows that the sample has a good thermal stability, in which the ΔT is 202 °C. Compared to the recently reported tellurite glasses, the ΔT was increased by approximately 24%. Under the 980 nm laser excitation, it was found that the full width at half maximum (FWHM) of the sample at 2.0 µm was 190 nm. Compared with the reported glasses for this type, the value was effectively improved. Meanwhile, the FWHM of the sample at 4.1 µm was 285 nm, which has not been reported yet. This indicates that Ho3+/Yb3+ co-doped tellurite–germanate glass has a great application prospect in mid-infrared broadband fiber amplifiers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. W.Q. Cao, T. Wang, F.F. Huang, R.G. Ye, R.S. Lei, Y. Tian, J.J. Zhang, S.Q. Xu, Analysis of mid-infrared photoluminescence around 2.85 µm in Yb3+/Ho3+ co-doped synthetic silica-germanate glass. Infrared Phys. Technol. 89, 363–368 (2018)

    Article  CAS  Google Scholar 

  2. Y. Lu, M.Z. Cai, R.J. Cao, Y. Tian, F.F. Huang, S.Q. Xu, J.J. Zhang, Enhanced effect of Er3+ ions on 2.0 and 2.85 µm emission of Ho3+/Yb3+ doped germanate–tellurite glass. Opt. Mater. 60, 252–257 (2016)

    Article  CAS  Google Scholar 

  3. T. Ragin, A. Baranowska, M. Sołtys, A. Górny, M. Kochanowicz, J. Zmojda, P. Miluski, R. Jadach, D. Dorosz, Intense and wide mid-infrared luminescence in bismuth–germanate glass co-doped with Ho3+/Er3+/Yb3+ ions. Infrared Phys. Technol. 92, 139–143 (2018)

    Article  CAS  Google Scholar 

  4. Y.Y. Guo, X.L. Liu, H.S. Duan, Y.S. Yang, G.Y. Zhao, F.F. Huang, G.X. Bai, J.J. Zhang, Optimization by energy transfer process of 2.7 µm emission in highly Er3+-doped tungsten-tellurite glasses. Infrared Phys. Technol. 99, 49–54 (2019)

    Article  Google Scholar 

  5. C.Z. Wang, Y. Tian, X.Y. Gao, Q.H. Liu, F.F. Huang, B.P. Li, J.J. Zhang, S.Q. Xu, Mid-infrared fluorescence properties, structure and energy transfer around 2 µm in Tm3+/Ho3+ co-doped tellurite glass. J. Lumin. 194, 791–796 (2018)

    Article  CAS  Google Scholar 

  6. G.W. Tang, X. Wen, Q. Qian, T.T. Zhu, W.W. Liu, M. Sun, X.D. Chen, Z.M. Yang, Efficient 2.0 µm emission in Er3+/Ho3+ co-doped barium gallo-germanate glasses under different excitations for mid-infrared laser. J. Alloys Compd. 664, 19–24 (2016)

    Article  CAS  Google Scholar 

  7. D.H. Li, W.B. Xu, P.W. Kuan, W.T. Li, Z.Q. Lin, X. Wang, L. Zhang, C.L. Yu, K.F. Li, L.L. Hu, Spectroscopic and laser properties of Ho3+ doped lanthanum–tungsten–tellurite glass and fiber. Ceram. Int. 42, 10493–10497 (2016)

    Article  CAS  Google Scholar 

  8. Y. Tian, L.Y. Zhang, S.Y. Feng, R.R. Xu, L.L. Hu, J.J. Zhang, 2 µm Emission of Ho3+-doped fluorophosphate glass sensitized by Yb3+. Opt. Mater. 32, 1508–1513 (2010)

    Article  CAS  Google Scholar 

  9. M. Kochanowicz, J. Żmojda, P. Miluski, A. Baranowska, T. Ragin, J. Dorosz, M. Kuwik, W.A. Pisarski, J. Pisarska, M. Leśniak, D. Dorosz, 2 µm emission in gallo-germanate glasses and glass fibers co-doped with Yb3+/Ho3+ and Yb3+/Tm3+/Ho3+. J. Lumin. 211, 341–346 (2019)

    Article  CAS  Google Scholar 

  10. X.Q. Liu, F.F. Huang, J.M. Cheng, X.K. Fan, S. Gao, J.J. Zhang, L.L. Hu, D.P. Chen, Investigation on Er3+/Ho3+ co-doped silicate glass for ~ 2 µm fiber lasers. J. Lumin. 162, 197–202 (2015)

    Article  CAS  Google Scholar 

  11. J.Z. Tang, K.L. Lu, S.Q. Zhang, P.Q. Zhang, F.F. Chen, S.X. Dai, Y.S. Xu, Surface plasmon resonance-enhanced 2 µm emission of bismuth germanate glasses doped with Ho3+/Tm3+ ions. Opt. Mater. 54, 160–164 (2016)

    Article  CAS  Google Scholar 

  12. Y.X. Zhou, L.B. Wu, B. Huang, F.J. Yang, S.X. Peng, Y.W. Qi, D.D. Yin, Enhanced 2 µm fluorescence and thermal stability in Ho3+/Tm3+ codoped WO3 modified tellurite glasses. Mater. Lett. 142, 277–279 (2015)

    Article  CAS  Google Scholar 

  13. D. Dorosz, J. Zmojda, M. Kochanowicz, Investigation on broadband near-infrared emission in Yb3+/Ho3+ co-doped antimony–silicate glass and optical fiber. Opt. Mater. 35, 2577–2580 (2013)

    Article  CAS  Google Scholar 

  14. X. Su, Y.X. Zhou, Y.R. Zhu, M.H. Zhou, J. Li, H.R. Shao, Energy transfer induced 2.0 µm luminescent enhancement in Ho3+/Yb3+/Ce3+ tri-doped tellurite glass. J. Lumin. 203, 26–34 (2018)

    Article  CAS  Google Scholar 

  15. J.N. Xia, Y. Tian, B.P. Li, L.X. Zheng, X.F. Jing, J.J. Zhang, S.Q. Xu, Enhanced 2.0 µm emission in Ho3+/Yb3+ co-doped silica-germanate glass. Infrared Phys. Technol. 81, 17–20 (2017)

    Article  CAS  Google Scholar 

  16. Y. Lu, M.Z. Cai, R.J. Cao, Y. Tian, F.F. Huang, S.Q. Xu, J.J. Zhang, Ho3+ doped germanate-tellurite glass sensitized by Er3+ and Yb3+ for efficient 2.0 µm laser material. Mater. Res. Bull. 84, 124–131 (2016)

    Article  CAS  Google Scholar 

  17. M. Kochanowicz, J. Żmojda, P. Miluski, T. Ragin, W.A. Pisarski, J. Pisarska, R. Jadach, M. Sitarz, D. Doros, Structural and luminescent properties of germanate glasses and double-clad optical fiber co-doped with Yb3+/Ho3+. J. Alloys Compd. 727, 1221–1226 (2017)

    Article  CAS  Google Scholar 

  18. G.J. Gao, G.N. Wang, C.L. Yu, J.J. Zhang, L.L. Hu, Investigation of 2.0 µm emission in Tm3+ and Ho3+ co-doped oxyfluoride tellurite glass. J. Lumin. 129, 1042–1047 (2009)

    Article  CAS  Google Scholar 

  19. M. Li, Y.Y. Guo, G.X. Bai, Y. Tian, L.L. Hu, J.J. Zhang, ∼2 µm Luminescence and energy transfer characteristics in Tm3+/Ho3+ co-doped silicate glass. J. Quant. Spectrosc. Radiat. Transfer 127, 70–77 (2013)

    Article  CAS  Google Scholar 

  20. Y.Z. Fang, G.Y. Zhao, J.Y. Xu, N. Zhang, Z.F. Ma, L.L. Hu, Energy transfer and 1.8 µm emission in Yb3+/Tm3+ co-doped bismuth germanate glass. Ceram. Int. 40, 6037–6043 (2014)

    Article  CAS  Google Scholar 

  21. B. Huang, Y.X. Zhou, P. Cheng, Z.Z. Zhou, J. Li, W. Jin, Tm3+/Yb3+ co-doped tellurite glass with silver nanoparticles for 1.85 µm band laser material. Opt. Mater. 60, 341–349 (2016)

    Article  CAS  Google Scholar 

  22. G.X. Bai, Y.Y. Guo, Y. Tian, L.L. Hu, J.J. Zhang, Light emission at 2 µm from Ho–Tm–Yb doped silicate glasses. Opt. Mater. 33, 1316–1319 (2011)

    Article  CAS  Google Scholar 

  23. S.X. Peng, L.B. Wu, B. Wang, F.J. Yang, Y.W. Qi, Y.X. Zhou, Intense visible upconversion and energy transfer in Ho3+/Yb3+ co-doped tellurite glasses for potential fiber laser. Opt. Fiber Technol. 22, 95–101 (2015)

    Article  CAS  Google Scholar 

  24. Y.R. Zhu, X.J. Shen, M.H. Zhou, X. Su, J. Li, G.B. Yang, H.R. Shao, Y.X. Zhou, 2.0 µm band emission enhancement and energy transfer in Ho3+/Yb3+/Er3+ tri-doped tellurite glasses. J. Lumin. 210, 28–37 (2019)

    Article  CAS  Google Scholar 

  25. W.J. Zhang, J. Lin, Y.J. Jia, S. Zhang, J.H. Zhao, G.Y. Sun, S. Ye, J.J. Ren, L. Rong, Enhanced 2–5 µm emission in Ho3+/Yb3+ codoped halide modified transparent tellurite glasses. Spectrochim. Acta Part A 134, 388–398 (2015)

    Article  CAS  Google Scholar 

  26. M.E. Alvarez-Ramos, J. Alvarado-Rivera, M.E. Zayas, U. Caldino, J. Hernandez-Paredes, Yellow to orange-reddish glass phosphors: Sm3+, Tb3+ and Sm3+/Tb3+ in zinc tellurite–germanate glasses. Opt. Mater. 75, 88–93 (2018)

    Article  CAS  Google Scholar 

  27. T.F. Xue, Y. Li, Y.Y. Liu, Z.J. Liu, S.X. Dai, M.S. Liao, L.L. Hu, High thermal stability and intense 2.71 µm emission in Er3+-doped fluorotellurite glass modified by GaF3. Opt. Mater. 75, 367–372 (2018)

    Article  CAS  Google Scholar 

  28. J.J. Leal, R. Narro-García, H. Desirena, J.D. Marconi, E. Rodríguez, K. Linganna, E.D. Rosa, Spectroscopic properties of tellurite glasses co-doped with Er3+ and Yb3+. J. Lumin. 162, 72–80 (2015)

    Article  CAS  Google Scholar 

  29. X. Su, Y.X. Zhou, M.H. Zhou, Y.R. Zhu, P. Cheng, Z.Z. Zhou, N.J. Wang, Enhanced 1.80 µm fluorescence in Er3+/Yb3+/Tm3+ tri-doped tellurite glass for fiber lasers. J. Alloys Compd. 739, 149–159 (2018)

    Article  CAS  Google Scholar 

  30. R. Chen, Y. Tian, B.P. Li, F.C. Wang, X.F. Jing, J.J. Zhang, S.Q. Xu, 2 µm fluorescence of Ho3+: 5I7 → 5I8 transition sensitized by Er3+ in tellurite germanate glasses. Opt. Mater. 49, 116–122 (2015)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work is supported by the National Natural Science Foundation of China (61604094).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chaomin Zhang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hou, G., Zhang, C., Li, G. et al. 2.0-µm and 4.1-µm mid-infrared broadband emission enhancement in Ho3+/Yb3+ co-doped tellurite–germanate glasses. J Mater Sci: Mater Electron 31, 2057–2062 (2020). https://doi.org/10.1007/s10854-019-02725-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-019-02725-8

Navigation