Abstract
Transparent electrodes are frequently used to drive opto-electronic devices, and the patterning of these electrodes is essential. The present work demonstrates a facile means of removing transparent conducting oxides (TCOs) from a glass substrate in selected areas. When agarose gel (agar), a material typically used in desserts, is sandwiched between two TCO-coated glass substrates and connected to a dry cell, the TCO is removed from the glass at the agar stamping area within 2 min. This method allows etching of TCOs using acid-free, inexpensive, and readily available starting materials. Analyses by optical microscopy, transmission spectroscopy, electrical resistance measurements, X-ray diffraction, and X-ray photoelectron spectroscopy demonstrate that this etching occurs as a result of reduction of the TCO in conjunction with the electrolysis of water at the interface between the TCO and agar surfaces. Using this technique, high-throughput patterning of TCOs with an edge resolution of several micrometres was achieved. Furthermore, the shape of the agar template can be readily changed simply by cutting the agar using scissors. Therefore, this method provides a useful means for both researchers and students to easily fabricate patterned substrates for use in electronics and related technologies.
Similar content being viewed by others
References
K.L. Chopra, S. Major, D.K. Pandya, Thin Solid Films 102, 1 (1983)
H. Hosono, K. Ueda, In Springer Handbook of Electronic and Photonic Materials, ed. By S. Kasap, P. Capper (Springer, Berlin, 2006) p. 1391
R.M. Pasquarelli, D.S. Ginley, R. O’Hayre, Chem. Soc. Rev. 40, 5406 (2011)
I. Hamberg, C.G. Granqvist, J. Appl. Phys. 60, R123 (1986)
K. Ide, K. Nomura, H. Hosono, T. Kamiya, Phys. Status Solidi A 216, 1800372 (2019)
K.V. Khot, T.D. Dongale, S.S. Mali, C.K. Hong, R.K. Kamat, P.N. Bhosale, J. Mater. Sci. 52, 9709 (2017)
K.V. Khot, S.S. Mali, R.M. Mane, P.S. Patil, C.K. Hong, J.H. Kim, J. Heo, P.N. Bhosale, J. Mater. Sci. 26, 6897 (2015)
C.C. Boyd, R. Cheacharoen, T. Leijtens, M.D. McGehee, Chem. Rev. 119, 3418 (2019)
T.L. Breen, P.M. Fryer, R.W. Nunes, M.E. Rothwell, Langmuir 18, 194 (2002)
N. Yamamoto, H. Makinoa, S. Osone, A. Ujihara, T. Ito, H. Hokari, T. Maruyama, T. Yamamoto, Thin Solid Films 520, 4131 (2012)
M. Scholten, J.E.A.M. van den Meerakker, J. Electrochem. Soc. 140, 471 (1993)
M. Takabatake, Y. Wakui, N. Konishi, J. Electrochem. Soc. 142, 2470 (1995)
M.M. Salunkhe, K.V. Khot, P.S. Patil, T.M. Bhave, P.N. Bhosale, New J. Chem. 39, 3405 (2015)
K.V. Khot, S.S. Mali, V.B. Ghanwat, S.D. Kharade, R.M. Mane, C.K. Hong, P.N. Bhosale, New J. Chem. 40, 3277 (2016)
C.J. Traverse, R. Pandey, M.C. Barr, R.R. Lunt, Nat. Energy 2, 849 (2017)
Z. Wang, C. Chen, K. Wu, H. Chong, H. Ye, Phys. Status Solidi A 216, 1700794 (2019)
H.D. Belitz, W. Grosch, P. Schieberle, Food Chemistry, 4th edn. (Springer, Berlin, 2009), pp. 302–303
G.A. Burdock, Encyclopedia of food and color additives (CRC Press, Boca Raton, 1997), p. 53
S.B. Smith, P.K. Aldridge, J.B. Callis, Science 243, 203 (1989)
F. Carle, M. Frank, M.V. Olson, Science 232, 65 (1986)
B. Alberts, A. Johnson, J. Lewis, M. Raff, K. Roberts, P. Walter, Molecular biology of the cell, 5th edn. (Garland Science, New York, 2008), p. 534
D. Voet, J.G. Voet, Biochemistry (Wiley, Hoboken, 2011), p. 147
C.J. Campbell, R. Klajn, M. Fialkowski, B.A. Grzybowski, Langmuir 21, 418 (2005)
B.A. Grzybowski, K.J.M. Bishop, C.J. Campbell, M. Fialkowski, S.K. Smoukov, Soft Matter 1, 114 (2005)
S.K. Smoukov, K.J.M. Bishop, R. Klajn, C.J. Campbell, B.A. Grzybowski, Adv. Mater. 17, 1361 (2005)
S.K. Smoukov, B.A. Grzybowski, Chem. Mater. 18, 4722 (2006)
B.A. Grzybowski, K.J.M. Bishop, Small 5, 22 (2009)
T.S. Hansen, K. West, O. Hassager, N.B. Larsen, Adv. Mater. 19, 3261 (2007)
M. Mayer, J. Yang, I. Gitlin, D.H. Gracias, G.M. Whitesides, Proteomics 4, 2366 (2004)
M.J. Jang, Y. Nam, Macromol. Biosci. 15, 613 (2015)
Y. Xia, Y. Tang, H. Wu, J. Zhang, Z. Li, F. Pan, S. Wang, X. Wang, H. Xu, J.R. Lu, A.C.S. Appl, Mater. Interfaces 9, 1255 (2017)
J.L. Zhuang, Y. Zhang, X.Y. Liu, C. Wang, H.L. Mao, X. Du, J. Tang, Appl. Surf. Sci. 469, 90 (2019)
X. Ma, D. Zhao, M. Xue, H. Wang, T. Cao, Angew. Chem. Int. Ed. 49, 5537 (2010)
L. Zhang, J.L. Zhuang, X.Z. Ma, J. Tang, Z.W. Tian, Electrochem. Commun. 9, 2529 (2007)
J. Tang, J.L. Zhuang, L. Zhang, W.H. Wang, Z.W. Tian, Electrochim. Acta 53, 5628 (2008)
L.H. Jin, B.Y. Yang, L. Zhang, P.L. Lin, C. Cui, J. Tang, Langmuir 25, 5380 (2009)
S. Sekine, S. Nakanishi, T. Miyake, K. Nagamine, H. Kaji, M. Nishizawa, Langmuir 26, 11526 (2010)
C.G. Granqvist, A. Hultåker, Thin Solid Films 411, 1 (2002)
M. Grell, D.D.C. Bradley, Adv. Mater. 11, 895 (1999)
K.H. Weinfurtner, H. Fujikawa, S. Tokito, Y. Taga, Appl. Phys. Lett. 76, 2502 (2000)
D. Neher, Macromol. Rapid Commun. 22, 1365 (2001)
M. Imanishi, D. Kajiya, T. Koganezawa, K. Saitow, Sci. Rep. 7, 5141 (2017)
CRC Handbook of Chemistry and Physics, 95th edn. W.M. Haynes Ed. (CRC Press, Boca Raton, FL, 2014), pp. 14–19
C.H. Liang, G.W. Meng, Y. Lei, F. Phillipp, L.D. Zhang, Adv. Mater. 13, 1330 (2001)
K. Soulantica, L. Erades, M. Sauvan, F. Senocq, A. Maisonnat, B. Chaudret, Adv. Funct. Mater. 13, 553 (2003)
M. Gross, N. Linse, I. Maksimenko, P.J. Wellmann, Adv. Eng. Mater. 11, 295 (2009)
NIST X-ray Photoelectron Spectroscopy Database, ver. 4.1. (NIST, 2012) http://dx.doi.org/10.18434/T4T88K. Accessed 2 Sept 2019
C. Donley, D. Dunphy, D. Paine, C. Carter, K. Nebesny, P. Lee, D. Alloway, N.R. Armstrong, Langmuir 18, 450 (2002)
M. Carmo, D.L. Fritz, J. Mergel, D. Stolten, Int. J. Hydrog. Energy 38, 4901 (2013)
T.A. Davis, S.L. Athey, M.L. Vandevender, C.L. Crihfield, C.C.E. Kolanko, S. Shao, M.C.G. Ellington, J.K. Dicks, J.S. Carver, L.A. Holland, J. Chem. Educ. 92, 116 (2015)
C.E. Housecroft, A.G. Sharpe, Inorganic Chemistry, 4th edn. (England, Pearson Education Limited, 2012), pp. 445–473
A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka, J. Am. Chem. Soc. 131, 6050 (2009)
M.M. Lee, J. Teuscher, T. Miyasaka, T.N. Murakami, H.J. Snaith, Science 338, 643 (2012)
A.K. Jena, A. Kulkarni, T. Miyasaka, Chem. Rev. 119, 3036 (2019)
S. Ray, R. Banerjee, N. Basu, A.K. Batabyal, A.K. Barua, J. Appl. Phys. 54, 3497 (1983)
M. Katayama, Thin Solid Films 341, 140 (1999)
Y. Xin, K. Nishio, K. Saitow, Appl. Phys. Lett. 106, 201102 (2015)
A. Paracchino, V. Laporte, K. Sivula, M. Grätzel, E. Thimsen, Nat. Mater. 10, 456 (2011)
K.H. Kim, K.C. Park, D.Y. Ma, J. Appl. Phys. 81, 7764 (1997)
X. Jiang, F.L. Wong, M.K. Fung, S.T. Lee, Appl. Phys. Lett. 83, 1875 (2003)
H. Kim, J.S. Horwitz, W.H. Kim, A.J. Mäkinen, Z.H. Kafafi, D.B. Chrisey, Thin Solid Films 420, 539 (2002)
Acknowledgements
This work was supported by JSPS KAKENHI Grants-in-Aid for Young Scientists (B) (Grant Numbers 26790015 and 17K14082). The author acknowledges Dr. Dote of Hiroshima University for help with XPS measurements and is grateful to Ms. Isagai of the Foundation for Promotion of Material Science and Technology of Japan for conducting XRD measurements. The author is also grateful to Ms. Tanaka of the Hiroshima City Industrial Promotion Centre for the stylus-type roughness instrument. The author also wishes to acknowledge Mr. Nawachi and Mr. Ito of the Hiroshima Prefectural Technology Research Institute for the sheet resistance metre. Transmission spectra and FE-SEM images were measured using shared equipment in the Cryogenics and Instrumental Analysis Division of N-BARD, Hiroshima University.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kajiya, D. An agar sandwich method for patterning transparent conducting oxides. J Mater Sci: Mater Electron 30, 20734–20740 (2019). https://doi.org/10.1007/s10854-019-02440-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-02440-4