Abstract
Herein, egg-shape bismuth vanadate (BiVO4) nanostructures were prepared by a one-pot and surfactant-free hydrothermal method using ethylenediamine and hydrazine hydrate as novel reactants. The obtained products were identified by FTIR, XRD, SEM, EDS, and DRS analyzes. Finally, the photocatalytic oxidation activity of as-prepared nanostructures on desulfurization of thiophene dissolved in n-hexane as a model light oil was studied. According to the results, the desulfurization rate was 81% after 180 min, which is higher than the other reported morphologies for pure BiVO4. Also, the trapping experiments of radical active species showed that superoxide (⋅O2−) and holes (h+) are the most active species in the process of desulfurization oxidation from thiophene. In addition, the photocatalytic recyclability test indicated that after five times the reuse of the as-synthesized nanostructures does not occur a significant change in the oxidation efficiency.
Similar content being viewed by others
References
X. Li, S. Ma, H. Qian, Y. Zhang, S. Zuo, C. Yaoa, Upconversion nanocompossite CeO2:Tm3+/attapulgite intermediated by carbon quantum dots for photocatalytic desulfurization. Powder Technol. 351, 38–45 (2019)
J. Wu, J. Li, J. Liu, J. Bai, L. Yang, A novel Nb2O5/Bi2WO6 heterojunction photocatalytic oxidative desulfurization catalyst with high visible light-induced photocatalytic activity. RSC Adv. 7, 51046 (2017)
S.F. Song, S.K. Shen, J.X. Yang, D.D. Hu, A green synthesis of CTAB–PTP/PAM microhydrogel and its application in oxidation of DBT. J. Mater. Sci. 47, 2501–2508 (2012)
H.W. Yang, B. Jiang, Y.L. Sun, L.H. Zhang, Z.N. Sun, J.Y. Wang, X.W. Tantai, Polymeric cation and isopolyanion ionic self-assembly: novel thin-layer mesoporous catalyst for oxidative desulfurization. Chem. Eng. J. 317, 32–41 (2017)
X.Y. Zeng, X.Y. Xiao, Y. Li, J.Y. Chen, H.L. Wang, Deep desulfurization of liquid fuels with molecular oxygen through graphene photocatalytic oxidation. Appl. Catal. B 209, 98–109 (2017)
L. Wang, W.Y. Wang, N. Mominou, L.X. Liu, S.Z. Li, Ultra-deep desulfurization of gasoline through aqueous phase in situ hydrogenation and photocatalytic oxidation. Appl. Catal. B 193, 180–188 (2016)
J. Zhang, D.S. Zhao, J.L. Wang, L.Y. Yang, Photocatalytic oxidation of dibenzothiophene using TiO2/bamboo charcoal. J. Mater. Sci. 44, 3112–3117 (2009)
H.W. Zheng, Z. Sun, X.L. Chen, Q. Zhao, X.H. Wang, Z.J. Jiang, A micro reaction-controlled phase-transfer catalyst for oxidative desulfurization based on polyoxometalate modified silica. Appl. Catal. A 467, 26–32 (2013)
W.S.A. Rahma, F.S. Mjalli, T. Al-Wahaibi, A.A. Al-Hashmi, Polymeric-based deep eutectic solvents for effective desulfurization of liquid fuel at ambient conditions. Chem. Eng. Res. Des. 120, 271–283 (2017)
C.E.D.A. Padilha, P.V.F. Dantas, F.C.S. Júnior, S.D.O. Júnior, C.D.C. Nogueira, D.F.D.S. Souza, J.A.D. Oliveira, G.R.D. Macedo, E.S.D. Santos, Recovery and concentration of ortho-phenylphenol from biodesulfurization of 4-methyl dibenzothiophene by aqueous two-phase flotation. Sep. Purif. Technol. 176, 306–312 (2017)
X.N. Sun, B.J. Tatarchuk, Photo-assisted adsorptive desulfurization of hydrocarbon fuels over TiO2 and Ag/TiO2. Fuel 183, 550–556 (2016)
L.Z. Zhuang, Q.H. Li, S.X. Chen, X.N. Hou, J.T. Lin, In-situ preparation of porous carbon-supported molybdenum dioxide and its performance in the oxidative desulfurization of thiophene. J. Mater. Sci. 49, 5606–5616 (2014)
F. Lin, Z. Shao, P. Li, Z. Chen, X. Liu, M. Li, B. Zhang, J. Huang, G. Zhu, B. Dong, Low-cost dual co-catalysts BiVO4 for highly efficient visible photocatalytic oxidation. RSC Adv. 7, 15053 (2017)
F. Lin, D. Wang, Z. Jiang, Y. Ma, L. Jun, R. Lia, C. Li, Photocatalytic oxidation of thiophene on BiVO4 with dual co-catalysts Pt and RuO2 under visible light irradiation using molecular oxygen as oxidant. Energy Environ. Sci. 5, 6400–6406 (2012)
F. Lin, Z.X. Jiang, N.F. Tang, C. Zhang, Z.P. Chen, T.F. Liu, B. Dong, Photocatalytic oxidation of thiophene on RuO2/SO4 2−-TiO2: insights for cocatalyst and solid-acid. Appl. Catal. B 188, 253–258 (2016)
L. Yun, Z. Yang, Z.B. Yu, T. Cai, Y. Li, C. Guo, C. Qia, T. Rena, Synthesis of four-angle star-like CoAl-MMO/BiVO4 p–n heterojunction and its application in photocatalytic desulfurization. RSC Adv. 7, 25455 (2017)
J. Wu, F. Duan, Y. Zheng, Y. Xie, Synthesis of Bi2WO6 nanoplate-built hierarchical nest-like structures with visible-light-induced photocatalytic activity. J. Phys. Chem. C 111, 12866–12871 (2007)
E. Aguilera-Ruiz, U.M. García-Pérez, M. de la Garza-Galvána, P. Zambrano-Robledoa, B. Bermúdez-Reyes, J. Peral, Efficiency of Cu2O/BiVO4 particles prepared with a new so procedure on the degradation of dyes under visible-light irradiation. Appl. Surf. Sci. 328, 361–367 (2015)
C. Ravidhas, A.J. Josephine, P. Sudhagar, A. Devadoss, C. Terashima, K. Nakata, A. Fujishima, A.M. EzhilRaj, C. Sanjeeviraja, Facile synthesis of nanostructured monoclinic bismuth vanadate by a co-precipitation method: Structural, optical and photocatalytic properties. Mater. Sci. Semicond. Process. 30, 343–351 (2015)
W. Yin, W. Wang, L. Zhou, S. Sun, L. Zhang, CTAB-assisted synthesis of monoclinic BiVO4 photocatalyst and its highly efficient degradation of organic dye under visible-light irradiation. J. Hazard. Mater. 173, 194–199 (2010)
M. Wang, Q. Liu, Y. Che, L. Zhang, D. Zhang, Characterization and photocatalytic properties of N-doped BiVO4 synthesized via a sol–gel method. J. Alloys Compd. 548, 70–76 (2013)
W. Liu, G. Zhao, M. An, L. Chang, Solvothermal synthesis of nanostructured BiVO4 with highly exposed (0 1 0) facets and enhanced sunlight-driven photocatalytic properties. Appl. Surf. Sci. 357, 1053–1063 (2015)
P. Madhusudan, M. Kumar, T. Ishigaki, K. Toda, K. Uematsu, M. Sato, Hydrothermal synthesis of meso/macroporous BiVO4 hierarchical particles and their photocatalytic degradation properties under visible light irradiation. Environ. Sci. Pollut. Res. 20, 6638–6645 (2013)
I. Khan, S. Ali, M. Mansha, A. Qurashi, Sonochemical assisted hydrothermal synthesis of pseudo-flower shaped Bismuth vanadate (BiVO4) and their solar-driven water splitting application. Ultrason. Sonochem. 36, 386–392 (2017)
S.M. Sun, W.Z. Wang, L. Zhou, H.L. Xu, Efficient methylene blue removal over hydrothermally synthesized starlike BiVO4. Ind. Eng. Chem. Res. 48, 1735–1739 (2009)
Q. Wu, R. Han, P. Chen, X. Qi, W. Yao, Novel synthesis and photocatalytic performance of BiVO4 with tunable morphologies and macroscopic structures. Mater. Sci. Semicond. Process. 38, 271–277 (2015)
Y.N. Guo, X. Yang, F.Y. Ma, K.X. Li, L. Xu, X. Yuan, Y.H. Guo, Additive-free controllable fabrication of bismuth vanadates and their photocatalytic activity toward dye degradation. Appl. Surf. Sci. 256, 2215–2222 (2010)
G.Q. Tan, L.L. Zhang, H.J. Ren, S.S. Wei, J. Huang, A. Xia, Effects of pH on the hierarchical structures and photocatalytic performance of BiVO4 powders prepared via the microwave hydrothermal method. ACS Appl. Mater. Interfaces. 5, 5186–5193 (2013)
S. Obregón, A. Caballero, G. Colón, Hydrothermal synthesis of BiVO4: structural and morphological influence on the photocatalytic activity. Appl. Catal. B 117–118, 59–66 (2012)
M. Mousavi-Kamazani, Z. Zarghami, R. Rahmatolahzadeh, M. Ramezani, Solvent-free synthesis of Cu-Cu2O nanocomposites via green thermal decomposition route using novel precursor and investigation of its photocatalytic activity. Adv. Powder Technol. 28, 2078–2086 (2017)
M. Mousavi-Kamazani, Facile sonochemical-assisted synthesis of Cu/ZnO/Al2O3 nanocomposites under vacuum: optical and photocatalytic studies. Ultrason. Sonochem. 58, 104636 (2019)
S. Alizadeh, M. Mousavi-Kamazani, M. Salavati-Niasari, Hydrothermal synthesis of rod-like LaOCl nanoparticles from new precursors. J. Clust. Sci. 26, 645–652 (2015)
M. Mousavi-Kamazani, S. Alizadeh, F. Ansari, M. Salavati-Niasari, A controllable hydrothermal method to prepare La(OH)3 nanorods using new precursors. J. Rare Earths 33, 425–431 (2015)
A.M. Latifi, M. Mirzaei, M. Mousavi-Kamazani, Z. Zarghami, Rice-like Ag/Al2O3 nanocomposites preparation from AlOOH nanostructures synthesized via a facile hydrothermal route for azo dyes photocatalytic degradation and Pb2+ adsorption. J. Mater. Sci. 29, 10234–10245 (2017)
M. Panahi-Kalamuei, M. Mousavi-Kamazani, M. Salavati-Niasari, Self-assembly of nanoparticles to form tree-like tellurium nanostructures using novel starting reagent. Mater. Lett. 136, 218–221 (2014)
Acknowledgements
The author thanked the University of Semnan for supporting this work.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Mousavi-Kamazani, M. Facile hydrothermal synthesis of egg-like BiVO4 nanostructures for photocatalytic desulfurization of thiophene under visible light irradiation. J Mater Sci: Mater Electron 30, 17735–17740 (2019). https://doi.org/10.1007/s10854-019-02123-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-019-02123-0